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Hoang Nam Nhat,Dinh Van Chau,Dinh Van Thuong,Nguyen Thi Hang 한국인터넷방송통신학회 2015 International Journal of Internet, Broadcasting an Vol.7 No.1
This paper presents the application of the bond valence method to estimate the valence charge distribution in several perovskite systems: La1xPbxMnO3 (x=0.1-0.5), La0.6Sr0. - xTixMnO3 (x=0.0-0.25) and La1xSrxCoO3 (x=0.1-0.5); the reviewing of their crystal structures is also incorporated. The results showed the failure of the elastic bonding mechanism in all studied systems and revealed the general deficit of the valence charge in their unit cells. This valence deficit was not associated with the structural defects and was not equally localized in all coordination spheres. As the content of substitution increased, the charge deficit declined systematically from balanced level, signifying the transfer of valence charge from the O6 to O12 spheres. This transfer depended on the valence deviation of spheres and the average reached near 2 electron per unit cell. The possible impact of the limitted accuracy of the available structural data on the bond valence results has also been considered.
Nhat, Hoang Nam,Chau, Dinh Van,Thuong, Dinh Van,Hang, Nguyen Thi The Institute of Internet 2015 International Journal of Internet, Broadcasting an Vol.7 No.1
This paper presents the application of the bond valence method to estimate the valence charge distribution in several perovskite systems: $La_{{\tilde{1}}x}Pb_xMnO_3$ (x=0.1-0.5), $La_{0.6}Sr_{0.{\tilde{4}}x}Ti_xMnO_3$ (x=0.0-0.25) and $La_{{\tilde{1}}x}Sr_xCoO_3$ (x=0.1-0.5); the reviewing of their crystal structures is also incorporated. The results showed the failure of the elastic bonding mechanism in all studied systems and revealed the general deficit of the valence charge in their unit cells. This valence deficit was not associated with the structural defects and was not equally localized in all coordination spheres. As the content of substitution increased, the charge deficit declined systematically from balanced level, signifying the transfer of valence charge from the ${\tilde{B}}O_6$ to ${\tilde{A}}O_{12}$ spheres. This transfer depended on the valence deviation of spheres and the average reached near 2 electron per unit cell. The possible impact of the limitted accuracy of the available structural data on the bond valence results has also been considered.
Phung Quoc Thanh,Seong-Cho Yu,Hoang Nam Nhat 한국자기학회 2008 Journal of Magnetics Vol.13 No.4
The authors studied the conduction mechanism in an uranium doped low dimensional magnetic system Ca₂CuO₃. This system exhibits the S=1/2 quasi 1D antiferromagnetic chains of -Cu-O- with strong magnetic coupling, and demonstrates continuous semiconductor-like behavior with constant covalent insulator character. This paper identifies the conduction is due to thermally activated phonon-assisted electron hopping between dopant uranium sites. The parameter a, the characteristic for hopping probability, was determined to be 0.18 A<SUP>?1</SUP>. This value manifests a relatively stronger hopping probability for Ca₂CuO₃ as compared with other uranium doped ceramics.
Numerical Simulation of Phase Separation in Bulk Hetero-junction Photoactive Layer
Hang, Nguyen Thi,Van Thuong, Dinh,Nhat, Hoang Nam,Van Chau, Dinh The International Promotion Agency of Culture Tech 2016 International Journal of Advanced Culture Technolo Vol.4 No.1
Morphology evolution of the active layer in bulk hetero-junction organic photovoltaic is modeled and visualized. The width of the phase domain can be predicted using the relationship of characteristics length and evolution time of the process. The 3D numerical simulation of the PCBM/P3HT blend morphology evolution with respect to time is presented. It is observed that the domain width of composition phase can be predicted by using the relationship between value of characteristic length R(t) and evolution time t.
Numerical Simulation of Phase Separation in Bulk Hetero-junction Photoactive Layer
Naguyen Thi Hang,Dinh Van Thuong,Hoang Nam Nhat,Dinh Van Chau 국제문화기술진흥원 2016 International Journal of Advanced Culture Technolo Vol.4 No.1
Morphology evolution of the active layer in bulk hetero-junction organic photovoltaic is modeled and visualized. The width of the phase domain can be predicted using the relationship of characteristics length and evolution time of the process. The 3D numerical simulation of the PCBM/P3HT blend morphology evolution with respect to time is presented. It is observed that the domain width of composition phase can be predicted by using the relationship between value of characteristic length R(t) and evolution time t.
Optical Spectra of the Colloidal Fe-doped Manganate CaMn1−xFexO3 (x = 0, 0.01, 0.03, 0.05)
Duc Huyen Yen Pham,Duc Tho Nguyen,Duc Thang Pham,Nam Nhat Hoang,The Tan Pham 한국물리학회 2013 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.62 No.12
We report the optical behaviors of the Fe-doped CaMnO3 family of compounds at low dopingconcentrations x 5%. The study aims at assisting the evaluation of the competition between ferroandantiferromagnetic orderings, which is believed to be a cause of many interesting properties of thisclass of compounds, including the magnetization reversal effect recently discovered. The structuralcharacterization showed a predominant orthorhombic phase with slightly increased cell constantsdue to doping. The Raman spectra revealed changes associated with the Mn sites, and the IRabsorption spectrum showed a characteristic Fe band at 1.2 eV, which should be accompanied bya change of spin. The analysis of the magnetization data allowed us to predict that while thedoping reduced the ferromagnetic coupling strength, and therefore the TC, the maximal dopingconcentration for the effective exchange to be zero was around 14%.
Tran Dang Thanh,Phan, T. L.,Phung Quoc Thanh,Hoang Nam Nhat,Duong Anh Tuan,Yu, S. C. IEEE 2014 IEEE transactions on magnetics Vol.50 No.6
<P>This paper presents a detailed study on the Co-doping influence on the electrical and magnetotransport properties of La0.7Ca0.3Mn1-xCoxO3(x = 0.09-0.17) prepared by solid-state reaction. Magnetic measurements versus temperature revealed a gradual decrease of the magnetization (M) and Curie temperature (T-C) with increasing Co concentration (x). The T-C values vary from 194 to 159 K as changing x from 0.09 to 0.17, respectively. H/M versus M-2 performances around T-C prove the x = 0.09 sample undergoing a first-order magnetic phase transition (FOMT) while the samples with x >= 0.11 undergo a second-order magnetic phase transition (SOMT). The other with x = 0.10 is considered as a threshold concentration of the FOMT-SOMT transformation. Considering temperature dependences of resistivity, rho(T), in the presence and absence of the magnetic field, the samples (excepting for x = 0.17) exhibit a metal-insulator transition at T (P) = 60-160 K, which shifts toward lower temperatures with increasing x. In the metallic-ferromagnetic region, the rho(T) data are well fitted to a power function rho(T) = rho(0) + rho(2) T-2 + rho(4.5) T-4.5. This indicates electron-electron and electron-magnon scattering processes are dominant at temperatures T < T (P). In addition, the conduction data at temperatures T > theta(D)/2 (theta(D) is the Debye temperature) and T (P) < T < theta(D)/2 obey the small-polaron and variable-range hopping models, respectively. The values of activation energy E-p, and density of states at the Fermi level N(E-F) were accordingly determined. Here, N(E-F) increases while E-p decreases when an external magnetic field is applied. We also have found that N(E-F) increases when materials transfer from the FOMT to the SOMT, and N(E-F) value becomes smallest for the sample having the coexistence of the FOMT and SOMT (i.e., x = 0.10).</P>