In-situ PECVD-enabled graphene-V₂O₃ hybrid host for lithium–sulfur batteries

Song, Yingze,Zhao, Wen,Wei, Nan,Zhang, Li,Ding, Feng,Liu, Zhongfan,Sun, Jingyu Elsevier 2018 Nano energy Vol.53 No.-

<P><B>Abstract</B></P> <P>Lithium–sulfur (Li–S) batteries have been regarded as promising candidates for current energy-storage technologies due to their remarkable advantages in energy density and theoretical capacity. However, one of the daunting challenges remained for advanced Li–S systems thus far deals with the synchronous suppression of polysulfide (LiPS) shuttle and acceleration of redox kinetics. Herein, a cooperative interface bridging adsorptive V<SUB>2</SUB>O<SUB>3</SUB> and conductive graphene is constructed <I>in-situ</I> by virtue of direct plasma-enhanced chemical vapor deposition (PECVD), resulting in the design of a novel V<SUB>2</SUB>O<SUB>3</SUB>-graphene hybrid host to synergize the LiPS entrapment and conversion. The redox kinetics and electrochemical performances of thus-derived cathodes were accordingly enhanced owing to the smooth adsorption-diffusion-conversion of LiPSs even at a sulfur mass loading of 3.7 mg cm<SUP>–2</SUP>. Such interfacial engineering offers us a valuable opportunity to gain insight into the comprehensive regulation of LiPS anchoring ability, electrical conductivity and ion diffusive capability in hybrid hosts on suppressing the LiPS shuttle and propelling the redox kinetics. Our devised PECVD route might pave a new route toward the facial and economic design of hetero-phased multi-functional hosts for high-performance Li–S systems.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Graphene-V<SUB>2</SUB>O<SUB>3</SUB> hybrid host was designed <I>in-situ</I> based on PECVD route. </LI> <LI> Thus-derived cathode showed a low capacity decay of merely 0.046% per cycle at 2 C after 1000 cycles. </LI> <LI> Cathodes with a relatively high sulfur mass loading (3.7 mg cm<SUP>–2</SUP>) were fabricated. </LI> <LI> The smooth adsorption-diffusion-conversion of polysulfides was thoroughly probed <I>via</I> experimental studies and DFT simulations. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

Synchronous immobilization and conversion of polysulfides on a VO₂-VN binary host targeting high sulfur load Li-S batteries

Song, Yingze,Zhao, Wen,Kong, Long,Zhang, Li,Zhu, Xingyu,Shao, Yuanlong,Ding, Feng,Zhang, Qiang,Sun, Jingyu,Liu, Zhongfan The Royal Society of Chemistry 2018 ENERGY AND ENVIRONMENTAL SCIENCE Vol.11 No.9

<P>Lithium-sulfur (Li-S) batteries are deemed as one of the most promising next-generation energy storage systems. However, their practical application is hindered by existing drawbacks such as poor cycling life and low Coulombic efficiency due to the shuttle effect of lithium polysulfides (LiPSs). We herein present an <I>in situ</I> constructed VO2-VN binary host which combines the merits of ultrafast anchoring (VO2) with electronic conducting (VN) to accomplish smooth immobilization-diffusion-conversion of LiPSs. Such synchronous advantages have effectively alleviated the polysulfide shuttling, promoted the redox kinetics, and hence improved the electrochemical performance of Li-S batteries. As a result, the sulfur cathode based on the VO2-VN/graphene host exhibited an impressive rate capability with ∼1105 and 935 mA h g<SUP>−1</SUP> at 1C and 2C, respectively, and maintained long-term cyclability with a low capacity decay of 0.06% per cycle within 800 cycles at 2C. More remarkably, favorable cyclic stability can be attained with a high sulfur loading (13.2 mg cm<SUP>−2</SUP>). Even at an elevated temperature (50 °C), the cathodes still delivered superior rate capacity. Our work emphasizes the importance of immobilization-diffusion-conversion of LiPSs toward the rational design of high-load and long-life Li-S batteries.</P>

Vanadium Dioxide-Graphene Composite with Ultrafast Anchoring Behavior of Polysulfides for Lithium-Sulfur Batteries

Song, Yingze,Zhao, Wen,Zhu, Xingyu,Zhang, Li,Li, Qiucheng,Ding, Feng,Liu, Zhongfan,Sun, Jingyu American Chemical Society 2018 ACS APPLIED MATERIALS & INTERFACES Vol.10 No.18

