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      • KCI등재

        Photooxidation Properties of Photosensitizer/Direct Dye Patterned Polyester/Cotton Fabrics

        Wangbingfei Chen,Weiwei Wang,Xiaodong Ge,Qufu Wei,Reza Arman Ghiladi,Qingqing Wang 한국섬유공학회 2018 Fibers and polymers Vol.19 No.8

        Towards the goal of developing anti-infective textiles based on a photodynamic inactivation mechanism, here we present the design, dyeing procedure, characterization, substrate photooxidation studies, and antibacterial efficacy of methylene blue-dyed polyester fabrics, termed MB-polyester. Dye-uptake and apparent K/S (absorption and scattering coefficient) values as a function of MB concentration % (o.w.f) were determined, and were found to correlate. Photooxidation studies employing the model substrate 1,5-dihydroxynaphthalene (1,5-DHN) revealed that the MB-polyester fabrics were able to generate singlet oxygen in an illumination time-dependent manner. Antibacterial efficacy was evaluated against Staphylococcus aureus (ATCC-29213), with our best results achieving a 99.89 % (~3 log units) reduction in Colony-Forming Units (CFU)/mL after only 30 min illumination (Xenon lamp, 3500 mW/cm2, 420-780 nm). On the basis of these results with MB-polyester, we subsequently designed patterned dual-dyed polyester/cotton fabrics, wherein an alternating pattern of MBdyed polyester was combined with direct dyes-dyed cotton, and showed that their ability to sensitize singlet oxygen (1O2) in the photooxidation reaction of 1,5-DHN was maintained. Taken together, these findings suggest that MB is a suitable photosensitizer (PS) against S. aureus for the practical development of low-cost polyester-based antimicrobial textiles, and can potentially be used in the production of diverse form-patterned textiles that possess a photodynamic antimicrobial inactivation mechanism.

      • KCI등재

        Laccase Biosensor Based on Ag-Doped TiO2 Nanoparticles on CuCNFs for the Determination of Hydroquinone

        Jie Yang,Dawei Li,Zengyuan Pang,Qufu Wei 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2016 NANO Vol.11 No.12

        A novel nanomaterial composed of copper and carbon nanofibers (CuCNFs) decorated with Agdoped TiO2 (Ag–TiO2) nanoparticles was prepared through electrospinning, carbonization and solvothermal treatment. The composites were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and electrochemical impedance spectroscopy (EIS). The obtained composites were mixed with laccase and Nafion to construct novel hydroquinone biosensor. The electrochemical behavior of the novel biosensor was studied using cyclic voltammetry (CV) and chronoamperometry. The results demonstrated that the biosensor possessed a wide detection linear range (1.20–176.50 µM), a good selectivity, repeatability, reproducibility and storage stability. This work provides a new material to design more efficient laccase (Lac) based biosensor for hydroquinone detection.

      • KCI등재

        Fluorescent Nitrogen-Doped Carbon Dots via Single-Step Synthesis Applied as Fluorescent Probe for the Detection of Fe3+ Ions and Anti-Counterfeiting Inks

        Chonghui Fan,Kelong Ao,Pengfei Lv,Jiancheng Dong,Di Wang,Yibing Cai,Qufu Wei,Yang Xu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.08

        Fluorescent nitrogen-doped carbon dots (N-CDs) with excellent stability were prepared via single-step hydrothermal carbonization of citric acid (CA) and ethylenediamine (EDA). The as-prepared N-CDs emit blue fluorescence under the excitation of 365 nm and have a size distribution of 2.80 ffi 0.47 nm with benign size effect. The structure and morphology were further characterized by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) spectroscopy. It was found that the surface of the N-CDs was successfully functionalized, which presented water solubility and chelation with Fe3+. XRD results display a diffraction peak at 23.9 ℃, which corresponds to the (002) interlayer spacing of a graphitic structure revealing an amorphous carbon phase. Furthermore, due to good sensitivity, N-CDs were used as probes for Fe3+ detection. The low limit of detection of 0.6 μM as a fluorescence probe was successfully obtained based on the linear relationship between (F0 - F) / F0 and concentration of Fe3+ ions. Besides the satisfactory fluorescence, PVA/N-CDs membranes and fluorescent inks demonstrate potential for anti-counterfeiting applications due to its characteristic flexibility, transparency, removability and invisibility under ambient lighting.

      • KCI등재

        Graphene Oxide/Polyester Fabric Composite by Electrostatic Self-Assembly as a New Recyclable Adsorbent for the Removal of Methylene Blue

        Di Wang,Dawei Li,Pengfei Lv,Qingqing Wang,Yang Xu,Qufu Wei 한국섬유공학회 2018 Fibers and polymers Vol.19 No.8

        A novel graphene oxide/polyester (GO/PET) composite fabric as a recyclable adsorbent was prepared via electrostatic self-assembly. The structure, morphology, and properties of the GO/PET composite fabrics were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), Fourier transformed infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and contact angle (CA), respectively. The absorption property was evaluated by the absorption amount and removal efficiency of methylene blue (MB) solution on the GO/PET composite fabric. The results indicated that the absorption amount was found to be 21.80 mg/g and the removal efficiency reached 99.93 % under the experimental conditions of GO concentration of 2 mg/ml, initial concentration of 50 mg/l, and area of 64 cm2. The experimental parameters were investigated including the concentration of GO, the initial concentration of MB solutions, and adsorbent area. Simultaneously, according to a series of dynamic analysis, the absorption process revealed that the kinetics was well-described by pseudo-second-order model. This study showed that the GO/PET composite fabric could be a recyclable, efficient adsorbent material for the environmental cleanup.

      • KCI등재

        3-D Deformation Behavior Simulation of Cable Stitch Based on Particle System in Weft Knitted Fabrics

        Sha Sha,Lei Luo,Zhongmin Deng,Dapeng Yuan,Bin Li,Xuewei Jiang,Hui Tao,Qufu Wei 한국섬유공학회 2018 Fibers and polymers Vol.19 No.9

        The static simulation of weft knitting can be efficiently realized by graphics simulation techniques, but there still remains a challenge for mechanical models. The lack of practical mechanical models significantly limit the realistic deformation behaviors of complex cable stitches, which lead to a great different between the simulation effect and the actual fabric. In order to obtain the deformation behavior and volumetric performance of cable stitch, loop models were built based on an improved particle system in this work. Compared with plain weft knitted, the offset value of bonding points of cable stitches were measured. By analyzing the relationship between the deformation of loops and the displacement of the particles, the deformation behavior of cable stitch was simulated. Velocity-Verlet integration was introduced to simulate cable stitches and the stable results were obtained. The results show that these models and algorithm displayed the accurate deformation behavior of cable stitches, as demonstrated by qualitative comparisons to measure the deformations of actual samples.

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