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고온 석탄 가스정제를 위한 아연계 탈황제의 첨가제 영향
정용길,이종대,박노국,이태진 한국공업화학회 2003 응용화학 Vol.7 No.1
The effect of additives on zin-base desulfurization sorbents for hot coal gas clean-up at middle temperature was studied in this work. In roder to advance a regeneration and durability of ZnO/natural zeolite sorbents, it modification by adding Fe_2O_3 or ZrO_2 was studied. It were prepared that the ZnO/natural zeolite/Fe_2O_3 or ZrO_2 by physical mixture method : the amount of ZnO, natural zeolite and additives were repectively fixed as a wight percent of 65, 25 and 10. The reactivity of sorbents was determined for 5cycles of sulfidation and regeneration in fixed-bed. Result showed that regeneration and durability were improved. Further more, the sorbent, containing ZrO_2, an excellent attrition resistance. As mentioned above, the sorbents, were highly advanced for durability, regeneration and attrition resistance by additive.
천연제올라이트를 지지체로 사용한 고온건식 아연계 탈황제의 반응특성 연구
박노국,정용길,이종대,이태진,김재창 한국화학공학회 2003 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.41 No.5
고온건식 탈황제의 지지체로 알루미나와 천연제올라이트를 사용하여 아연계 탈황제를 제조하였으며 성능을 조사하였다. 두 가지 탈황제의 반응특성실험은 480℃/580℃(황화/재생온도)에서 칸 밸런스와 고정층 반응장치로 반응속도와 황수용능력을 비교하였으며 내마모 실험장치를 이용하여 탈황제의 내마모도를 조사하였다. 두 탈황제의 성능 실험결과 천연제올라이트를 지지체로 사용한 탈황제의 초기 황화반응속도가 알루미나를 지지체로 사용한 탈황제보다 빨라졌으며, 10 cycle에서 황수용능력이 20 gS/100 g sorbent 이상 유지되었다. 내마모성은 AI(마모지표)값이 14.7%정도였다. 본 연구에서는 천연제올라이트의 고온건식 탈황제의 지지체로 적용 가능성을 확인하였다. Two types of zinc-based sorbents using alumina and natural zeolite as the supports for hot-gas desulfurization were prepared, and investigated their desulfurization capability. Their reaction rate and sulfur capacity were compared by Cahn balance and over the fixed bed reactor system at 480℃/580℃ (sulfidation/regeneration). The attrition resistance was measured by ASTM methd. Thc initial sulfidation rate of ZnO/natural zeolite sorbent was higher than that of ZnO/alumina, and the sulfur capacity of ZnO/natural zeolite sorbent was maintained above 20 gS/l00 g sorbent for 10 cycles. A attrition index was 14.7%. The use of natural zeolite as a support of sorbents may be possible for hot gas desulfurization.
기포유동층 반응기 내에서 천연제올라이트를 사용한 아연계 탈황제의 반응특성연구
김동현,정용길,박노국,이종대,전진혁,류시옥,이태진 한국공업화학회 2003 응용화학 Vol.7 No.2
To improve attrition resistance, calcium oxide was added to durable ZZF sorbent. It was named ZZFCa sorbent. The reactivity of ZZFCa sorbent was investigated in the fluidized-bed reactor. The influencesof the sulfur capacity and the regeneration time for various fluidization velocities from 0.07㎧ to 0.20㎧ were investigated for 5-cycles. As a result, ZZFCa sorbent appeared the high sulfur capacity abouve 10gS/100g sorbent. The sulfur capacity of ZZFCa was maintained, although fluidization velocities increased.