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Huai Liu,Xuejuan Cao,Ting Wang,Junnan Wei,Xing Tang,Xianhai Zeng,Yong Sun,Tingzhou Lei,Shijie Liu,Lu Lin 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.77 No.-
The conversion of concentrated 5-hydroxymethylfurfural (HMF) or fructose to 2,5-furandicarboxylic acid(FDCA), a renewable alternative to petroleum-derived terephthalate acid, is highly desirable butchallenging for FDCA production in an industrial scale. In this contribution, DMSO/H2O mixture wasdemonstrated as an effective medium for the production of FDCA from high concentration of HMF orfructose. For example, FDCA yield up to 93% was achieved at 10 wt% HMF concentration in DMSO/H2Oover commercially available Ru/C (2 equiv. NaHCO3, 130 C, 4 MPa O2 and 12 h). Furthermore, an overallFDCA yield of 65% was achieved from concentrated fructose (19 wt%) through a facile two-step process. Notably, it is so far the highest HMF or fructose concentration employed for FDCA formation. As comparedto pure water or DMSO, DMSO/H2O mixed system is able to stabilize HMF in an alkaline environment,which allows the efficient oxidation of HMF at high concentrations.
Ting Wang,Junnan Wei,Huai Liu,Yunchao Feng,Xing Tang,Xianhai Zeng,Yong Sun,Tingzhou Lei,Lu Lin 한국공업화학회 2020 Journal of Industrial and Engineering Chemistry Vol.81 No.-
2, 5-Bishydroxymethylfuran (BHMF) has been currently emerged as a promising biomass-derivedmonomer. It is highly desirable to proceed a chemical process at a high substrate concentration, by whicha facile and cost-effective separation of products can be expected. Herein, we report for thefirst time onthe hydrogenation of highly concentrated 5-hydroxymethylfurfural (HMF) in deep eutectic solvents(DESs), giving a near quantitative selectivity towards BHMF in ChCl-glycerol DES at 25 C in 3 h usingNaBH4 as the H-donor. DES is hailed as a new class of green solvent, in which HMF/BHMF could bestabilized by the strong hydrogen-bond interaction, and allowed the selective hydrogenation of HMF athigh concentration up to 40 wt%. Notably, the resulting BHMF could be facilely separated by extractionwith ethyl acetate, and then high purity of BHMF with a desirable isolated yield around 80% was obtainedafter removing of ethyl acetate. Additionally, the reaction efficiency of HMF hydrogenation in DESs wasverified to be strongly associated with the viscosity of DESs and the pKa value of hydrogen-bonding donor.
Yongjie Li,Qiang Fu,Hongyun Qin,Kun Yang,Junnan Lv,Qicheng Zhang,Zhang Hui,Feng Liu,Xia Chen,Ming Wang 한국화학공학회 2021 Korean Journal of Chemical Engineering Vol.38 No.10
With the intensity of resource scarcities and environmental problems, the disposal and recovery of spent lithium-ion batteries, especially recovery of valuable metals, becomes vital. In this work, a method of co-extracting nickel, cobalt, manganese and being separated from lithium by single-stage solvent extraction is proposed. The extraction and separation process of D2EHPA was studied. The effects of extractant concentration, saponification percentage, extraction time and O:A on the extraction efficiency of D2EHPA were systematically studied. Nearly 100% manganese, 94% cobalt and about 90% nickel were co-extracted and separated from lithium using D2EHPA in kerosene by single-stage extraction. The maximum value of separation factors (Ni/Li, Co/Li and Mn/Li) was 13.03, 23.42 and 1904.24. The mathematical model of extraction of four ions was developed by combination of Levenberg-Marquardt method and Universal Global Optimization method. The proposed extraction model accurately fits the experimental data and helps to predict the extraction efficiency of each metal under the corresponding conditions.
Yang Cuiting,Xiangyu Chen,Jinkui Teng,Shuai Chen,Jianmei Yang,Xiaoqing Liu,Junnan He,Jin Zhang,Yan Zhao 한국고분자학회 2024 Macromolecular Research Vol.32 No.1
Supramolecular nanoplatforms with stimuli-responsive behavior feature sensitive performance and effective drug delivery, which are desirable as intelligent drug delivery systems. Generally, tumor cells are characterized by excessive acid production, resulting in a lower pH in the tumor microenvironment (pH < 6.5) than in normal tissues (pH ≈7.4) and providing the possibility for the drug delivery system to exploit this decrease in pH as a trigger for drug release. Here, an acid-sensitive supramolecular nanoplatform (CM-β-CD/FC12 +Br− NPs) with assembly/disassembly properties was designed and constructed, which was exploited to capture, deliver, and release anti-tumor compound CSL. 2D NOESY was utilized to examine the host–guest interaction and the potential mechanism for CM-β-CD/FC12 +Br− NPs loading CSL. CM-β-CD/FC12 +Br− NPs present good blood compatibility. Cytotoxicity assay revealed that CSL-loaded NPs display minimal toxicity against normal cells BEAS-2B and good anticancer ability against five human cancer cell lines, especially for Human hepatoma cell line SMMC-7721. In addition, cell apoptosis and cycle assay further verified that CSL-loaded NPs-induced apoptosis in SMMC- 7721 cells up to ~ 93%, as well as blocking the cells in G0/G1 phase and inhibiting the proliferation of SMMC-7721 cells in a dose-dependent manner. We expect that CM-β-CD/FC12 +Br− NPs will be potential acid-answered drug delivery candidates.