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Ito, Eisuke,Arai, Takayuki,Hara, Masahiko,Noh, Jaegeun Korean Chemical Society 2009 Bulletin of the Korean Chemical Society Vol.30 No.6
Surface potential and growth processes of hexadecanethiol (HDT) self-assembled monolayers (SAMs) on Au(111) surfaces were examined by Kelvin probe method and scanning tunneling microscopy. It was found that surface potential strongly depends on surface structure of HDT SAMs. The surface potential shift for the striped phase of HDT SAMs chemisorbed on Au(111) surface was +0.45 eV, which was nearly the same as that of the flat-lying hexadecane layer physisorbed on Au(111) surface. This result indicates that the interfacial dipole layer induced by adsorption of alkyl chains is a main contributor to the surface potential change. In the densely-packed HDT monolayer, further change of the surface potential was observed, suggesting that the dipole moment of the alkanethiol molecules is an origin of the surface potential change. These results indicate that the work function of a metal electrode can be modified by controlling the molecular orientation of an adsorbed molecule.
Eisuke Ito,Takayuki Arai,Masahiko Hara,노재근 대한화학회 2009 Bulletin of the Korean Chemical Society Vol.30 No.6
Surface potential and growth processes of hexadecanethiol (HDT) self-assembled monolayers (SAMs) on Au(111) surfaces were examined by Kelvin probe method and scanning tunneling microscopy. It was found that surface potential strongly depends on surface structure of HDT SAMs. The surface potential shift for the striped phase of HDT SAMs chemisorbed on Au(111) surface was +0.45 eV, which was nearly the same as that of the flat-lying hexadecane layer physisorbed on Au(111) surface. This result indicates that the interfacial dipole layer induced by adsorption of alkyl chains is a main contributor to the surface potential change. In the densely-packed HDT monolayer, further change of the surface potential was observed, suggesting that the dipole moment of the alkanethiol molecules is an origin of the surface potential change. These results indicate that the work function of a metal electrode can be modified by controlling the molecular orientation of an adsorbed molecule.
Masayuki Sekine,Takayuki Enomoto,Masami Arai,Hiroki Den,Hiroyuki Nomura,Takeshi Ikeuchi,Seigo Nakamura 대한부인종양학회 2022 Journal of Gynecologic Oncology Vol.33 No.4
Objective: and mutation carriers are recommended to undergo risk-reducing salpingo-oophorectomy (RRSO) by age 40 and 45, respectively. However, the carriers have a different way of thinking about their life plan. We aimed to investigate the distribution of age at diagnosis of ovarian cancer (OC) patients to examine the optimal timing of RRSO in the carriers. Methods: We examined a correlation between age at diagnosis of OC and common mutation types in 3,517 probands that received genetic testing. Among them, germline mutation (g m), germline mutation (g m) and germline wild-type (g wt) were found in 185, 42 and 241 OC patients, respectively. Results: The average age at diagnosis of OC in g m and g m was 51.3 and 58.3 years, respectively, and the difference from g wt (53.8 years) was significant. Theg m carriers did not develop OC under the age of 40. The average age was 50.1 years for L63X and 52.8 years for Q934X in , and 55.1 years for R2318X and 61.1 years for STOP1861 in . The age at diagnosis in L63X or R2318X carriers was relatively younger than other or carriers, however their differences were not significant. With L63X and R2318X carriers, 89.4% (42/47) and 100% (7/7) of women were able to prevent the development of OC, respectively, when RRSO was performed at age 40. Conclusion: There appears to be no difference in the age at diagnosis of OC depending on the type of common mutation. Further analysis would be needed.
