Sensitive and selective m-tolyl hydrazine chemical sensor development based on CdO nanomaterial decorated multi-walled carbon nanotubes

Mohammed M. Rahman,M.M. Alam,Khalid A. Alamry 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.77 No.-

In this approach, the wet-chemical (co-precipitation) technique was used to prepare the cadmium oxide(CdO) nanoparticles (NPs) decorated with multi-walled carbon nanotubes (CNT) at low temperature. Thepowder XDR, UV–vis, TEM, XPS, and FTIR spectroscopy were used for detail characterization of thesynthesized CdO/CNT nanocomposite (NCs). A thin layer of CdO/CNT NCs was deposited onto a glassycarbon electrode (GCE) with conducting coating binder to obtain a chemical sensor which wassubsequently used to detect m-tolyl hydrazine hydrochloride (m-THyd) in buffer medium byelectrochemical approach for environmental safety. The proposed m-THyd chemical sensor exhibitedlong-term stability, good selectivity, broad linear dynamic range, lower detection limit, and enhancedelectrochemical response. The calibration curve of the current vs concentration of m-THyd was found tobe linear (r2 = 0.9903) over the linear dynamic range (LDR) of 0.01 nM to 0.1 mM. The sensitivity(25.7911 mA mM cm 2) of chemical sensor was calculated from the slope of calibration curve and surfacearea of GCE (0.0316 cm2) and the detection limit (4.0 0.2 pM) was estimated from the signal to noiseratio at 3. These preliminary results suggest that the newly developed CdO/CNT NCs nanocompositecould be promising electrochemical sensors for the detection of hazardous toxins to clean theenvironment in broad scales.

Stable and effective super-hydrophilic polysulfone nanofiber mats for oil/water separation

Obaid, M.,Barakat, Nasser A.M.,Fadali, Olfat A.,Al-Meer, Saeed,Elsaid, Khalid,Khalil, Khalil Abdelrazek Elsevier 2015 Polymer Vol.72 No.-

<P><B>Abstract</B></P> <P>Hydrophobicity of polysulfone is the main constraint facing wide application in the most important field; water treatment, although this polymer shows promising characteristics to be used in different separation technologies. In this study, super-hydrophilic polysulfone nanofiber mats are introduced using novel modifications. The introduced nanofibers were synthesized by electrospinning of polysulfone/NaOH/DMF electrospun solution. The prepared electrospun nanofibers have been activated by deposition of a polyamide layer using interfacial polymerization (IP) reaction between m-phenylenediamine and 1,3,5-benzenetricarbonyl chloride. Three different heat treatment methodologies were investigated to enhance the characteristics of the activated nanofiber mats; normal drying at 70 °C, and soaking in boiled water followed by either normal drying at 70 °C or storing in the water. Investigation of the mechanical properties indicated that incorporation of NaOH improves the tensile stress by 40% compared to the pristine polysulfone nanofibers. Interestingly, treatment of the activated nanofiber mats in the boiled water followed by storing in water led to produce super-hydrophilic mats with water contact angle of 3° due to enhancing the IP reaction on the surface of the individual nanofibers. In oil/water separation process, the proposed heat treatment for the modified nanofiber mats resulted in increase the water flux from 8 to 12.21 m<SUP>3</SUP>/m<SUP>2</SUP> day with oil rejection of 99.976%.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Super-hydrophilic membrane based on PSF nanofibers is introduced. </LI> <LI> The membrane was modified using simple and effective heat treatment process. </LI> <LI> The corresponding water flux is very high; 12.21 m<SUP>3</SUP>/m<SUP>2</SUP> day. </LI> <LI> The fabrication process is simple, cheap and applicable. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

Inducing Potential Mutants in Bread Wheat Using Different Doses of Certain Physical and Chemical Mutagens

Ghada M.Sh.M. Abaza,Hassan A. Awaad,Zakaria M. Attia,Khalid S. Abdel-lateif,Mohamed A. Gomaa,Safy M.Sh.M. Abaza,Elsayed Mansour 한국육종학회 2020 Plant Breeding and Biotechnology Vol.8 No.3

