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The “Trivial” Mechanism for the Photo-Fries Reaction of Phenyl Acetate and Biphenylyl Acetates
윤효정,고성혜,고미경,최우기,Yun, Hyo Jeong,Go, Seong Hye,Go, Mi Gyeong,Choe, U Gi Korean Chemical Society 2000 Bulletin of the Korean Chemical Society Vol.21 No.9
The mechanism for the photo-Fries rearrangement of phenyl acetate andbiphenylyl acetates were reinvestigat-ed in phenol (or phenol derivatives) containing media. The results showed that the phenol (or phenol deriva-tives) which is the most common by-product of Fries reaction reacts with acyl radical togive Fries-product. These phenol (or phenol derivatives) contributions to the Fries-products were suggested as the Trivial mecha-nism for the photo-Fries reaction.