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- 저자 : Deng Qihuang (검색결과 6 건)
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Deng Qihuang,Zhou Junquan,Li Xianping,Feng Yefeng,Liang Yurun,Liu Qihang 한국물리학회 2021 Current Applied Physics Vol.22 No.-
Polymer/conductive ceramic composites with high dielectric constant have become research hotspot of dielectric capacitor materials. However, the conductivity and dielectric loss increase when high dielectric constant is achieved. In order to reconcile high dielectric constant and low dielectric loss, in this study, poly (vinylidene fluoride) (PVDF)/chromium carbide (Cr2C3)/montmorillonite (MMT) ternary composite films were prepared by solution cast. Dielectric response based on interfacial polarization was improved and dielectric constant of composites was increased. MMT ceramic was used to suppress interface leakage current. Compared with PVDF/ Cr2C3 composites, the conductivity and dielectric loss of ternary composites were reduced.
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Chen, Ke,Chen, Youhu,Deng, Qihuang,Jeong, Seol-Ha,Jang, Tae-Sik,Du, Shiyu,Kim, Hyoun-Ee,Huang, Qing,Han, Cheol-Min Elsevier 2018 Materials letters Vol.229 No.-
<P><B>Abstract</B></P> <P>Herein, strong and biocompatible Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>z</SUB>-enhanced poly(lactic acid) (PLA) nanocomposite membranes were prepared. The interface of the Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>z</SUB> nanosheets with the hydrophobic PLA matrix was mediated using n-octyltriethoxysilane (OTES). The optimized ultimate tensile strength of the OTES-Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>z</SUB>/PLA nanocomposite membrane was 72 MPa (33% higher than that of a pure PLA membrane). The addition of Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>z</SUB> enhanced the biological properties of the membrane, including the <I>in vitro</I> adhesion, proliferation, and osteogenic differentiation of MC3T3-E1 mouse preosteoblasts.</P> <P><B>Highlights</B></P> <P> <UL> <LI> First effort to introduce MXene into polymer matrix for tissue engineering. </LI> <LI> A robust strategy developed to prepare Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>z</SUB>-enhanced PLA nanocomposite. </LI> <LI> Successful interfacial mediation between hydrophilic Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>z</SUB> nanosheets and hydrophobic PLA. </LI> <LI> Intriguing future of this strong and biocompatible nanocomposite for GBR membrane. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
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Ni Nanoparticle Anchored on MWCNT as a Novel Electrochemical Sensor for Detection of Phenol
Yajing Wang,Jiankang Wang,Zhongping Yao,Chenyu Liu,Taiping Xie,Qihuang Deng,Zhaohua Jiang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.11
Increasing active sites and enhancing electric conductivity are critical factors to improve sensing performance toward phenol. Herein, Ni nanoparticle was successfully anchored on acidified multiwalled carbon nanotube (a-MWCNT) surface by electroless plating technique to avoid Ni nanoparticle agglomeration and guarantee high conductivity. The crystal structure, phase composition and surface morphology were characterized by XRD, SEM and TEM measurement. The as-prepared Ni/a-MWCNT nanohybrid was immobilized onto glassy carbon electrode (GCE) surface for constructing phenol sensor. The phenol sensing performance indicated that Ni/a-MWCNT/GCE exhibited an amazing detection performance with rapid response time of 4s, a relatively wide detection range from 0.01 mM to 0.48 mM, a detection limit of 7.07 μM and high sensitivity of 566.2 μAmM -1 cm -2. The superior selectivity, reproducibility, stability and applicability in real sample of Ni/a-MWCNT/GCE endowed it with potential application in discharged wastewater.
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Xiaofeng Xia,Junquan Zhou,Huimin Ding,Qin Li,Maolin Bo,Qihuang Deng,Yefeng Feng 대한금속·재료학회 2021 ELECTRONIC MATERIALS LETTERS Vol.17 No.1
Dielectric constants of polymer/conductor composites are often high, owing to strong interface interaction in those composites. They can be used for dielectric energy storage, but they usually have high dielectric loss and conductivity. In order toreduce the dielectric loss and conductivity in poly(vinylidene fluoride-hexafluoropropylene) (P(VDF-HFP))/V2AlC MAXcomposites, in this study, we explored the novel P(VDF-HFP)/V2AlC MAX/montmorillonite (MMT) ternary composites. Compared with binary composites, the ternary composites showed the mildly reduced dielectric constant, significantlydecreased dielectric loss and conductivity. Using highly-conductive V2AlCMAX filler aimed at taking advantage of thepolymer/MAX interface polarization to increase the dielectric response of composites. Employing well-insulating MMTfiller aimed at reducing the interface electric leakage conduction. At 1 kHz, the outstanding ternary composite with 2 wt%MMT and 20 wt% MAX could exhibit a high dielectric constant of ca. 27 and low dielectric loss of ca. 0.21. This workmight offer a new research idea for the construction of high-performance composite dielectric films containing modernMAX ceramic fillers.
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Qin Li,Junquan Zhou,Yanhui Chen,Xiaofeng Xia,Maolin Bo,Qihuang Deng,Yefeng Feng 한국고분자학회 2020 Macromolecular Research Vol.28 No.13
Polymer/conductor composite dielectric materials have a high dielectric constant. In recent years, composite dielectrics have become a study hotspot in highdensity energy storage capacitors. However, high dielectric loss and high electrical conductivity make the application of the composite materials very limited. In order to obtain composite materials with high dielectric constant, low dielectric loss and low conductivity, we added the insulating boron nitride (BN) filler into polymer/Cr2AlC composites. As a conductive filler, Cr2AlC ternary-layered-compound (MAX) ceramic has an interface polarization with the polymer matrix, thereby increasing the dielectric constant of the composites. The insulating BN has a very low electrical conductivity, which can effectively reduce the electrical conductivity and dielectric loss of the composites. Compared with the binary polymer/Cr2AlC composite materials, the ternary polymer/Cr2AlC/BN composite materials can achieve the low dielectric loss and low conductivity as well as properly-lowered dielectric constant. The ternary composite material filled with 10 wt% Cr2AlC and 2 wt% BN has a dielectric constant of about 30, a dielectric loss of about 0.7 and a conductivity of about 4.6×10- 7 S m-1 at 100 Hz. In this work, high-performance composite dielectrics were prepared through good cooperation between conductive and insulating ceramic fillers, which might provide an idea for design of promising energy storage capacitors.
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Peiyao Chen,Binghe Chen,Ben Qin,Jiangqiong Wang,Qihuang Deng,Yefeng Feng 한국고분자학회 2021 Macromolecular Research Vol.29 No.9
Present work aimed at studying the effect of montmorillonite (MMT) on dielectric and conductive properties of composites based on polymer/hafnium carbide (HfC) mother composite system. Polymer/HfC/MMT composite films based on double-filler modification strategy were prepared by solution cast. To obtain control group, binary polymer/HfC composite films were prepared. MMT ceramic had excellent insulation property, which could suppress interface leakage current and thus reduce dielectric loss of composites. Compared with binary system, ternary system could show better overall electric features including mildly reduced permittivity, obviously reduced dielectric loss and conductivity. Optimized ternary composite bearing 3 wt% HfC and 3 wt% MMT exhibited a high permittivity of 34, low dielectric loss of 0.33 and low conductivity of 5.5 × 10-7 S m-1 at 100 Hz. This research might enable the fabrication of advanced composite dielectrics.
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