Mutation is an effective strategy not only for creating novel variation into crop genome but also for direct releasing adapted and high-yielding genotypes. The current work explores inducing genetic variability in bread wheat using physical and chemical mutagens. Three wheat cultivars were treated by three mutagens; gamma irradiation (five doses; 250, 300, 350, 400 and 450 Gray); laser ray (three treatments; 1, 1.5, and 2 hour exposure) and EMS (three concentrations; 0.2, 0.3 and 0.4%). Besides, a combination of physical (laser) and chemical (EMS) mutagens using middle range of each treatment (1.5 hour laser and 0.3% EMS) was attempted to be applied. The treated seeds were sown in the first season and 4050 M1 plants were harvested. The harvested seeds were sown in the second season, and 78750 M2 plants were obtained. The selection was performed in second season (M2) based on morpho-physiological and yield traits; flag leaf area, flag leaf chlorophyll content, plant height, spike length, grain yield per plant and its components. Based on evaluated traits fourteen mutants were selected to be evaluated in the third generation (M3). The results indicated that the used mutagens had direct impact and significantly improved agronomic traits in derivative mutants compared to their parent cultivars. Moreover, the maximum increment in yield related traits were obtained by 0.4% EMS, 1 and 2 hour-laser, 350-Gy, 1.5 hour × 0.3% EMS and 250-Gy. The obtained results highlighted the importance of these doses of applied mutagens to induce useful genetic variability in bread wheat for improving grain yield and contributing traits.

Polyaniline-engineered zinc sulphide nanocomposite as a highly efficient electrocatalyst for the oxygen evolution process

Alenad Asma M.,Fatima Sofia,Khalid Usman,Bano Nigarish,Abid Abdul Ghafoor,Manzoor Sumaira,Farid Hafiz Muhammad Tahir,Messali Mouslim,Alzahrani Huda A.,Taha Taha Abdel Mohaymen 한국세라믹학회 2023 한국세라믹학회지 Vol.60 No.5

Hydrogen is the ideal future fuel, since it is clean, saves energy, and is abundant in nature. Though there are several methods for producing hydrogen, only a few of them are environmentally friendly. To employ water electrolysis to make hydrogen and solve the energy shortage problem, highly active electrocatalysts must be created. Zinc sulphide/polyaniline (ZnS/PANI) nanocomposite was successfully produced using a straightforward two-step coprecipitation and polymerization procedure. Different analyses were used to characterize the fabricated materials. The findings show that the ZnS/PANI nanocomposite's morphology has a consistent porous shape, and the electrical structure of the active sites determines how well catalysts can make contact with the intermediates. Multiple attempts have been made to create the most affordable, functional electrocatalyst for oxygen evolution reactions (OER). However, clean energy production from such materials is sluggish. In comparison to pure PANI nanofibers (143.14 m2 g−1 and 0.4827 nm) and ZnS nanostructures (249.85 m2 g−1 and 0.4224 nm), the composite ZnS/PANI displays a greater Brunauer–Emmett–Teller (BET) surface area around 372.65 m2 g−1 along with nanoporous size of 0.393 nm due to the interaction, which provides distinctive features in contrast to ZnS and PANI. Synergistically, composite ZnS/PANI indicates lower overpotentials of 132 mV for oxygen evolution performance at 10 mA cm−2. An improved OER activity is observed by composite ZnS/PANIs as high current density, lower overpotential and reduced Tafel value of 53 mV dec−1. This catalyst also exhibited a significant double-layer capacitance and a large electrochemically active surface area. ZnS/PANI is a magnificent electrocatalyst for oxygen evolution.

