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        Preparation of carbonated apatite nano-whiskers in SBF with ultrasonic assistance

        Yanli Geng,Yanbao Li,Dongxu Li 한양대학교 세라믹연구소 2009 Journal of Ceramic Processing Research Vol.10 No.5

        Carbonated apatite nano-whiskers were prepared in simulated body fluids (SBF) with ultrasonic assistance at 37℃. The effects of the initial pH value in the SBF solution and reaction times were investigated in this study. The calcium phosphate precipitates were examined by XRD, FTIR and TEM techniques. The results showed that the initial pH value in the SBF had an important effect on the morphology and composition of the calcium phosphate precipitates, and carbonated apatite nanowhiskers with length/diameter ratio of ~20 were obtained at an initial pH = 7.5 after ultrasonic treatment for 24 h. Carbonated apatite nano-whiskers were prepared in simulated body fluids (SBF) with ultrasonic assistance at 37℃. The effects of the initial pH value in the SBF solution and reaction times were investigated in this study. The calcium phosphate precipitates were examined by XRD, FTIR and TEM techniques. The results showed that the initial pH value in the SBF had an important effect on the morphology and composition of the calcium phosphate precipitates, and carbonated apatite nanowhiskers with length/diameter ratio of ~20 were obtained at an initial pH = 7.5 after ultrasonic treatment for 24 h.

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        Crystal structure, dielectric and piezoelectric properties of Ta/W codoped Bi3TiNbO9 Aurivillius phase ceramics

        Zhihang Peng,Dongxu Yan,Qiang Chen,Deqiong Xin,Dan Liu,Dingquan Xiao,Jian-guo Zhu 한국물리학회 2014 Current Applied Physics Vol.14 No.12

        Aurivillius phase Bi3Ti1xTaxNb1xWxO12 high temperature piezoceramics were prepared by a conventional solid state reaction method. The crystal structure, dielectric, electrical conduction and piezoelectric properties were systematically studied. Pure or modified Bi3TiNbO9 ceramics revealed the presence of only two-layered Aurivillius phase, indicating that Ta/W doping entered into the B-site of pseudo-perovskite structure and formed solid solutions. The Curie temperature had a strong reliance on the structural distortion. Furthermore, Ta/W dopants act as a donor doping, decrease the number of oxygen vacancies and facilitate the domain wall motion. As a result, Ta/W modifications significantly increase the DC resistivity and piezoelectric properties. Bi3Ti0.98Ta0.02Nb0.98W0.02O12 ceramics possess the optimum d33 value (~12.5 pC/N) together with a high TC point (~893 C). Moreover, the resonance eantiresonance spectra demonstrate that the Ta/W-BTN ceramics are indeed piezoelectric in nature at 600 C. The d33 value of BTTNW-2 ceramic remains ~12.2 pC/N after annealing at 700 C. These factors suggest that the BTTNW-based ceramic is a promising candidate for ultra-high temperature sensor applications.

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