Sound change of /o/ in modern Seoul Korean
Igeta, Takako,Sonu, Mee,Arai, Takayuki 한국음성학회 2014 말소리와 음성과학 Vol.6 No.3
This article represents a first step in a large study aimed at elucidating the relationship between production and perception involved in sound change of /o/ in (Seoul) Korean. In this paper we present the results of a production study and a perception experiment. For the production study we examined vowel production data of 20 young adult speakers, measuring the first and second formants, then conducted a discriminant analysis based on those values. In terms of their F1-F2 values, the distribution of /o/ and /u/ were close, and even overlapping in some circumstances, which is consistent with the literature. This tendency was more apparent among the female speakers than the males. Moreover, with the females" distributions, /o/ was frequently categorized as /u/, suggesting that the direction of the sound change is indeed increasing from /o/ to /u/. Next, to investigate the effects of this proximity on perception, we used the production data of five randomly selected speakers from the production study as stimuli for a perception experiment in which 21 young adult native speakers of (Seoul) Korean performed a vowel identification task and provided a Goodness rating on a 5-point scale. We found that while rates of correctness were high, when these correctness scores were weighted by the Goodness rating, these “weighted correctness” scores were lower in some cases, indicating a degree of confusion in distinguishing between the two vowels.
Masatoshi Sato,Yoshiaki Kobayashi,Takayuki Kawamata,Yukio Yasui,Kazunori Suzuki,M. Itoh,Ryoichi Kajimoto,Kazuhiko Ikeuchi,M. Arai,Phillipe Bourges 한국물리학회 2013 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.62 No.12
To identify the superconducting symmetry of Fe-based superconductors, we studied effects ofnonmagnetic-impurities on Tc, magnetic excitation spectra 00 and NMR 1/T1 − T curve, whichare sensitive to the relative signs between the order parameters on the disconnected Fermi surfacesin reciprocal space, because the symmetry is closely connected with the pairing mechanism:If the signs are opposite (symmetry S±), the mechanism is considered to be a magneticone, but when the signs are the same (symmetry S++), a novel mechanism is plausible becausethe ordinary phonon mechanism cannot realize the Tc value as high as 55 K found in Ln1111(Ln=lanthanide). Results are as follows: (a) The very small rates of Tc-suppression by impurityatoms M of LnFe1−yMyAs0.89−xF0.11+x (M=Ni, Co, Ru) can be explained only by S++. (b) The00-data for Ba(Fe, Co)2As2 (Tc 23 K) and Ca-Fe-Pt-As crystals seem to be well explained byS++ rather than by S±. (c) The nuclear magnetic resonance data can be consistently understoodby S++, too. These results suggest the S++ symmetry and a novel pairing mechanism, which canbe considered to be related to the elastic softening of C66 induced by the orbital fluctuation of thesystem.
Overlapping of /o/ and /u/ in modern Seoul Korean
Takako Igeta,Sadao Hiroya,Takayuki Arai 한국음성학회 2017 말소리와 음성과학 Vol.9 No.1
Previous studies have reported on the overlapping of F₁ and F₂ distribution for the vowels /o/ and /u/ produced by young Korean speakers of the Seoul dialect. It has been suggested that the overlapping of /o/ and /u/ occurs due to sound change. However, few studies have examined whether speech rate influences the overlapping of /o/ and /u/. On the other hand, previous studies have reported that the overlapping of /o/ and /u/ in syllable produced by male speakers is smaller than by female speakers. Few reports have investigated on the overlapping of the two vowels in read speech produced by male speakers. In the current study, we examined whether speech rates affect overlapping of /o/ and /u/ in read speech by male and female speakers. Read speech produced by twelve young adult native speakers of Seoul dialect were recorded in three speech rates. For female speakers, discriminant analysis showed that the discriminant rate became lower as the speech rate increases from slow to fast. Thus, this indicates that speech rate is one of the factors affecting the overlapping of /o/ and /u/. For male speakers, on the other hand, the discriminant rate was not correlated with speech rate, but the overlapping was larger than that of female speakers in read speech. Moreover, read speech by male speakers was less clear than by female speakers. This indicates that the overlapping may be related to unclear speech by sociolinguistic reasons for male speakers.