Phosphorus Removal in Pilot Plant Using Biofilm Filter Process from Farm Wastewater

차월석,Sung-Euy Shin,DuBok Choi,Choon-Boem Lee 한국생물공학회 2006 Biotechnology and Bioprocess Engineering Vol.11 No.4

Various environmental conditions affecting total phosphorus removal from farm wastewater in a biofilm filter process were investigated using loess balls and Chromobacterium LEE-38 at a pilot plant. When Chromobacterium LEE-38 was used, the removal efficiency of total phosphorous was approximately 10- or 5-fold higher than that of Acinetobacter CHA-2-14 or Acinetobacter CHA-4-5, respectively. When a loess ball of 11~14 mm manufactured at a 960°C calcining temperature was used, the removal efficiency of total phosphorous was 90.0%. When 70% of the volume fraction was used, the maximum efficiency of total phosphorus removal was 93.1%. Notably, when the initial pH was in the range of 6.0 to 8.0, the maximum removal efficiency of total phosphorus was obtained after 30 days. When the operating temperature was in the range of 30 to 55°C, the maximum removal efficiencies of total phosphorus, 95.6 to 94.6%, were obtained. On the other hand, at operating temperatures below 20°C or above 40°C, the removal efficiency of total phosphorous decreased. Among the various processes, biofilm filter process A gave the highest removal efficiency of 96.4%. Pilot tests of total phosphorus removal using farm wastewater from the biofilm filter process A were carried out for 60 days under optimal conditions. When Acinetobacter sp. Lee-11 was used, the average removal efficiency in the p-adsorption area was only 32.5%, and the removal efficiencies of chemical oxygen demand (COD) and biological oxygen demand (BOD) were 56.7 and 62.5%, respectively. On the other hand, when Chromobacterium LEE-38 was used, the average removal efficiency was 95.1%, and the removal efficiencies of COD and BOD were 91.3 and 93.2%, respectively.

Phosphorus Removal in Pilot Plant Using Biofilm Filter Process from Farm Wastewater

Shin, Sung-Euy,Choi, Du-Bok,Lee, Choon-Boem,Cha, Wol-Suk The Korean Society for Biotechnology and Bioengine 2006 Biotechnology and Bioprocess Engineering Vol.11 No.4

Various environmental conditions affecting total phosphorus removal from farm wastewater in a biofilm filter process were investigated using loess balls and Chromobacterium LEE-38 at a pilot plant. When Chromobacterium LEE-38 was used, the removal efficiency of total phosphorous was approximately 10- or 5-fold higher than that of Acinetobacter CHA-2-14 or Acinetobacter CHA-4-5, respectively. When a loess ball of $11{\sim}14mm$ manufactured at a $960^{\circ}C$ calcining temperature was used, the removal efficiency of total phosphorous was 90.0%. When 70% of the volume fraction was used, the maximum efficiency of total phosphorus removal was 93.1%. Notably, when the initial pH was in the range of 6.0 to 8.0, the maximum removal efficiency of total phosphorus was obtained after 30 days. When the operating temperature was in the range of 30 to $55^{\circ}C$, the maximum removal efficiencies of total phosphorus, 95.6 to 94.6%, were obtained. On the other hand, at operating temperatures below $20^{\circ}C$ or above $40^{\circ}C$, the removal efficiency of total phosphorous decreased. Among the various processes, biofilm filter process A gave the highest removal efficiency of 96.4%. Pilot tests of total phosphorus removal using farm wastewater from the biofilm filter process A were carried out for 60 days under optimal conditions. When Acinetobacter sp. Lee-11 was used, the average removal efficiency in the p-adsorption area was only 32.5%, and the removal efficiencies of chemical oxygen demand (COD) and biological oxygen demand (BOD) were 56.7 and 62.5%, respectively. On the other hand, when Chromobacterium LEE-38 was used, the average removal efficiency was 95.1%, and the removal efficiencies of COD and BOD were 91.3 and 93.2%, respectively.

Loess ball에 의한 총질소 제거에 관한 연구

신성의,이춘범,차월석,Shin Sung-Euy,Lee Choon-Boem,Cha Wol-Suk 한국생명과학회 2005 생명과학회지 Vol.15 No.4

