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      • KCI등재

        Controlled synthesis and luminescence properties of doped NaLa(WO4)2 microstructures

        Yunhua Han,Yan Wang,Shaohua Huang,Fan-Long Jin,Shili Gai,Na Niu,Liuzhen Wang,Piaoping Yang 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.34 No.-

        In this work, well-defined NaLa(WO4)2microstructures were prepared by a facile hydrothermal processin the presence of oleylamine and oleic acid as a mixed surfactant. The phase, morphology, size andluminescence properties were well characterized by means of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectra, and decaytime, respectively. The results reveal that the morphology and size of the as-synthesized samples can betuned by altering the reaction time and the amounts of oleic acid. A possible formation mechanism oftetragonal NaLa(WO4)2 is proposed on the basis of oleic acid amount-dependent experiments. Uponultraviolet (UV) excitation, NaLa(WO4)2:Eu3+ and NaLa(WO4)2:Tb3+ exhibit the characteristic downconversionemissions of Eu3+ and Tb3+. Yb3+/Er3+ and Yb3+/Tm3+ co-doped NaLa(WO4)2 samples showstrong green (Er3+, 4S3/2, 2H11/2!4I15/2) and blue (Tm3+, 1G4!3H6) up-conversion emission under980 nm laser diode excitation. Upconversion emission mechanisms of NaLa(WO4)2:Ln (Ln = Yb/Er, Yb/Tm) are also presented based on the emission spectra and the plot of luminescence intensity to pumppower. It should be noted that the intensity of the upconversion emissions can be dramatically enhancedcompared with sodium free tungstates, which can be attributed to the charge compensation and meansthe introduction of Na+ ions in WO42 causes less distortion in the crystal structure.

      • 3D Model Compression For Collaborative Design

        Liu, Jun,Wang, Qifu,Huang, Zhengdong,Chen, Liping,Liu, Yunhua Society for Computational Design and Engineering 2007 International Journal of CAD/CAM Vol.7 No.1

        The compression of CAD models is a key technology for realizing Internet-based collaborative product development because big model sizes often prohibit us to achieve a rapid product information transmission. Although there exist some algorithms for compressing discrete CAD models, original precise CAD models are focused on in this paper. Here, the characteristics of hierarchical structures in CAD models and the distribution of their redundant data are exploited for developing a novel data encoding method. In the method, different encoding rules are applied to different types of data. Geometric data is a major concern for reducing model sizes. For geometric data, the control points of B-spline curves and surfaces are compressed with the second-order predictions in a local coordinate system. Based on analysis to the distortion induced by quantization, an efficient method for computation of the distortion is provided. The results indicate that the data size of CAD models can be decreased efficiently after compressed with the proposed method.

      • KCI등재

        Utilization of electron beam to modulate electron injection over Schottky barrier

        Qi Zhang,Junjie Qi,Yunhua Huang,Huifeng Li,Xin Li,Ruoshui Wang,Yue Zhang 한국물리학회 2011 Current Applied Physics Vol.11 No.3

        Modulation of electron injection over Schottky barrier was realized by employing electron beam irradiation on the metal/ZnO-nanowire contact. The structure revealed a good response to the illumination at a scanning frequency of 0.1 Hz, which can be enhanced by increasing bias and decreased with the increase of electron beam energy. These phenomena can be attributed to the Schottky barrier formed at the metal/ZnO-nanowire interface which limits the electron transport across the contact. The electron beam irradiation gives rise to high efficiency of electron injection over the barrier, while the interplay between charge discreteness, coherent scattering, and Coulomb interaction may reduce the conductivity.

      • KCI등재

        Influence of Cooling Rate on Secondary Phase Precipitation and Proeutectoid Phase Transformation of Micro-Alloyed Steel Containing Vanadium

        Kun Dou,Lingtao Meng,Qing Liu,Bo Liu,Yunhua Huang 대한금속·재료학회 2016 METALS AND MATERIALS International Vol.22 No.3

        During continuous casting process of low carbon micro-alloyed steel containing vanadium, the evolution of strand surface microstructure and the precipitation of secondary phase particles (mainly V(C, N)) are significantly influenced by cooling rate. In this paper, influence of cooling rate on the precipitation behavior of proeutectoid α-ferrite at the γ-austenite grain boundary and in the steel matrix are in situ observed and analyzed through high temperature confocal laser scanning microscopy. The relationship between cooling rate and precipitation of V(C, N) from steel continuous casting bloom surface microstructure is further studied by scanning electron microscopy and electron dispersive spectrometer. Relative results have shown the effect of V(C, N) precipitation on α-ferrite phase transformation is mainly revealed in two aspects: (i) Precipitated V(C, N) particles act as inoculant particles to promote proeutectoid ferrite nucleation. (ii) Local carbon concentration along the γ-austenite grain boundaries is decreased with the precipitation of V(C, N), which in turn promotes α-ferrite precipitation.

      • Size control of Co-doped ZnO rods by changing the solvent

        Zhao, Jing,Yan, Xiaoqin,Lei, Yang,Zhao, Yanguang,Huang, Yunhua,Zhang, Yue Techno-Press 2012 Advances in materials research Vol.1 No.1

        In this work, the Co-doped ZnO rods were prepared by the hydrothermal method. The size of these rods can be changed from micro-size to nano-size by using different solutions during the preparation. The results of transmission electron microscopy (TEM) and selected area electron diffraction (SAED) showed that the as-prepared nano-sized Co-doped rods have single-crystal structure. The polarized Raman experiments were presented on an individual micro-sized Co-doped ZnO rod in the $X(YY)\vec{X}$, $X(ZY)\vec{X}$ and $X(ZZ)\vec{X}$ configurations, the results of polarized Raman indicated that these rods are crystallized and their growth direction is parallel to c-axis.

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