붕소화합물을 이용한 대나무의 방부처리

나종범,김사익,조종수,윤승락,노정관,김동귀,최길동 진주산업대학교 산업과학기술연구소 2007 산업과학기술연구소보 Vol.- No.14

This study was performed to investigate the effect of wax layer of bamboo on leaching of boron compounds. The removal of wax layer increased the loading of boron on bamboo surface. However, it had an effect on increasing the leaching rates of boron compounds during leaching test. The addition of water repellent retarded leaching of boron compounds to some extent from treated samples. Although borate/WRP system did not qualify borate treated wood for ground contact use, it showed a potential to improve performance of borate treated bamboo in above-ground applications not subjected to continuous wetting conditions.

편백 잎(葉) 정유 성분의 항균(抗菌)활성 물질 분석

조종수,김사익,윤승락,노정관,나종범,김동귀,최길동 진주산업대학교 산업과학기술연구소 2007 산업과학기술연구소보 Vol.- No.14

To investigate the antimicrobial effects of essential oil in the leaves of Chamaecyparis obtusa extractives by paper disc method, the extractives were fractionated into four portions. In antimicrobial test, essential oil in the leaves of Chamaecyparis obtusa was found to have strong inhibitory effects against the growth of Bacillus subtilis and Staphylococcus aureus. A part of analyzed inhibition components of essential oil in the leaves of Chamaecyparis obtusa from GC-MS was supposed to be α,β-pinene, α-terpinolene, camphor, β-myrcene, 1-α-terpinolene, 4-thujen-2-α-yl, limonene, Cardinene.

수액치한법을 이용한 소경재의 산지처리(Ⅰ) : 증산법과 원구법을 이용한 처리 가능성 Feasibility of Treatment Using Transpiration Method and Butt-end Method

전수경,김재진,나종범,김규혁 한국목재공학회 2002 목재공학 Vol.30 No.4

본 연구는 수액치환법을 이용한 침엽수 간벌소경재나 미(저)이용 활용수재의 산지 보존처리 기술을 개발하기 위하여 수행되었다. 본 논문에서는 증산법과 원구법을 이용한 3종 침엽수와 3종 활엽수의 방부제, 난연제, 치수안정제 처리 가능성을 조사하여 보고한다. 수종과 처리약제의 조합에 관계없이 원구법이 증산법에 비하여 약제의 목재내 침투가 양호할 뿐만 아니라 약제의 침투가 균일한 관계로 수분 이동경로를 이용한 처리재 생산은 원구법의 사용이 바람직하였다. 원구법 처리는 수관부를 절단한 후 실시하기 때문에 증산법에 비하여 처리가 용이할 뿐만 아니라 벌채 및 조재 후 산지의 일정 장소로 운재 후 처리를 실시하기 때문에 증산법과 비교할 때 집약적 처리로 단위시간당 처리재 생산량이 높고 산지 환경오염 문제도 예방할 수 있는 장점이 있다. This research was carried out to develop field treatment techniques of thinned small diameter softwood logs and less utilized hardwood logs using sap displacement method. In this paper, we report the feasibility of using transpiration method and butt-end method for the treatment of three softwood species and three hardwood species with preservatives, fire-retardant chemicals, and dimensional stabilizer. Butt-end method was effective as a field treatment technique compared to transpiration method when considered the treatability, easiness of treatment, productivity of treated wood, and environmental aspects related to chemical treatment, regardless of the combination of wood species and chemicals.

