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Caprolactam Synthesis using Ce-MCM-41Catalysts
Cadiam Mohan Babu,Rajangam Vinodh,Aziz Abidov,Rramaswamy Ravikumar,Mei Mei Peng,Wang Seog Cha,Hyun Tae Jang 보안공학연구지원센터 2016 International Journal of Bio-Science and Bio-Techn Vol.8 No.3
Siliceous MCM-41 was synthesized by hydrothermal method using sodiummetasilicate as a source. Cerium ion incorporated Si-MCM-41 was synthesized by hydrothermal method using Cetyltrimethylammonium bromide as template. 2, 3 and 4 weight percentage of Ceria was loaded over MCM-41 by wet impregnation method. The synthesized catalysts were characterized using FT-IR, DRS-UV-Vis, XRD and SEM techniques. The catalytic activity of the cerium ion incorporated and ceria impregnated MCM-41 was evaluated in the synthesis of caprolactam from cyclohexanone oxime in the liquid phase condition. At high temperature all the catalyst showed high conversion. In that 4 wt.% Ce impregnated Si-MCM-41 produced high conversion (76.2%) and percentage yield (66.4%). The impregnated catalyst may contain more number of cerium present in the pores, so the lewis acid sites will be more and the conversion of cyclohexanone oxime into caprolactam will be high.
HYBRID NVH DESIGN SENSITIVITY ANALYSIS OF GENERAL CROSS-SECTION BEAMS
Semyung Wang,Mohan Godse 한국자동차공학회 1998 한국자동차공학회 춘 추계 학술대회 논문집 Vol.1998 No.5_2
This paper presents a hybrid process for design sensitivity analysis(DSA) of Noise, Vibration, and Harshness (NVH) responses with respect to general cross-section beam design parameters. Design parameters associated with general cross-section beams are overall height, overall width, and part thicknesses. In the hybrid process, NVH design sensitivities are computed using the chain rule of differentiation combining sizing and shape DSA results to get the total derivative. The beam design sensitivity expressions are analytically derived using the continuum approach and the adjoint variable method. NVH DSA is implemented external to the FEA program, MSC/NASTRAN. A simplified box model is used to validate and illustrate the approach.<br/>
FABRICATION OF NANOPOROUS CHITOSAN MEMBRANES
XIAOLIANG WANG,XIANG LI,ELEANOR STRIDE,MOHAN EDIRISINGHE 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2010 NANO Vol.5 No.1
Naturally derived biopolymers have been widely used for biomedical applications such as drug carriers, wound dressings, and tissue engineering scaffolds. Chitosan is a typical polysaccharide of great interest due to its biocompatibility and film-formability. Chitosan membranes with controllable porous structures also have significant potential in membrane chromatography. Thus, the processing of membranes with porous nanoscale structures is of great importance, but it is also challenging and this has limited the application of these membranes to date. In this study, with the aid of a carefully selected surfactant, polyethyleneglycol stearate-40, chitosan membranes with a well controlled nanoscale structure were successfully prepared. Additional control over the membrane structure was obtained by exposing the suspension to high intensity, low frequency ultrasound. It was found that the concentration of chitosan/surfactant ratio and the ultrasound exposure conditions affect the structural features of the membranes. The stability of nanopores in the membrane was improved by intensive ultrasonication. Furthermore, the stability of the blended suspensions and the intermolecular interactions between chitosan and the surfactant were investigated using scanning electron microscope and Fourier transform infrared spectroscopy (FTIR) analysis, respectively. Hydrogen bonds and possible reaction sites for molecular interactions in the two polymers were also confirmed by FTIR analysis.
Preparation and characterization of RGO‑incorporated hypercross‑linked polymers for CO2 capture
Rajangam Vinodh,Cadiam Mohan Babu,Aziz Abidov,Muthiahpillai Palanichamy,Wang Seog Cha,Hyun Tae Jang 한국탄소학회 2019 Carbon Letters Vol.29 No.1
The growing demand for nano-structured composite materials and sustainable processes for next generation CO2 capture technologies has necessitated the need to develop novel and cost-effective synthetic routes for solid CO2 adsorbents based on hypercross-linked polymers (HCPs) and reduced graphene oxide (RGO) microporous sorbent materials with improved physico-chemical properties. The most important selection is modification of the synthesized microporous sorbent materials by the incorporation of RGO, giving rise to composite materials that combine the properties of both. These hybrid materials will be of great potential for carbon capture and storage (CCS) applications, especially for post-combustion CO2 capture, owing to the increase in CO2 capturing efficiency and selectivity to CO2 compared to other flue gases. Herein, we report a facile and effective approach for fabrication of HCPs-supported reduced graphene oxide composites. The microporous HCPs was synthesized using 4,4′-bis(chloromethyl)-1,1′-biphenyl monomer by Friedel–Crafts alkylation. The RGO was prepared by modified Hammers method. The as-synthesized composites were characterized by TEM, SEM, FTIR, TGA and N2 adsorption–desorption isotherm. The HCP/RGO composite showed maximum CO2 adsorption of 5.1 wt% than the HCPs alone at 40 °C and 1 atm.