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        Polyethylenimine Grafted Chitosan Nanofiber Membrane as Adsorbent for Selective Elimination of Anionic Dyes

        Xinwen Gong,Dongxue Yang,Nannan Wang,Shian Sun,Jun Nie,Guiping Ma 한국섬유공학회 2020 Fibers and polymers Vol.21 No.10

        In order to improve the adsorption capacity of chitosan to organic dyes, the amino rich functionalized chitosanelectrospun nanofibers membrane was prepared. In the process of high efficiency synthesis, PGMA and PEI were grafted onthe surface of CS NFMs in turn. By means of XRD, ATR-FTIR and XPS, the successful introduction of amino group into CSwas confirmed. The selective adsorption capacity of CS-PGMA-PEI NFMs for anionic dyes was studied. The adsorptionkinetics analysis shows that the adsorption process of CS-PGMA-PEI NFMs is mainly pseudo second-order model. Itsadsorption isotherms can be described by the Langmuir model and it conforms to monolayer adsorption. The maximumadsorption capacity of Congo red calculated by Langmuir model is 657.47 mg/g. CS-PGMA-PEI NFMs has selectiveadsorption capacity for Congo red/methylene blue mixture. CS-PGMA-PEI NFMs also showed good circulation stability. This study provides a method for the synthesis of water purification membrane.

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