황토볼을 담체로 사용하여 혐기조${\rightarrow}$호기조${\rightarrow}$무산소조의 순서로 진행되는 폐수처리 시스템(F-STOP PROCESS)에서 폐수의 조성이 COD 200, 총질소 40 (ppm)정도의 합성폐수를 처리하여 다음과 같은 결론을 얻었다. 총질소 성분의 평균 제거율은 $83.0\%$이였으며, 암모니아성 질소는 평균 제거율이 $84.4\%$이였다. 또한 질산성 질소는 호기조의 평균 질산화율은 $60.2\%$이였는데 유출수의 pH범위가 $4.8\~6.0$인 것을 고려하면 양호한 결과를 보였으며, 무산조의 질산성 질소의 제거율은 $96.3\%$으로 상당히 좋은 결과를 보이고 있다. 최종 방류조의 유출수 COD는 12.8ppm으로 평균 제거율 $93.6\%$이였으며, SS의 경우에는 평균발생량은 7.0ppm이였다. 이러한 결과치는 하수종말처리장(특별대책지역 및 잠실수중보권지역) 기준 및 폐수처리시설(농공단지 오 폐수처리시설 포함) 기준 이내의 기준에 해당하는 영양염류의 수치로 양호한 결과를 보여주었다. 그러나 이러한 결과를 유지하기 위해서는 폐수성상에 따른 시스템 순서의 변경, 비정상상태에서 정상운전에 이르는데 요구되는 시간을 줄이는 것 등이 관건으로 되어 있으며, 향후 이러한 방향으로 보다 연구가 진행되어야할 필요성이 있다. In this study, the wastewater treatment was conducted to evaluate the removal efficiency of total nitrogen from synthetic wastewater in the F-STEP PROCESS $(anaerobic{\rightarrow}\;oxic\;{\rightarrow}\;anoxic)$ with loess ball as support metrics. The average removal efficiencies of total nitrogen and ammonia nitrogen were $83.0\%\;and\;84.4\%$, respectively. The average nitrification efficiency at the oxic area was $60.9\%$ in the pH range of effluent water between 4.8 and 6.0. On the other hand, in the case of pH range of effluent water between 6.5 and 7.5, the denitrification efficiency at the anoxic area was $96.3\%$. The average concentration of COD was 12.8 ppm and the removal efficiency of COD in the F-STEP PROCESS were $96.3\%$. In the case of SS, the average concentration was $7.0\%$ at the effluent.

Optimization for Phosphorus Remove by Loess Ball Using Chromobacterium

최두복,이춘범,차월석,Choi Du Bok,Lee Choon-Boem,Cha Wol-Suk Korean Society of Life Science 2005 생명과학회지 Vol.15 No.4

담체인 황토볼와 Chromobacterium WS 2-14을 이용하여 F-STEP공정(혐기${\rightarrow}$ 호기${\rightarrow}$ 무산소)에서 실제폐수에 존재하는 인산을 효율적으로 제거하기 위해 최적 황토볼 크기 및 소성 온도, 폐수의 초기 pH,폐수의 초기 인산염 농도, 운전온도, 그리고 통기를 검토했다. 최적 조건은 다음과 같다. 황토볼 크기 및 소성 온도, $2\~4mm,\;960^{\circ}C$; 실페수의 초기pH, 6.0; 실페수의 초기 인산 농도, 5.0mg/1. 운전온도, $30^{\circ}C$; 그리고 통기, 5.0L/min등이 얻어졌다. 그리고 최적 운전조건을 이용해서 pilot test을 65일 동안 진행했다. 인산 평균 제거율은 $92.0\%$였고. 또한 최종 유출수에서 COD와 BOD의 평균 제거율은 각각 77.1와 $74.2\%$였으며, SS의 경우는 평균 제거율이, $86.4\%$였다. 이상의 결과로부터 황토볼을 담체로 이용한 Biofilter System은 실제폐수에 존재하는 인산 제거 가능성을 암시했다. To investigate factors affecting the removal of phosphorus from the practical wastewater in the F-STEP PROCESS using a loess ball and Chromobacterium WS 2-14, first, the loess ball size and calcining temperature, initial pH, initial phosphorus concentration, working temperature, and aeration were studied. A $2\~4mm$ of loess ball made at $960^{\circ}C$ of calcining temperature was the most suitable one for the removal of phosphorus. When the initial pH was increased from 3.0 to 6.0, the removal efficiency of phosphorus was increased. Especially, at 6.0 of initial pH, the maximum removal efficiency of phosphorus was $88.7\%$. The maximum removal efficiency of phosphorous was gained, 1.8mg/h when the initial concentration of phosphorous was 5.0mg/1. When the operating temperature was $30^{\circ}C$, the maximum removal efficiency of phosphorus was obtained. In the case of aeration, when it was increased from 0.5 to 5.0L/min, the removal efficiency of phosphorus was increased. On the other hand, above 7.0 L/min, the removal efficiency of phosphorus did not increased. Using the optimum operation conditions, pilot tests for the effective removal efficiency of phosphorus were carried out for 65 days. The average removal efficiency of phosphorus was $92.0\%$. The average removal efficiency of COD, BOD, and SS were 77.1, 74.2, and $86.4\%$, respectively. from the results, it can be concluded that F-STEP PROCESS using loess ball might be useful process for phosphorus removal.