소나무와 잣나무 원목에서 변재변색 발생

김규혁,김재진,나종범 한국목재공학회 2002 목재공학 Vol.30 No.2

본 연구는 동절기 (1월 중순)에 벌채된 후 목재집하장으로 운반되어 야적장에 저목 중인 소나무와 잣나무 원목을 대상으로 변재변색의 발생시기와 변색 특성을 조사하기 위하여 수행되었다. 벌채 후 3, 4, 5, 6, 8개월 경과시 변색 평가를 실시하였는데, 매 평가시 원목 3개를 임의로 선정하여 원목당 수축방향에 대해 일정 간격으로 7∼9개의 두께 3 ㎝ 원판을 채취하여 변색 원인균을 분리한 후 변재변색의 방사방향 최대 침투깊이와 % 변색율을 측정하였다. 변재변색은 전적으로 층형변색이었으며, 주요 변색원인균인 Ophiostomatoid 균을 매개하는 수피천공충은 소나무좀으로 확인되었다. 소나무와 잣나무 원목은 5월 이전까지는 변재변색의 위험없이 저목할 수 있으나 5월 이후부터는 원목의 변재변색이 급속하게 증가하였다. 변색의 정도는 소나무보다 잣나무에서 심하였으며, 장마철 저목 중에 소나무 원목에서 개떡버섯과 치마버섯의 자실체를 다수 관찰할 수 있었다. 본 연구를 통해 밝혀진 결과들은 앞으로 동절기에 벌채되어 저목 중인 소나무와 잣나무 원목에 발생하는 변재변색을 예방하기 위한 제반 조치를 취하는데 매우 중요한 자료로 사용될 것이다. This study was conducted to investigate the influence of storage time on the sapstain development of Japanese red pine and Korean pine logs during storage in log yard, and their stain characteristics. Japanese red pine and Korean pine trees were harvested and cut into logs in mid January of 2001. These logs were transported to the two local sawmills where they were closely stacked in remote parts of log yard. The logs were then sampled destructively by cutting seven to nine 3-㎝ long discs along the length of each log at intervals of 3, 4, 5, 6, and 8 month after felling. The stain coverage and maximal radial penetration of stain were measured from the discs of the sampled logs after the isolation of causal staining fungi. The sapstain was primarily infested by the attack of bark beetles and the species of bark beetle was identified as Tomicus piniperda. The main fungal species isolated from stained wood was Ophiostoma species. Based on the present study, the logs could be stored in log yard until May without stain; but stain development was rapid after May and the severity of stain increased proportionally with storage time. Korean pine was more susceptible to fungal stain than Japanese red pine. During summer storage, decay started to develop in logs and the main species were identified as Tyromyces sp. and Schizophyllum commune. Information provided in this paper would be very useful to develop more effective control strategies for sapstain prevention in Japanese red pine and Korean pine logs.

CCA 처리재로부터 방부제 유효성분의 용제추출

김규혁,공일곤,나종범,조재성,김재진 한국목재공학회 2003 목재공학 Vol.31 No.4

본 연구는 CCA 처리재로부터 방부제 유효성분을 추출하기 위한 적정 용제를 선정하고, 선정된 용제의 최적추출조건을 평가하기 위 해 수행되었다. 추출수율과 용제의 사용 및 환경 안전성을 고려할 때, 과산화수소가 CCA유효성분을 추출하는 데 가장 적절한 용제로 선정되었다. 과산화수소를 이용한 추출 결과. 추출온도, 추출용제농도, 추출시간 간에 상호작용이 존재하였으나 추출온도와 추출용제의 농도가 높을수록, 그리고 추출시간이 연장될수록 CCA유효성분의 추출수율은 증가되었다. 경제적인 측면을 고려할 때 가능하면 낮은 농도의 추출용제를 사용하여 저온에서 추출하여야 하나, 이 경우에는 필요한 추출수율을 달성하기 위한 추출시간이 상당히 길어지기 때문에 40℃ 이상의 온도에서 추출이 바람직하며 사용할 추출용제의 농도는 추출시간을 고려하여 최종적으로 결정하여야 된다고 사료된다. This research was performed to select an appropriate agent to extract preservative components from CCA-treated wood, and then to evaluate the effect of reagent concentration, extracting temperature, and CCA-treated wood, and then to evaluate the effect of reagent concentration, extracting temperature, and extracting time on the removal of chrome, copper, and arsenic from treated wood. Hydrogen peroxide was selected as the best extracting agent when considered extraction yield as well as use and environmental safety. Its extraction yield was dependent on extracting variables (temperature, concentration, and time), and a highly significant interaction existed among variables. It should be possible to optimize extraction by manipulating these extracting variables. The results may suggest that the required temperature conditions for the reasonable removal of CCA components are at least above 40℃ because extracting time is too long at low temperature (20℃). Reagent concentrations for extracting at above 40℃ should be decided by considering the extracting time.

