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      • 擔體를 包含한 에멀젼型 液膜의 구리이온 促進 傳達에 關한 模寫硏究

        宋東益,崔相俊 慶北大學校 1984 論文集 Vol.38 No.-

        A mathematical model for facilitated transport simultaneously taken account of both the formation reaction of copper complex at the external aqueous solution and internal diffusion of the complex in the liquid membrane was developed and compared with the experimental data. Overall reaction equilibrium constant was estimated to be 6×10exp(-10) by fitting the model equations to the experimental data. The formation rate of copper complex was confirmed to be nearly first order with respect to the copper ion concentration. More studies on the reaction order of the hydrogen ion concentration, however, seem to be required. First of all, kinetic studies should be performed to obtain more accurate reaction rate equation for the development of the extraction processes in the future.

      • 에멀젼형 액막의 안정성에 영향을 미치는 인자들 : 실험계획법에 의한 체계적 접근 예 An example of systematic approach using experimental design

        송동익 경북대학교 공과대학 1986 工大硏究誌 Vol.15 No.-

        Factors influencing on the stability of the emulsion-type liquid membrane were analysed using factorial design method. It was shown that the volume ratio of aqueous phase to oil phase(W/O ratio) and the pH of the external aqueous phase were the main effects on liquid membrane stability. Binary interaction between W/O ratio and aqueous phase pH was also important as the surfactant weight percent increased. The range of each influential variable which was expected to give a stable liquid membrane was determined from single variable experiment.

      • 에멀젼型 液膜에 對한 數式모델 比較硏究

        宋東益,崔相俊 慶北大學校 1983 論文集 Vol.36 No.-

        Two diffusion-controlled mathematical models for emulsion-type liquid membrane, which were proposed by Lightfoot and Ho, and Ihm and Choi, were simulated by solving numerically the coupled moving boundary value problem using Crank-Nicholson implicit method and were compared with the batch experimental data obtained previously for removal of phenol from waste water. The results have shown that Lightfoot and Ho's model which was based on uniform mass transfer resistance inside the emulsion globules was not in good agreement with the experimental data especially at initial time period, but Ihm and Choi's model considering mass transfer resistances in the outer liquid membrane layer and in the inner reacted zone simulataneously, was fitted well the experimental data for nearly entire time period. Therefor, Ihm and Choi's model taking into consideration the outer mass transfer resistance layer of liquid membrane was thought to be more predictive and more precise than Lightfoot and Ho's one in the emulsion-type liquid membrane.

      • 液膜法에 依한 Cu(Ⅱ) 이온의 抽出에 關한 硏究

        崔相俊,宋東益 慶北大學校 1984 論文集 Vol.37 No.-

        Water in oil (W/O) emulsion was prepared from aqueous hydrochloric acid solution and xylene containing both benzoyl acetone as a carrier and Span 80 as a surfactant. After dispersing W/O emulsion into a third aqueous phase, external buffer solution dissolving copper ion, water in oil in water (W/O/W) emulsion was manufactured. Copper ion extraction was performed using this W/O/W emulsion system. Effects of characteristic of external aqueous solution on emulsion stability were investigated and optimum extraction conditions were determined using the results of extraction experiment. Optimum conditions were as follows; surfactant concentration was 2wt. %, internal aqueous hydrochloric acid concentration 0.3M, carrier concentration 0.02M, stirring speed 200 rpm, pH of external aqueous buffer solution 5.5 and volume ratio of external aqueous buffer solution to emulsion phase 6. When initial copper concentration of external aqueous buffer solution was 500 ppm, copper ion could be removed to 99% from external solution in 30 min.

      • KCI등재

        한국어 판 구조화 임상면담도구 개발 : 신뢰도 연구

        한오수,안준호,송선희,조맹제,김장규,배재남,조성진,정범수,서동우,함봉진,이동우,박종익,홍진표 대한신경정신의학회 2000 신경정신의학 Vol.39 No.2

