우라늄 이온(UO_2^2+) - 초분자 화학센서

고광락,McStay, D.,엄년식,강신원 경북대학교 센서기술연구소 1997 연차보고서 Vol.1997 No.-

본 연구는 표면 플라즈몬 공명 현상을 이용한 우라늄 (UO_2^2+) - 초분자 화학센서시스템의 기초적 개발에 대한 것으로, 크게 표면 플라즈몬 공명형 센서 시스템의 간단한 구축과 구성된 센서 시스템의 기초 특성 및 우라늄 이온 감지 특성 평가에 대한내용으로 수행되었다. 특히 우라닐 이온 감지 특성에서, 우라닐 이온의 선택적 감지물질인 수용성 calix[6] arene이 함유된 감지막을 사용하여 수용액 상태에서 우라닐 이온의 감지정도를 측정해 본 결과 calix[6] arene이 함유되지 않은 감지막에 비해 플라즈몬 공명각의 변화량이 약 5.5 배 커짐을 볼 수 있었고, 10^-7 ∼ 10^-11 M의 저농도 우라닐 이온을 함유한 수용액을 농도별로 제조하여 공명특성을 측정한 결과 decade 농도당 공명각 변화량이 0.145°로 감도가 비교적 높았으며 빠른 응답특성도 함께 볼 수 있었다. This project was basic studies for the constructing the uranium ion - supramolecular chemosensor system using SPR (surface plasmon resonance) phenomenon. We constructed a simple SPR sensor system and measured the characterization of the sensing chip and uranyl ion detecting with this system. On uranyl ion sensing In solution state, especially, the use of sensing matrix interface with very well-known receptor for uranyl ion (calix[6]arene) and polymer composite matrix amplified resonance angle shift of the constructed SPR system. This amplified signal is about 5.5 times greater than the case of using simple polymeric matrix without calix[6]arene as a sensing interface. Also the linear resonance angle shift was observed in the range of very low uranyl ion concentration from 10 to 10 M. The sensitivity (resonance angle shift per uranyl concentration decade) was relatively high as 0.145° and the response time was similar to almost measurement moment.

광섬유 ROTDR 센서를 이용한 사회기반시설물의 보안에 관한 연구

박형준,고광락,권일범 한국비파괴검사학회 2003 한국비파괴검사학회지 Vol.23 No.2

광섬유 ROTDR(Rayleigh optical time domain reflectometry) 센서를 이용하여 중요 보안 대상체인 사회기반시설물에 침투하는 침입자의 위치와 무게 정도를 탐지할 수 있는 기초 연구를 수행하였다. 넓은 면적을 감지할 수 있는 매설형 광섬유 센서탐지판을 제작하고, 인가된 침입물체의 위치와 무게에 따른 신호특성을 고찰하였다. ROTDR 센서는 펄스 폭이 30 ㎱이고, 광섬유의 길이는 10㎞ 이상이다. 위치탐지오차는 약 3m 이내였으며, 무게에 따른 탐지능력은 20kgf, 40kgf, 60kgf의 세단계를 구분할 수 있음을 알 수 있었다. A detection technique is studied to determine the location and the weight of an intruder into infrasturcture using fiber optic ROTDR(Rayleigh optical time domain reflectometry) sensor. Fiber optic sensing plates buried in sand are prepared to measure the intruder effects. The signal of ROTDR was analyzed to confirm the detection performance. The constructed ROTDR system could be used up to 12 ㎞ at the pulse width of 30 ㎱. The location error was less than 3 m and the weight could be detected into three levels of grade, such as 20 kgf, 40 kgf and 60 kgf.

Optode형 glucose 센서의 개발

강신원,고광락,이수미,김수진 경북대학교 센서기술연구소 1997 연차보고서 Vol.1997 No.-

인간의 미각은 단맛 (甘味, sweet taste), 신맛 (酸味, sour taste), 짠맛(鹽味, saline taste), 쓴맛 (苦味, bitter taste)의 4가지 기본요소와 우마미 (Umami)^1)로 이루어져 있다. 본 연구에서는 그 중 글루코오스를 감지할 수 있는 당도 (糖度)센서인 초보적인 미각센서의 개발을 위하여 광섬유를 이용한 optode형의 센서소자를 제작하여 glucose의 농도 1×10 exp (-7) ∼ 1×10 exp (-2) M의 범위에 대해 측정하였다. 본 센서의 측정원리는 광섬유를 통한 광의 전달시 감지막의 글루코오스에 대한 반응에 따른 흡광 특성에 의해 일어나는 출력광의 감소 즉, 소산파의 흡수를 측정하는 원리를 이용하였다. The taste is composed of five fundamental tastes, sweet, sour, saline, bitter taste and umami. This research purposed to develope a glucose sensor, sweet taste sensor. The glucose sensor device used five kinds of dye/PMMA polymer sensing membranes containing five dyes. All experiment processor is based on the pH 7.4, 0.05 M tris-HCl buffer solution and glucose concentration from 1×10 exp (-7) to 1×10 exp (-2) M range. The fiber optode of the sensor device is made of skipped cladding in the fiber's middle site and then coated by dye/PMMA membrane. The principle of the sensor is based on the absorbance change of the evanescent wave of the sensing membrane according to glucose concentration change. In this experiments, we made a response pattern of the glucose sensor system using the evanescent wave.

pH-LAPS의 제작 및 그 특성

장수원,고광락,강신원 경북대학교 센서기술연구소 1997 센서技術學術大會論文集 Vol.8 No.1

A silicon-based light addressable potentiometric sensor (LAPS) to detect the pH changes was developed. The pH-LAPS structure is Si_(3)N_(4)/SiO_(2)/Si layers, and SiO_(2) layer and Si_(3)N_(4) thin flim which is used as a pH-sensing layer had been grown by dry oxidation and LPCVD method, respectively. We excited photocurrent in the pH-LAPS device by illuminating 10kHz alternative light upon the back of it. The phtocurrent changes according to the potential change, varied by the pH, on the interface between electrolyte and insulator. The fabricated pH-LAPS shows good sensitivity(about 56mV/pH) and lineality in the range from pH 2 to pH 11.