Allelic variation of melanocortin-1 receptor locus in Saudi indigenous sheep exhibiting different color coats

Mahmoud, Ahmed H.,Mashaly, Ashraf M.,Rady, Ahmed M.,Al-Anazi, Khalid M.,Saleh, Amgad A. Asian Australasian Association of Animal Productio 2017 Animal Bioscience Vol.30 No.2

Objective: This study was designed to characterize the DNA polymorphisms of the melanocortin-1 receptor (MC1R) gene in indigenous Saudi Arabian sheep breeds exhibiting different color coats, along with individuals of the Sawaknee breed, an exotic sheep imported from Sudan. Methods: The complete coding region of MC1R gene including parts of 3' and 5' untranslated regions was amplified and sequenced from three the indigenous Saudi sheep; Najdi (generally black, n = 41), Naeimi (generally white with brown faces, n = 36) and Herri (generally white, n = 18), in addition to 13 Sawaknee sheep. Results: Five single nucleotide polymorphisms (SNPs) were detected in the MC1R gene: two led to nonsynonymous mutations (c.218 T>A, p.73 Met>Lys and c.361 G>A, p.121 Asp>Asn) and three led to synonymous mutations (c.429 C>T, p.143 Tyr>Tyr; c.600 T>G, p.200 Leu>Leu, and c.735 C>T, p.245 Ile>Ile). Based on these five SNPs, eight haplotypes representing MC1R $E^d$ and $E^+$ alleles were identified among the studied sheep breeds. The most common haplotype (H3) of the dominant $E^d$ allele was associated with either black or brown coat color in Najdi and Sawaknee sheep, respectively. Two other haplotypes (H6 and H7) of $E^d$ allele, with only the nonsynonymous mutation A218T, were detected for the first time in Saudi indigenous sheep. Conclusion: In addition to investigating the MC1R allelic variation in Saudi indigenous sheep populations, the present study supports the assumption that the two independent nonsynonymous Met73Lys and Asp121Asn mutations in MC1R gene are associated with black or red coat colors in sheep breeds.

Households' dietary habits and food consumption patterns in Hamishkoreib locality, Kassala State, Sudan

Fatima A. Khalid,Awadia K.M. Ali,Siteldar A. Ali,Zemzem Y.A. Mosmar,Sarah S.M. Salih,Tahani K. Salman,Mohammed A. Desogi,Mohammed A. Soghaier,Eltayeb E. Mohammed,Abdalla A. Mohammed 한국식품연구원 2017 Journal of Ethnic Foods Vol.4 No.3

Background: Hamishkoreib is among the localities that have suffered most from chronic food insecurity in Kassala State, Sudan. This study was designed to determine the dietary habits and food consumption patterns in this locality. Methods: A descriptive cross-sectional survey was conducted among 403 households in the Hamishkoreib locality from June 2014 to February 2015. Sociodemographic and dietary information was collected through a modified food frequency questionnaire. The collected data were analyzed using SPSS 16.0 to estimate the frequency of variables. Results: Among 403 households, the incidence of informal education and illiteracy was 93.3%. Charcoal production and firewood cutting as the main source of income was reported by 66.6%. Three meals per day were consumed by 83.4% of households. They depended largely on cereal foods, particularly sorghum in the form of kissra and assida. Milk and dairy products were dominant in breakfast and dinner. Meat was consumed by 67.7% of households just once per week. However, chicken, fish, and eggs were rarely consumed (1.5%, 0.7%, and 19.8% respectively). Most (85.3%) households related poor or rare consumption of these protein- rich foods to culture, while 14.7% related it to financial reasons or illness. These types of food were mainly consumed by men and were not allowed to be consumed by women and children. Tea and coffee were excessively consumed in the morning and during the day. Fruit and vegetable consumption was low. Conclusion: The study revealed consumption of an unbalanced diet with insufficient proteins and micronutrients. There was excessive consumption of tea and coffee, which had a negative impact on food intake and absorption. The paper recommends launching a major nutrition program to encourage diversity of food consumption and to improve the capacity building of households.

NOx removal efficiency and N2 selectivity during selective catalytic reduction processes over Al2O3 supported highly cross-linked polyethylene catalysts

Ahmad M. Abu-Jrai,Ala’a H. Al-Muhtaseb,Jehad A. Yamin,Khalid A. Ibrahim,Omar A. Al-Khashman,Mouath A. Al-Shaweesh,Muhannad A. Hararah,Umer Rashid,Mohammad Ahmad,Gavin M. Walker 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.4

The performance of a highly cross-linked polyethylene catalyst supported on alumina for low temperature selective catalytic reduction of NOx by unburned hydrocarbons (HCs) existing in an exhaust gas was examined at different engine conditions with the addition of exhaust-gas recirculation. The HXPE catalyst was shown to exhibit good NOx reduction activity at low temperatures (100–250℃) where the only reductant was the unburned HC, which was already present in the exhaust flow. The maximum NOx reduction of approximately 52% was achieved at a temperature of 150℃. HXPE demonstrated very good selectivity toward N2 in the majority of tested conditions ( 80%).

