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        트리클로로에틸렌의 유통,사용 실태조사 결과

        조형열 ( Hyung Yoel Cho ),조성현 ( Sung Hyun Cho ),유장진 ( Jang Jin Ryoo ),김병규 ( Byung Gyu Kim ),박승현 ( Seung Hyun Park ),강성규 ( Seong Kyu Kang ) 한국산업위생학회 2007 한국산업보건학회지 Vol.17 No.3

        Trichloroethylene(TCE) is widely used as a degreasing solvent in workplaces. TCE is primarily toxic to the nervous system, however, systemic disorder like Stevens-Johnson syndrome has been recently reported in small-scale factories, where the government has had limited information of chemical use. A survey was performed to investigate the actual condition of using TCE and to provide practical information to occupational health service agencies and professionals. This survey was carried out on 103 factories out of 430 factories which were conducted periodic work environment measurement for TCE. Degreasing was the most popular reason for using TCE in Korea, which reached to 94%. TCE was also used as a solvent for rubber in the coating or molding process, and adhesives in the bonding process. Metal fabrication was the most common as 23%, followed by assembling automobile parts (17%), and machinery (12%). Workers exposed to TCE during full-shift were 52% while 48% were exposed during short period of the shift or intermittently. Manual or semiautomatic work occupied 87% while automatic work was just 13%. Though automatic work by a closed system was generally lower exposed to TCE, compared to manual work, it can cause a high exposure when the maintenance system is improper. Semi-automatic work especially like open-top degreasing process can cause a high exposure when local exhaust system with condensing and refrigerating coils in the degreaser does not work well. In conclusion, the survey showed nationwide status of TCE exposure in various aspects. It can be used to monitor workplaces and workers exposed to TCE to prevent occupational diseases.

      • KCI등재

        EDXRF에 의한 용접흄 중의 중금속의 비파괴 정량

        박승현,정지연,유장진,이나루,일재,송경석,이용학,한정희,김성진,박정선,정호근 한국산업위생학회 2001 한국산업보건학회지 Vol.11 No.3

        The EDXRF(energy Dispersive X-ray Fluorescence Spec=trometer) technique was applied to the determination of heavy metals in welding fume. The EDXRF method designed in this study was a non-destructive analysis method. Samples were analyzed directly by EDXRF without any pre-treatment such as digestion and dilution. The samples used to evaluate such as digestion and dilution. the samples used to evaluate this method were laboratory samples exposed in a chamber connected with a welding fume generator. The samples were first analyzed using a non-destructive EDXRF method. The samples subsequently were analyzed using AAS method to verify accuracy of the EDXRF method. The purpose of this study was to evaluate the possibility of the non-destructive analysis of heavy metals in welding fume by EDXRF. The results of this study were as follow: 1. When the samples were collected under the open-face sampling condition, a surface distribution of welding fume particles on sample filters was uniform, which made non-destructive analysis possible. 2. The method was statistically evaluated according to the NIOSH(National Institute for Occupational Safety and Health) and HSE(Health and Safety Executive) Method. 3. The overall precision of the EDXRF method was calculated at 3.45% for Cr, 2.57% for Fe and 3.78% for Mn as relative standard deviation(RSD), respectively. The limits of detection were calculated at 0.46 ㎍/sample for Cr, 0.20 ㎍/sample for Fe and 1.14 ㎍/sample for Mn, respectively. 4. A comparison between the results of Cr, Fe, Mn analyzed by EDXRF and AAS was made in order to assess the accuracy of EDXRF method. The correlation coefficient between the results of EDXRF and AAS was 0.9985 for cr, 0,995 for Fe and 0.9982 for Mn, respectively. The overall uncertainty was determined to be ±12.31% , 8.64% and 11.91% for Cr, Fe and Mn, respectively. In conclusion, this study showed that Cr, Fe, Mn in welding fume were successfully analyzed by the EDXRF without any sample pre-treatment such as digestion and dilution and a good correlation between the results of EDXRF and AAS was obtained. It was thus possible to use the EDXRF technique as an analysis method of working environment samples. The EDXRF method was an efficient method in a non-destructive analysis of heavy metals in welding fume.

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