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Optimization of photocatalytic degradation of Cefradine using a “green” goethite/H2O2 system
Ruiping Li,Shaoming Hong,Xiaocong Li,Bin Zhang,Hailin Tian,Yingping Huang 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.78 No.-
An environmental friendly photocatalyst, goethite in the presence of H2O2, was used to remove Cefradinefrom aqueous solution. Four factors were examined using Box–Behnken Design and results wereanalyzed by response surface method. H2O2 concentration had the largest effect on Cefradine removaland the optimal reaction conditions were: H2O2 concentration, 4 mmol/L; solution pH, 5; goethitedosage, 1.2 g/L and illumination time, 9 h. Experimental data on Cefradine removal under optimalconditions closely coincided with model predictions, validating the model. Hydroxyl radicals ( OH) andsuperoxide anion were involved in the Cefradine photodegradation process and that OH makes thelarger contribution.