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        Effect of glycidyl methacrylate-grafted poly(ethylene octene) on the compatibility in PLA/PBAT blends and films

        Ye Zhang,Shiling Jia,Pan Hongwei,Lijuan Wang,Junjia Bian,Yang Guan,Bohao Li,Huiliang Zhang,Huili Yang,Lisong Dong 한국화학공학회 2021 Korean Journal of Chemical Engineering Vol.38 No.8

        A series of poly(lactic acid) (PLA), poly(butylene adipate-co-terephthalate) (PBAT) and glycidyl methacrylate- grafted poly(ethylene octene) (GPOE) blends and films with different GPOE content were prepared by melt blending and blowing film technique. The effect of GPOE on the rheological behavior, melt strength, crystallization behavior, crystallization morphology, miscibility, mechanical property, phase morphology, thermal stability and water vapor permeability were studied. The addition of GPOE improved melt rheological properties. Results of DSC showed that addition of GPOE encouraged the mobility of PLA molecular chains and enhanced crystalline ability. POM observations revealed that the addition of GPOE made the density of spherulite nucleation increase and the size of crystalline particles decrease. From DMA and SEM analysis, it was demonstrated that PLA/PBAT blend was an immiscible system and GPOE in the blend could improve compatibility between PLA and PBAT. Results of mechanical test showed that the PLA/PBAT/GPOE blends and films obtained had excellent mechanical properties. The elongation at break of 50/30/ 20 w/w/w PLA/PBAT/GPOE blend (477%) was higher by about 2.2 times than that of 70/30/0 w/w/w PLA/PBAT/ GPOE blend (220%). The tensile strength of all the PLA/PBAT/GPOE blends exceeded 31 MPa. The tensile strength reached 32.9MPa (MD) and 22.5MPa (TD), the elongation at break exceeded 210% and tear strength exceeded 140 kN/m for 50/30/20 w/w/w PLA/PBAT/GPOE film. With increasing GPOE content, thermal stability and water vapor barrier property also improved.

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        Constructing foldable cylindrical surfaces via unfolded waterbomb origami units

        Zhao Yan,Wei Yinglei,Jia Yiyang,Li Shiling,Zhang Mingyue,Zeng Lanling,Yang Yang,Mitani Jun 한국CDE학회 2022 Journal of computational design and engineering Vol.9 No.4

        Origami tessellations have shown the potential to be utilized for approximating curved target surfaces by folding a set of elemental units. As those units are in partially folded states, the origami approximation captures the outline of the target while demonstrating a corrugated surface. In this paper, we focus on the cylindrical surface and propose a method for constructing its discrete version via square or rectangular units with crease patterns inspired by the waterbomb tessellation. We unify the unit size through optimization to realize cost-efficient constructions. Three-dimensional curved structures are deployed by folding collinear creases between adjacent rows of units and the other creases in each row are remained unfolded. The deployed structure can still be folded to a compact state by folding all creases. To flexibly approximate the outline of the target surface, we analyse relationships between the width and height of the rectangular unit and utilize variations of the waterbomb tessellation to control the region of the origami structure when fully folded. The proposed method provides a novel solution to the so-called inverse-origami-design problem for generating foldable cylindrical surfaces using unfolded waterbomb origami units.

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