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Chen Ting,Liu Pengfei,Liu Tianxiao,Li Xueyuan,Wang Huihui,He Tingwei,Liu Zhiyong 한국물리학회 2024 Current Applied Physics Vol.58 No.-
Electron transport layer (ETL) plays an important role in perovskite solar cells (PSCs). In this paper, a stable and cheap metal chelating agent, subnitrotriacetic acid (NTA), was used to modify SnO2 ETL in two ways:1) By incorporating NTA into SnO2 colloidal dispersion, the oxygen vacancy causing charge recombination was greatly reduced, and the recombination of psc was reduced by reducing the introduction of surface Ovs, 2) Spin-coating NTA at the SnO2/perovskite interface not only manages a large number of oxygen vacancies generated by high-temperature annealing, but also interacts with the unpaired Pb2+ in the perovskite absorption layer by interface modification of the C=O bond in NTA, passivates the surface of the perovskite layer, inhibits ion migration, stabilize the perovskite structure, and avoid its collapse, while significantly reducing the defect state density. By inhibiting the shallow interface trap and reducing the non-radiative recombination, efficient and stable perovskite solar cells were prepared. Under the condition of relative humidity greater than 40 % (RH), the efficiency of perovskite solar cells prepared by interface-anchored NTA was increased to 22.6 %, and the stability was significantly enhanced.