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      • KCI등재

        Preparation and In-Vitro Release Performance of Geranium Wilfordii Maxim Filled Biodegradable Microcapsules

        Mengxuan Li,Rui Wang,Xing Liu 한국고분자학회 2017 폴리머 Vol.41 No.3

        Encapsulation of Geranium wilfordii Maxim (GWM) into polyvinyl alcohol (PVA) biodegradable microcapsules was performed using the interfacial polymerization method. The optimum synthesis conditions including the core/shell ratio and the emulsifier concentration were explored. The fabricated microcapsules were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The in-vitro release behaviour of the GWM microcapsules was studied by ultraviolet-visible spectroscopy (UV-VIS). The results show that when the core/shell ratio was 1:1 and the emulsifier concentration was 5%, the GWM microcapsules sizes have a normal distribution with a mean diameter of 23.94 μm. FTIR results show that the GWM was successfully encapsulated by the PVA polymer. TG results indicate that the GWM microcapsules are stable below 300℃. Moreover, the release from the GWM microcapsules occurs according to a non-Fickian diffusion model.

      • KCI등재

        Effect of glass cooling rate on the crystallization behavior and structure of Al2O3-SiO2-Na2O-CaF2 oxyfluoride glass-ceramics

        Mengxuan Li,Jinxin Zou,Guangping Guo,Jianxiang Liu,Guicheng Wang 한양대학교 세라믹연구소 2021 Journal of Ceramic Processing Research Vol.22 No.5

        The glass cooling rate during molding process has significant effect on the crystallization behavior and structural uniformityof Al2O3-SiO2-Na2O-CaF2 oxyfluoride glass-ceramics. Abaqus Finite Element Analysis indicated that at room temperaturecooling environment, the cooling rate of 8mm thick glass was notably lower than that of 3 mm thick glass. The interiortemperature of 8 mm thick precursor glass was still above 710 oC even after the sample was cooled for 15 s, which caused theformation of “crystal stones” in precursor glass. The microstructure of oxyfluoride glass and glass-ceramics with differentthickness was analyzed by using DTA, XRD, IR and SEM. Since the 8 mm thick glass was cooled slowly, the initial crystalnucleation generated in the interior of glass, mixed crystal phases were formed in the interior after heat treatment, while singleCaF2 crystal phase formed on the surface. On the contrary, there was only uniform CaF2 crystal phase generating in the 3mm thick precursor glass after heat treatment, as a result of high cooling rate during molding process. Besides, the mechanismand ways to optimize the structure uniformity of glass ceramics were also be discussed.

      • KCI등재

        Parameter identification of the phenomenological model for magnetorheological fluid dampers using hierarchic enhanced particle swarm optimization

        Jin Guo,Zhendong Li,Mengxuan Zhang 대한기계학회 2021 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.35 No.3

        The magnetorheological (MR) fluid damper, as a new generation of highperformance and intelligent vibration damping devices for engineering structures, has broad application prospects in structural vibration reduction. Nonlinear hysteresis is a complex phenomenon of MR dampers. In this paper, the phenomenological model is used to simulate the dynamics of MR dampers. To accurately and efficiently identify the parameters of the phenomenological model, the hierarchical enhanced particle swarm optimization (HEPSO) algorithm is proposed. This algorithm applies a hierarchical optimization mechanism and introduces media particles to the enhanced PSO (EPSO) algorithm to improve the optimization process of parameter identification and enhance the performance of the PSO algorithm without reducing the possibility of finding the optimal solution. Compared with the standard PSO (SPSO) algorithm and the EPSO algorithm, the HEPSO algorithm has a higher efficiency, accuracy and robustness in identifying a highly nonlinear hysteretic system problem.

      • SCOPUSKCI등재

        Ni/ZnO-based Adsorbents Supported on Al<sub>2</sub>O<sub>3</sub>, SiO<sub>2</sub>, TiO<sub>2</sub>, ZrO<sub>2</sub>: A Comparison for Desulfurization of Model Gasoline by Reactive Adsorption

        Meng, Xuan,Huang, Huan,Weng, Huixin,Shi, Li Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.10

        Reactive adsorption desulfurization (RADS) experiments were conducted over a series of commercial metal oxide supports ($Al_2O_{3-}$, $SiO_{2-}$, $TiO_{2-}$ and $ZrO_{2-}$) supported Ni/ZnO adsorbents. The adsorbents were characterized by X-ray diffraction (XRD), temperature programmed reduction (TPR), and Fourier transform infrared spectroscopy (FTIR) in order to find out the influence of specific types of surface chemistry and structural characteristics on the sulfur adsorptive capacity. The desulfurization performance of all the studied adsorbents decreased in the following order: Ni/ZnO-$TiO_2$ > Ni/ZnO-$ZrO_2$ > Ni/ZnO-$SiO_2$ > Ni/ZnO-$Al_2O_3$. Ni/ZnO-$TiO_2$ shows the best performance and the three hour sulfur capacity can achieve 12.34 mg S/g adsorbent with a WHSV of $4h^{-1}$. Various characterization techniques suggest that weak interaction between active component and support component, high dispersion of NiO and ZnO, high reducibility and large total Lewis acidity of the adsorbents are important factors in achieving better RADS performance.

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