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        Crystal structure, dielectric and piezoelectric properties of Ta/W codoped Bi3TiNbO9 Aurivillius phase ceramics

        Zhihang Peng,Dongxu Yan,Qiang Chen,Deqiong Xin,Dan Liu,Dingquan Xiao,Jian-guo Zhu 한국물리학회 2014 Current Applied Physics Vol.14 No.12

        Aurivillius phase Bi3Ti1xTaxNb1xWxO12 high temperature piezoceramics were prepared by a conventional solid state reaction method. The crystal structure, dielectric, electrical conduction and piezoelectric properties were systematically studied. Pure or modified Bi3TiNbO9 ceramics revealed the presence of only two-layered Aurivillius phase, indicating that Ta/W doping entered into the B-site of pseudo-perovskite structure and formed solid solutions. The Curie temperature had a strong reliance on the structural distortion. Furthermore, Ta/W dopants act as a donor doping, decrease the number of oxygen vacancies and facilitate the domain wall motion. As a result, Ta/W modifications significantly increase the DC resistivity and piezoelectric properties. Bi3Ti0.98Ta0.02Nb0.98W0.02O12 ceramics possess the optimum d33 value (~12.5 pC/N) together with a high TC point (~893 C). Moreover, the resonance eantiresonance spectra demonstrate that the Ta/W-BTN ceramics are indeed piezoelectric in nature at 600 C. The d33 value of BTTNW-2 ceramic remains ~12.2 pC/N after annealing at 700 C. These factors suggest that the BTTNW-based ceramic is a promising candidate for ultra-high temperature sensor applications.

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