        연구목적: 정신장애의 정확한 진단과 평가는 임상에서뿐만 아니라 신뢰성 있는 연구를 위해서도 매우 중요하다. Structured Clinical Interview for DSM-IV(SCID)는 임상전문가들이 사용하는 진단도구로서, 비교적 짧은 시간에 정확한 진단을 내릴 수 있다. 본 연구는 한국어판SCID를 개발하고 그 신뢰도를 평가하기 위해 수행되었다. 방법: 국문학자가 포함된 번역위원회를 통하여 연구용판 SCID를 번역한 후, 정신과 의사 2인과 임상심리학자 1인에게 한국어판SCID 실시방법을 교육시킨 뒤 한국어판SCID를 이용한 면담의 평가자간 신뢰도 (interrater reliability)를 검증하였다. 면담 대상은 1999년 2월에서 3월까지 2개 병원 정신과에 치료중인 환자 90명(남:41명, 여:29명)이었다. 결과: 현재 장애(current disorder) 평가에서 주요 우울장애, 기분부전장애, 정신분열병, 알코올 남용 및 의존, 기타 물질 남용 또는 의존, 여러 불안장애들 및 섭식장애 등과 같은 대부분 장애의 kappa값은 .70이상으로 매우 높았다. 그 이외의 양극성 장애, 망상장애, 광장공포증, 감별 불능 신체화 장애 및 건강염려증의 kappa값도 .69에서 .40사이로 수용할 수 있는 정도였다. 평생 장애(lifetime disorder)에서는 양극성 장애(k=.69)와 감별 불능 신체화장애(k=.59)를 제외한 다른 모든 장애의 kappa값이 .70이상이었다. K-SCID 면담시 Ⅰ축 질환에 대하여 흔하게 다중 진단이 내려졌으며, 평균 진단 수는 1.5∼1.7개로 나타났다. 결론: 한국어판 SCID는 신뢰도가 높은 진단도구로 생각되며, 향후 정신질환의 정확한 진단과 임상연구에 유용하게 사용될 수 있다. Objectives: Accurate diagnosis and assessment for psychiatric disorders is crucial for research, as well as for clinical practice. Structured Clinical Interview for DSM-Ⅳ(SCID-RV) is a less time-consumimg and more accurate structured diagnostic interview form. It can be used by clinical professions and is known for a reliable diagnostic tool. Present study was conducted to develop Korean version of SCID-RV and to test the inter-rater reliability. Methods: The authors have translated original SCID-RV into Korean, and revised in parallel with sociocultural background of Korea. Ninety patients from two psychiatric hospitals, both outpatient and inpatient, were interviewed and rated independently by three raters. Results: The kappa coefficients for most of illnesses, such as major depressive disorder, dysthymia, schizophrenia, alcohol abuse and dependency, anxiety disorder and eating disorder were excellent(>0.70) in the evaluation of current disorders. And the kappa coefficients for bipolar disorder, delusional disorder, agoraphobia, undifferentiated somatoform disorder, and hypochondriasis were acceptable(>0.40) in the evaluation of current disorders. In the evalua-tion of lifetime disorders, the concordant rates of all the diagnoses except bipolar disorder and undifferentiated somatoform disorder were excellent. Lack of hierarchy in DSM-Ⅳ allows for multiple Axis I diagnoses. Mean numbers of Axis I diagnoses per subject assigned by the three raters were 1.5-1.7. Conclusions: Our findings confirm that SCID-RV yields highly reliable diagnoses. SCID-RV is recommended for accurate diagnosis in clinical practice and research on psychiatric disorders.

      • KCI등재

        저농도 실내공기 정화를 위한 염소화 및 방향족 탄화수소의 광촉매 분해

        조완근,권기동,최상준,송동익 한국환경과학회 2004 한국환경과학회지 Vol.13 No.9

        This study evaluated the technical feasibility of the application of TiO₂ photocatalysis for the removal of volatile hydrocarbons(VHC) at low ppb concentrations commonly associated with non-occupational indoor air quality issues. A series of experiments was conducted to evaluate five parameters (relative humidity (RH), hydraulic diameter (HD), feeding type (FT) of VHC, photocatalytic oxidation (PCO) reactor material (RM), and inlet port size (IPS) of PCO reactor) for the PCO destruction efficiencies of the selected target VHC. None of the target VHC presented significant dependence on the RH, which are inconsistent with a certain previous study that reported that under conditions of low humidity and a ppm toluene inlet level, there was a drop in the PCO efficiency with decreasing humidity. However, it is noted that the four parameters (HD, RM, FT and IPS) should be considered for better VHC removal efficiencies for the application of TiO₂ photocatalytic technology for cleansing non-occupational indoor air. The PCO destruction of VHC at concentrations associated with non-occupational indoor air quality issues can be up to nearly 100%. The amount of CO generated during PCO were a negligible addition to the indoor CO levels. These abilities can make the PCO reactor an important tool in the effort to improve non-occupational indoor air quality.