<P>The lithium-sulfur (Li-S) battery has been deemed as one of the most promising energy-storage systems owing to its high energy density, low cost, and environmental benignancy. However, the capacity decay and kinetic sluggishness stemming from polysulfide shuttle effects have by far posed a great challenge to practical performance. We herein demonstrate the employment of low-cost, wet-chemistry-derived VO<SUB>2</SUB> nanobelts as the effective host additives for the graphene-based sulfur cathode. The VO<SUB>2</SUB> nanobelts displayed an ultrafast anchoring behavior of polysulfides, managing to completely decolor the polysulfide solution in 50 s. Such a fast and strong anchoring ability of VO<SUB>2</SUB> was further investigated and verified by experimental and theoretical investigations. Benefitting from the synergistic effect exerted by VO<SUB>2</SUB> in terms of chemical confinement and catalytic conversion of polysulfides, the Li-S batteries incorporating VO<SUB>2</SUB> and graphene manifested excellent cycling and rate performances. Notably, the batteries delivered an initial discharge capacity of 1405 mAh g<SUP>-1</SUP> when cycling at 0.2 C, showed an advanced rate performance of ∼830 mAh g<SUP>-1</SUP> at 2 C, and maintained a stable cycling performance at high current densities of 1, 2, and 5 C over 200 cycles, paving a practical route toward cost-effective and environmentally benign cathode design for high-energy Li-S batteries.</P> [FIG OMISSION]</BR>

Research on vibration control of a transmission tower-line system using SMA-BTMD subjected to wind load

Li Tian,Jingyu Luo,Mengyao Zhou,Wenzhe Bi,Yuping Liu 국제구조공학회 2022 Structural Engineering and Mechanics, An Int'l Jou Vol.82 No.5

As a vital component of power grids, long-span transmission tower-line systems are vulnerable to wind load excitation due to their high flexibility and low structural damping. Therefore, it is essential to reduce wind-induced responses of tower-line coupling systems to ensure their safe and reliable operation. To this end, a shape memory alloy-bidirectional tuned mass damper (SMA-BTMD) is proposed in this study to reduce wind-induced vibrations of long-span transmission tower-line systems. A 1220 m Songhua River long-span transmission system is selected as the primary structure and modeled using ANSYS software. The vibration suppression performance of an optimized SMA-BTMD attached to the transmission tower is evaluated and compared with the effects of a conventional bidirectional tuned mass damper. Furthermore, the impacts of frequency ratios and SMA composition on the vibration reduction performance of the SMA-BTMD are evaluated. The results show that the SMA-BTMD provides superior vibration control of the long-span transmission tower-line system. In addition, changes in frequency ratios and SMA composition have a substantial impact on the vibration suppression effects of the SMABTMD. This research can provide a reference for the practical engineering application of the SMA-BTMD developed in this study.

Estimating the Effects of Multipath Selection on Concurrent Multipath Transfer

( Jingyu Wang ),( Jianxin Liao ),( Jing Wang ),( Tonghong Li ),( Qi Qi ) 한국인터넷정보학회 2014 KSII Transactions on Internet and Information Syst Vol.8 No.4

Multi-mode device which combines multiple access technologies into a device will offer more cost-effective solution than a sole access implementation. Its concurrent multipath transfer (CMT) technology can transmit media flows over multiple end-to-end paths simultaneously, which is essential to select at least two paths from all available paths. At real networks, different paths are likely to overlap each other and even share bottleneck, which can weaken the path diversity gained through CMT. Spurred by this observation, it is necessary to select multiple independent paths as much as possible to avoid underlying shared bottleneck between topologically joint paths. Recent research in this context has shown that different paths with shared bottleneck can weaken the path diversity gained through CMT. In our earlier work, a grouping-based multipath selection (GMS) mechanism is introduced and developed. However, how to estimating the selection is still to be resolved. In this paper, we firstly introduce a Selection Correctness Index (SCI) to evaluate the correctness of selection results in actual CMT experiment. Therefore, this metric is helpful to discuss and validate the accuracy of the output paths. From extensive experiments with a realized prototype, the proposed scheme provides better evaluation tool and criterion in various network conditions.

Aerodynamic effects of subgrade-tunnel transition on high-speed railway by wind tunnel tests

Jingyu Zhang,Mingjin Zhang,Yongle Li,Chen Fang 한국풍공학회 2019 Wind and Structures, An International Journal (WAS Vol.28 No.4

The topography and geomorphology are complex and changeable in western China, so the railway transition section is common. To investigate the aerodynamic effect of the subgrade-tunnel transition section, including a cutting-tunnel transition section, an embankment-tunnel transition section and two typical scenarios for rail infrastructures, is selected as research objects. In this paper, models of standard cutting, embankment and CRH2 high-speed train with the scale of 1:20 were established in wind tunnel tests. The wind speed profiles above the railway and the aerodynamic forces of the vehicles at different positions along the railway were measured by using Cobra probe and dynamometric balance respectively. The test results show: The influence range of cutting-tunnel transition section is larger than that of the embankment-tunnel transition section, and the maximum impact height exceeds 320mm (corresponding to 6.4m in full scale). The wind speed profile at the railway junction is greatly affected by the tunnel. Under the condition of the double track, the side force coefficient on the leeward side is negative. For embankment-tunnel transition section, the lift force coefficient of the vehicle is positive which is unsafe for operation when the vehicle is at the railway line junction.