표백에 의한 라디에타소나무의 청변 제거

김규혁,김형준,나종범,김재진 한국목재공학회 2003 목재공학 Vol.31 No.1

본 연구는 라디에타소나무 제재목의 균 변색을 제거하기 위한 표백처리의 사용 가능성을 조사하기 위하여 수행하였다. 염소계 표백제인 아염소산나트륨과 차아염소산나트륨은 표백조건(약제농도, 처리온도, 처리시간)의 조절에 따라 만족할만한 변색제거 효과를 얻을 수 있었다. 비염소계 표백제인 과산화수소는 표백조건의 조절만으로는 변색제거가 불가능하였으나 규산나트륨과 수산화나트륨을 활성제로 첨가하는 경우에는 염소계 표백제보다 탁월한 변색제거 효과를 나타내었다. 그러나 활성제 첨가에 따라 재색의 녹색화 문제가 발생하였는데, 앞으로 이러한 문제점을 해결하기 위한 연구가 진행되어야 할 것이다. 또한, 앞으로 본 연구를 통해 개발된 변색제거방법의 현장 적용을 후속 연구도 필요하다고 본다. The feasibility of using bleaching treatments for removing fungal stain was evaluated on heavily stained raiadta pine sapwood. Sodium chlorite and sodium hypochlorite appeared to destain fungal discoloration by providing proper treatment conditions (chemical concentration, treatment temperature, and treatment time), while hydrogen peroxide did not remove fungal stain under the bleaching regimes evaluated. The addition of sodium silicate and sodium hydroxide in the hydrogen peroxide solution as a buffer could remove fungal discoloration completely:; however, the color of wood surface turned faint green after bleaching, thereby reducing the lightness of bleached samples. The results suggest that hydrogen peroxide bleaching could be a feasible method for removing fungal discoloration of stained radiata pine sapwood, although further research is needed to solve the problem of color change after bleaching Also, further tests under field conditions are recommended.

케나프 TMP, CTMP의 섬유 특성

윤승락,김사익,조종수,노정관,나종범,김동귀,최길동 진주산업대학교 산업과학기술연구소 2007 산업과학기술연구소보 Vol.- No.14

Thermomechanical pulp (TMP) and chemical thermomechanical pulp (CTMP) of kenaf cultivated in Korea were manufactured and their fiber properties were investigated. TMP made of the core part of kenaf showed various geometric types of fibers such as rectangular, spindle, and cylindrical forms. The most TMP made of the outer part of kenaf were composed of bast fibers, where no damages on the surface and cutting section of bast fibers was found. CTMP made of the core showed that some fibers were damaged. However, the fibers in CTMP made of the bast were observed not to be damaged. The TMP made of the core showed sound fibers, but the CTMP made of the core showed some damaged fibers. The TMP made of the bast showed curl indexes higher than the CTMP made of the bast, and most of fibers were not damaged in both TMP and CTMP pulps.

폐기 목질 재료로 제조한 학생용 책상 천판의 성능에 미치는 성형조건의 영향

노정관,김재경,김사익,조종수,윤승락,나종범,도정락 한국목재공학회 2002 목재공학 Vol.30 No.4

폐기 목질재료를 사용하여 학생용 책상 천판의 성형시 각 제조조건에 따른 천판의 성능을 검토하였다. 책상 천판의 파티클 구성은 고운 파티클과 거친 파티클을 적절히 혼합한 것이 고운 파티클이나 거친 파티클만으로 제조한 것보다는 전체적으로 성능이 양호하였으며, 특히 표층에는 고운 파티클을 중층에는 거친 파티클을 구성하는 것이 표면 마감성이 가장 우수하였다. 그리고 밀도가 높을수록 박리강도, 휨 강도는 우수하나, 흡수두께 팽창율은 증가하였으며, 수지 도포량이 많을수록 박리강도, 흡수두께 팽창율은 양호하나, 포름알데히드의 방출량은 높았다. 가압온도는 높을수록 대부분의 성능이 향상되었으며, 190℃가 가장 적절하였다. 가압시간은 1단계 2분과 2단계 2분이 비교적 양호하나 2단계의 가압시간을 1분으로 단축하여도 성능에는 큰 문제가 없어 앞으로 생산성의 향상을 기대할 수 있을 것으로 생각된다. This research was performed to investigate the effect of moulding conditions on properties of the table top for student desk manufactured by wood waste materials. The table top manufactured using the mat mixed properly with fine particles and coarse particles generally showed better physical properties than those manufactured using either fine particles or coarse particles did. Especially, highest performance for overlaying was observed when fine particles were used for face layer and coarse particles were used for core layer. The internal bond (IB) strength, the bending strength and thickness swelling increased with the increase of density. Most of physical properties were improved with the increase of hot pressing temperature. The best physical properties were found at 190℃ when the first hot pressing and the second hot pressing times were two minutes. However, the effect of the second hot pressing time of two minutes on the physical properties was not markedly different from that of one minute. This result suggests that the second hot pressing time of one minute is enough to increase the productivity in manufacturing the table top with the least decrease of the physical properties.

Measurment of Copper Concentration in ACQ, CUAZ, and CB-HDO Solutions by Using a Spectrophotometer

Jong Bum Ra 한국목재공학회 2010 목재공학 Vol.38 No.5

Simple measurement of the concentrations of ACQ, CuAZ, and CB-HDO solutions by spectrophotometer

( Jong Bum Ra ) 韓國木材工學會 2010 한국목재공학회 학술발표논문집 Vol.2010 No.-