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Xueqin Zhang,Wencheng Tu,Meitian Xiao,Yongjun Liu,Jing Ye 한국물리학회 2017 Current Applied Physics Vol.17 No.10
A one-step approach was developed to prepare carbon covered alumina (CCA) material by using Al-based MOFs (Al-PCP) as sacrificial template. Pt/CCA nanoparticle catalysts were characterized by using XRD, TGA, XPS, N2 sorption, SEM, TEM and elemental analysis and revealed that they retained the mesostructure with high Pt dispersion and had a CCA structure. Moreover, after reduced at 800 C, Pt/CCA-800 afforded the highest enantiomeric excess (84.8%) after chirally modified with cinchonidine at the second time reaction and can be recycled for more than 8 times without distinct loss of activity or enantioselectivity in the asymmetric hydrogenation of ethyl 2-oxo-4-phenylbutyrate.
Cong Mao,Jie Zhang,Meitian Xiao,Yongjun Liu,Xueqin Zhang 한국물리학회 2018 Current Applied Physics Vol.18 No.12
Mesoporous carbon-silica composites supported Pt nanoparticle catalysts (Pt/MCS) were firstly applied to the heterogeneous asymmetric hydrogenation of ethyl 2-oxo-4-phenylbutyrate (EOPB). A series of different silica contents were investigated in the fabrication of this mesoporous material. When the volume of added tetraethyl orthosilicate (TEOS) during the preparation of composites is 8 mL, Pt/MCS-8 holds carbon and silica as the main components and possesses relatively strong acidity, mesoporous structures with micropores, appropriate Pt nanoparticle size and high dispersibility showing by XRD, XPS, TPD, N2 sorption and TEM. These properties cause its good catalytic performance in the heterogeneous asymmetric hydrogenation of EOPB with the enantiomeric excess value and conversion up to 85.6% and 97.8%, respectively.
Zou Yi,Changyou Han,Fang Wang,Yanhua Tan,Saina Yang,Chuying Huang,Shengyou Xie,Xueqin Xiao 한국식물학회 2021 Journal of Plant Biology Vol.64 No.2
Aloe vera L. is an excellent resource for medication. Selenium-enriched aloe can act as a functional food to human health. To understand the molecular mechanisms underlying selenium accumulation in Aloe vera L., we characterized the metabolic and transcriptome responses of aloe leaves under different Na2SeO4 levels (0, 200, and 400 mg/L) treatments. Aloe leaves spraying with exogenous selenium fertilizer showed a significant increase in total Se content compared with those under non-treatment control, and no distinct differences were observed between 200 and 400 mg/L Se treatment. Non-targeted metabolic profiling revealed that Se treatment triggered the accumulation of antioxidants, including amino acid and derivatives, phenols, flavonoids, terpene, as well as indole derivatives. Consistent with metabolic changes following Se treatment, the transcript level of genes involved in Se assimilation and Se-response showed dramatically increase, such as those encoding sulfate transporter, antioxidants, phytohormone signaling, transcription factors, and phenols metabolites, suggesting Se assimilation generally accompanied with antioxidant and pathogen defense. This study exhibited comprehensive insights on Se response in Aloe vera L., and provided us with targeted genes for genetic engineering, thereby improving the therapeutic value of aloe.