AUTONOMOUS CONSUMPTION:ROBOTS IN HOSPITALITY AND TOURISM SERVICE

Jingyu Liu,Yibei Li,Lingxu Zhou 글로벌지식마케팅경영학회 2023 Global Marketing Conference Vol.2023 No.07

The extensive application of robots in hospitality and tourism service has transformed the original human-contact into contact-less, so it is necessary to understand the transformation of customers consumption behaviors under this new service mode. While studies have started investigating how service robots enhance the consumer autonomy, the impact of such technology on customers consumption behaviors remains largely unexplored and its underlying mechanism are still unclear. To address this issue, we explore how service robots shape customers autonomous behaviors in hospitality and tourism services. Drawing on the social impact theory, we presented an underlying process in terms of social discomfort, and reveal the boundary conditions.

Voltage Vector Selection Area of the Direct Torque Control for Permanent Magnet Synchronous Motor

Li, Yaohua,Ma, Jian,Yu, Qiang,Liu, Jingyu Journal of International Conference on Electrical 2012 Journal of international Conference on Electrical Vol.1 No.2

The control of stator flux, torque angle, excitation torque, reluctance torque and total torque of the direct torque control (DTC) for a permanent magnet synchronous motor (PMSM) are studied in this paper. Simplified expressions to represent the changes of these variables due to the application of a voltage vector are given. Finally, a voltage vector selection area and the implementation of a voltage vector selection strategy are proposed.

Ginsenoside Rg3 ameliorates myocardial glucose metabolism and insulin resistance via activating the AMPK signaling pathway

Jingyu Ni,Zhihao Liu,Miaomiao Jiang,Lan Li,Jie Deng,Xiaodan Wang,Jing Su,Yan Zhu,Feng He,Jingyuan Mao,Xiumei Gao,Guanwei Fan 고려인삼학회 2022 Journal of Ginseng Research Vol.46 No.2

Background: Ginsenoside Rg3 is one of the main active ingredients in ginseng. Here, we aimed to confirm its protective effect on the heart function in transverse aortic coarctation (TAC)-induced heart failure mice and explore the potential molecular mechanisms involved. Methods: The effects of ginsenoside Rg3 on heart and mitochondrial function were investigated by treating TAC-induced heart failure in mice. The mechanism of ginsenoside Rg3 for improving heart and mitochondrial function in mice with heart failure was predicted through integrative analysis of the proteome and plasma metabolome. Glucose uptake and myocardial insulin sensitivity were evaluated using micro-positron emission tomography. The effect of ginsenoside Rg3 on myocardial insulin sensitivity was clarified by combining in vivo animal experiments and in vitro cell experiments. Results: Treatment of TAC-induced mouse models with ginsenoside Rg3 significantly improved heart function and protected mitochondrial structure and function. Fusion of metabolomics, proteomics, and targeted metabolomics data showed that Rg3 regulated the glycolysis process, and Rg3 not only regulated glucose uptake but also improve myocardial insulin resistance. The molecular mechanism of ginsenoside Rg3 regulation of glucose metabolism was determined by exploring the interaction pathways of AMPK, insulin resistance, and glucose metabolism. The effect of ginsenoside Rg3 on the promotion of glucose uptake in IR-H9c2 cells by AMPK activation was dependent on the insulin signaling pathway. Conclusions: Ginsenoside Rg3 modulates glucose metabolism and significantly ameliorates insulin resistance through activation of the AMPK pathway.

Theoretical models of threshold stress intensity factor and critical hydride length for delayed hydride cracking considering thermal stresses

Jingyu Zhang,Jiacheng Zhu,Shurong Ding,Liang Chen,Wenjie Li,Hua Pang 한국원자력학회 2018 Nuclear Engineering and Technology Vol.50 No.7

Delayed hydride cracking (DHC) is an important failure mechanism for Zircaloy tubes in the demandingenvironment of nuclear reactors. The threshold stress intensity factor, KIH, and critical hydride length, lC ,are important parameters to evaluate DHC. Theoretical models of them are developed for Zircaloy tubesundergoing non-homogenous temperature loading, with new stress distributions ahead of the crack tipand thermal stresses involved. A new stress distribution in the plastic zone ahead of the crack tip isproposed according to the fracture mechanics theory of second-order estimate of plastic zone size. Thedeveloped models with fewer fitting parameters are validated with the experimental results for KIH andlC. The research results for radial cracking cases indicate that a better agreement for KIH can be achieved;the negative axial thermal stresses can lessen KIH and enlarge the critical hydride length, so its effectshould be considered in the safety evaluation and constraint design for fuel rods; the critical hydridelength lC changes slightly in a certain range of stress intensity factors, which interprets the phenomenonthat the DHC velocity varies slowly in the steady crack growth stage. Besides, the sensitivity analysis ofmodel parameters demonstrates that an increase in yield strength of zircaloy will result in a decrease inthe critical hydride length lC , and KIH will firstly decrease and then have a trend to increase with the yieldstrength of Zircaloy; higher fracture strength of hydrided zircaloy will lead to very high values ofthreshold stress intensity factor and critical hydride length at higher temperatures, which might be themain mechanism of crack arrest for some Zircaloy materials