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        Polycyclic aromatic hydrocarbon emissions of non-road diesel engine treated with non-thermal plasma technology

        Chaochen Ma,Jianbing Gao,Shikai Xing,Liwei Sun,Jiangquan Liu 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.12

        Non-road diesel engines are important polycyclic aromatic hydrocarbon (PAH) sources in the environment due to their high emission concentration compared to on-road diesel engines. Particle- and gas-phase PAH concentrations of a non-road diesel engine were investigated. Non-thermal plasma (NTP) as an effective after-treatment technology was used to reduce PAH emissions. The results showed that particle-phase PAH concentrations were 329.7 μg/m3, 3,206.7 μg/m3, and 1,185.7 μg/m3 without the action of NTP at three different engine loads respectively. Relatively low concentrations were measured for gas-phase PAHs. Excellent linearity was shown for particle-phase with total PAH concentrations both with, and without, NTP. The gas-phase PAH concentrations linearly increased with engine load without NTP. The five most abundant compounds of PAHs were among low molecular weight (LMW) and medium molecular weight (MMW) compounds. Total PAH cleaning efficiency was beyond 50% when treated with NTP at the three different engine loads. We hypothesized that naphthalene (Nap) concentrations increased greatly at 60% and 80% engine loads because it was produced within the plasma zone by decomposition of high molecular weight (HMW) PAHs. The PAHs content of particulate matter (PM) aggregation at 60% load was approximately three times higher than at 40% and 80% loads. High correlation values were observed for MMW PAHs with total PAH concentrations. Correlations of PAH concentration reduction could be important to clarify the PAH reduction mechanism with NTP technology.

      • KCI등재

        Tung Oil Anhydride Modified Hemp Fiber/Polypropylene Composites: The Improved Toughness, Thermal Stability and Rheological Property

        Hongming Wu,Dinghong Xu,Ying Zhou,Chengtao Gao,Jianbing Guo,Weidi He,Yong He,Shuhao Qin 한국섬유공학회 2020 Fibers and polymers Vol.21 No.9

        Natural fibers reinforced composites (NFCs) have renewable and low cost advantages. In this paper, the tung oilanhydride (TOA) modified polypropylene (PP)/hemp fiber composites have been prepared by a melt-blended process. Thereaction between the tung oil anhydride and the as-treated hemp fiber make the TOA molecules to accumulate on the surfaceof hemp fiber and to form a TOA layer on the surface of hemp fibers, which is confirmed by the FT-IR and SEM analyses. The TOA layer improves the compatibility between PP matrix and hemp fibers. The elongation at break (EB) and impactstrength of the PP/hemp fiber/TOA composites are twice more than the PP/hemp fiber composites. Thermal analysis showsthe Toneset and Tmax of the composites increasing that reflects the thermal stability of the composites improved. The crystallineproperty reveals that the Tc moves to high temperature with the TOA or hemp fiber added in the blends. The DMA andrheology properties analysis indicate that the TOA layer improved molecular mobility of the composites and show a shearthinning effect.

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