The Status of the Bring Your Own Device (BYOD) in Saudi Arabia: Dataset

Khalid A. Almarhabi,Adel A. Bahaddad,Ahmed M. Alghamdi International Journal of Computer ScienceNetwork S 2023 International journal of computer science and netw Vol.23 No.2

The paper brings across data that is utilized in the Bring Your Own Device (BYOD) status collected between February and April of 2021 across Saudi Arabia. The data set was collected using questionnaires established through online mechanisms for the respondents. In the questionnaire, personal details included five questions while seven questions addressed the working model of personal mobile devices. Six questions addressed the awareness of employees bring your own device awareness for employees comprised seven questions and two questions addressed the benefits of business achievements. In the identification of suitable respondents for the research, two approaches were applied. The research demanded that the respondents be Saudi Arabian nationals and have attained 18 years. Snowball and purposive techniques were applied in the collection of information from a wide area of Saudi Arabia while employing social media approaches that include the use of WhatsApp and emails in the collection of data. The approach ensured the collection of data from 857 respondents used in the identification of the status as well as issues across the BYOD environment and accompanying solutions. The data was also used in the provision of awareness in the community through short-term courses, cyber security training and awareness programs. The results of the research are therefore applicable to the context of the Saudi Arabian country that is currently facing issues in dealing with the application of personal devices in the work environment.

Synthesis and biological evaluation of pyrazole chalcones and derived bipyrazoles as anti-inflammatory and antioxidant agents

Hassan M. Faidallah,Sherif A. F. Rostom,Khalid A. Khan 대한약학회 2015 Archives of Pharmacal Research Vol.38 No.2

A series of bipyrazoles functionalized withsulfonamide, N1,N3-disubstituted sulfonylurea, sulfonylthioureapharmacophores, and some derived thiazolidinoneand thiazoline ring systems were synthesized. Thestructures of the newly synthesized compounds were substantiatedby analytical and diverse spectroscopic data. Theanti-inflammatory and antioxidant activity of some of thenewly synthesized compounds were tested and the resultsreveled that compounds 14, 16, 20, 24 and 25 proved to bethe most active anti-inflammatory agents according to theCarrageenan-induced rat paw edema bioassay. Whereas,the analogs 14, 16 and 24 were able to exhibit good tomoderate antioxidant activity in the DPPH radical-scavengingassay. Hence, compounds 14, 16 and 24 can beconsidered as lead structures for dual anti-inflammatoryand antioxidant activities.

Effect of Cotton Leaf Mosaic Disease on Morphology, Yield and FibreCharacteristics of Upland Cotton in Pakistan

Khalid P. Akhtar,M. A. Haq,Wajid Ishaque,M. K. R. Khan,Azeem I. Khan 한국식물병리학회 2005 Plant Pathology Journal Vol.21 No.2

The effect of cotton leaf mosaic disease on morphology,yield and fibre characteristics was examined for a susceptible cotton candidate variety CRIS-168. Plants inoculated at most susceptible growth stage (six week) under screen house showed severe mosaic symptoms.There was a significant reduction in plant height and yield. Cotton leaf mosaic disease was found to produce severe effects on plant morphology with 24.1% reduction in plant height, 25% in internode length and 37.5% in number of sympodia on main stem. However no changes were observed against number of monopodial branches per plant. Inoculated plants showed 82% decrease in yield/plant, 80% in number of boll set/plant, 12.1% in boll weight, 12.8% in lint weight, 10.8% in seed weight, and 6.8% in seed index. Cotton leaf mosaic disease also showed effects on fibre characteristics with 0.8% decrease in GOT and 1.6% in fibre length. In contrast, uniformity ratio, fibre fineness and maturity index was increased by 20.5%, 14.4% and 0.9%, respectively.