      • 한국 대도시 고령자의 체격, 체력 및 운동실태와 운동 프로그램개발에 관한 연구

        김경지,강동원,장주호,전익기,윤우상,곽은창,박영진,유재충 경희대학교 사회체육연구소 1996 體育科學論叢 Vol.- No.9

        The purpose of this study was to investigate the patterns of the health related variables, and physical characteristics and physical fitness of the elderly people in order to provide a exercise program. The data about the health related variables were collected through the personal interview, and the data about physical charateristics and physical fitness (height, weight, % body fat, blood pressure, pulse rate, grip stength, trunk flexion, side step test, 2 min, harvard step test) of 373 elderly people living Seoul and kyungkee area were collected. The conclusions of this study can be summarized as follow; 1. The test results about smoking, drinking, sleeping and self-evaluation of health revealed that the elderly people have self-confidence about their health. 2. Not many elderly people participate the proper exercise program even though they recognize the need of exercise. 3. The results showed that the elderly people do not pay much attention to the intensity of the exercise. 4. Muscle strength training for leg and the lower back and cardio-vascular endurance training was recommended to reduce the risk of varius problems caused by aging. 5. A exercise program was suggested for the elderly people.

      • KCI등재

        생물검정법을 이용한 하수슬러지 장기연용 토양의 독성평가

        남재작,이승환,권순익,홍석영,임동규,고문환,송범헌 한국환경농학회 2004 한국환경농학회지 Vol.23 No.4

        생물검정법에 의한 토양 내 독성평가의 유용성을 확인하기 위해 두 종류의 하수슬러지를 7년간 연용한 토양을 Microtox^(?) 생물검정법과 상추종자 뿌리 신장법을 사용하여 독성을 평가하였다. 이 방법들은 하수오니의 종류나 시용량에 따른 토양의 독성 정도를 잘 평가 할 수 있었다. 상추종자 뿌리 신장법은 특별한 장비나 복잡한 처리 없이도 유의성 있는 결과를 구할 수 있었고 Microtox^(?) 검정법은 전반적으로 재현성과 감도에서 유의성이 있었으며 또한 유기화합물에 대한 종합적인 평가도 가능하였다. 하수오니와 같이 다양한 화합물이 혼재되어 있는 유기성 자원의 토양 시용시 기존의 제한된 화학성분의 토양 분석법만으로는 독성평가에 한계가 있고 또 개별적으로는 별 영향이 없더라도 여러 화합물이 복합적으로 존재할 때 나타나는 독성작용에 대한 평가는 더욱이 어렵다. 그러므로 이러한 영향을 종합적으로 평가할 수 있는 생물검정법이 토양의 독성 평가에서 화학분석법을 보완하는 평가방법으로서의 중요성은 충분하다고 할 수 있다. 그리고 생물독성법의 유용성을 높이기 위해서는 생물검정법의 시료 추출방법 개선과 실험의 재현성을 높이기 위한 노력이 필요하리라 생각된다. 따라서 이런 생물검정법의 많은 제약에도 불구하고 환경의 종합적인 평가에 있어서 생물검정법의 중요성은 대단히 크며 직접적으로 생물을 이용하는 방법뿐만 아니라 유전독성 평가 방법 등 다양한 방법들이 환경독성 평가에 응용될 수 있을 것으로 판단된다. Bioassay was employed to assess toxicity of soil which had been treated with sewage sludges for seven years. The Microtox^(?) and root elongation test of lettuce (Lactuca Saliva) elucidated that the intensity of soil toxicity was closely related with the types and amount of sewage sludges applied. Both bioassay methods proved to be useful in an assessment of soil toxicity and were consistent to some extent with the conventional chemical analysis methods. EC_(50) values resulted from Microtox^(?) were highly correlated with concentration of heavy metals in soils amended with sewage sludges : Cu (r²= 0.86^(**)), Cr (r²= 0.84^(**)), Ni (r²= 0.83^(**)), and Zn (r²= 0.69^(**)). This demonstrated that both bioassay techniques could be employed as tools for soil toxicity assessment when the soil was exposed to solid wastes such as sewage sludge.

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