표면 플라즈몬 공명형 Sucrose 센서의 제작 및 특성

엄년식,고광락,김재호,강신원 경북대학교 센서기술연구소 1997 센서技術學術大會論文集 Vol.8 No.1

A surface plasmon resonance (SPR) sensor for determination of sucrose concentration using gold thin film was constructed. The properties of gold thin film are very serious factors in exciting surface plasmon resonance. So the optimum condition of gold thin-film for the SPR phenomenon was investigated. The result is that the optimum thickness is 545Å at 43.75° resonance angle and roughness is about 3A at that time. Using this SPR system, we got the characteristic of the linear resonance angle shift from 10 wt% to 40 wt% sucrose concentrations.

표면 플라즈몬 공명 신호의 증폭을 위한 새로운 금 콜로이드 센서칩 제조와 특성 연구

임정혁,이경호,고광락,강신원,김재호 경북대학교 센서기술연구소 1998 센서技術學術大會論文集 Vol.9 No.1

New gold colloidal film sensor chips were employed to enhance the sensitivity of the Surface Plasmon Resonce (SPR). Au collodal solutions were synthesized, and Au colloidal films were fabricated by immobilization of colloid on vacuum deposited Au film through the coupling agent of 1,8-diaminooctane. Specific interaction of human IgG antibody to human antigen was monitored by in situ SPR measurement from both a smooth and a Au colloidal films. Au colloidal film sensor chips resulted in 27 % enhancements effect for the same reaction on SPR angle shifts compared to a smooth Au film.

Silicone rubber 멤브레인을 이용한 압저항형 저차압센서의 개발

서창택,공성수,심준환,고광락,서현미,김영진,설철규,신장규,이종현 경북대학교 센서기술연구소 1998 센서技術學術大會論文集 Vol.9 No.1

A 4-beam piezoresistive differential pressure sensor using a silicone rubber membrane has been fabricated on the selectively diffused (100)-oriented n/n^(+)/n silicon substrates by an unique silicon micromachining technique using porous silicon etching. The width, length, and thickness of the beam is 120 μn, 600 μm, and 6 μm, respectively, and the thickness of the silicone rubber membrane was 36 gm. By the use of four-beam structure, the mechanical strength of the differential pressure sensor can be highly improved due to smaller shear stress. And the lower sensitivity of the sensor can be simply solved by combining two output signals of half-bridge. The effectiveness of the sensor is confirmed through an experiment and FEM simulation in which the differential pressure sensor is characterized.

Spiroxazine유도체의 분자 광스위칭을 이용한 능동형 평판 광도파로 자외선센서

옥경식,김시홍,김성훈,김응수,고광락,강신원 경북대학교 센서기술연구소 1998 센서技術學術大會論文集 Vol.9 No.1

UV Sensor is widely used for various fields with the study on UV detector and UV related researches. Also due to the recent increasing of UV radiation by ozone depletion enforces the development of techniques on efficient UV detection. Thus, in our study, we proposed novel UV sensor using photochromic molecular device that has good UV sensitivity and easiness to manufacturing, and low cost. Furthermore, this molecular device is useful for the construction of a thin film active waveguide type device that has excellent sensitivity and feasibility to miniaturization.

Crystal Structures of Vacuum Dehydrated Fully $Cd^{2+}$-Exchanged Zeolite A and Its Ethylene Sorption Complex

Kwang Nak Koh,Un Sik Kim,Duk Soo Kim,Yang Kim Korean Chemical Society 1991 Bulletin of the Korean Chemical Society Vol.12 No.2

The crystal structure of dehydrated fully $Cd^{2+}$-exchanged zeolite A evacuated at $2{\times}10^{-6}$ Torr and $450^{\circ}C (a = 12.225(2){\AA})$ and of its ethylene sorption complex (a = 12.219(2) ${\AA}$) have been determined by single crystal X-ray diffraction techniques in the cubic space group Pm3m at $21(1)^{\circ}$. The structures were refined to final error indices, $R_1$ = 0.063 and $R_2$ = 0.065 with 266 reflections and $R_1$ = 0.055 and $R_2$ = 0.062 with 260 reflections, respectively, for which $I{\gg}3{\sigma}(I)$. In both structures, six $Cd^{2+}$ ions lie at two distinguished three-fold axes of unit cell. Dehydrated $Cd_6$-A sorbs 4 ethylene molecules per unit cell at $25^{\circ}C$ (vapor pressure of ethylene is ca. 100 Torr). Each $Cd^{2+}$ ion forms a lateral ${pi}$ complex with an ethylene molecule. Four $Cd^{2+}$ ions exist in a nearly tetrahedral environment, 2.210(7)${\AA}$ apart from three framework oxygen ions (considering ethylene molecule as a monodentate ligand) and $2.67(6){\AA}$ from each carbon atom of ethylene molecule.

Molecular System Design for the Acetylcholine fluorescent Chemosensor

Koh, Kwang Nak 한국센서학회 1997 센서학회지 Vol.6 No.6

We exploited a new molecular system - acetylcholine (neurotransmitter) detection system as a building block for the perfect molecular information system (sensing membrane of the chemical sensor) - using water soluble calix[n]arene-p-sulfonates which are useful even in aqueous (water/methanol) neutral solution. This achievement is due to several outstanding properties of these calix[n]arene derivatives such as low pK_a values, canon-interactions, and high water-solubility, etc..