e - beam 증발법으로 제조된 비정질 WO3 박막과 전해질 계면으로 삽입되는 리튬의 층간 반응에 관한 전기화학적 특성

민병철,손태원,주재백 ( Byoung Chul Min,Tae Won Sohn,Jeh Beck Ju ) 한국공업화학회 1997 공업화학 Vol.8 No.6

본 연구에서는 1M LiClO₄/PC 유기 용액 중에 존재하는 리튬 이온의 층간 반응에 의하여 전기 발색 현상을 나타내는 전자-선 증발법으로 제조된 비정질의 텅스텐 산화물 박막과 전해질 계면에서의 전기화학적 특성들을 연구하기 위하여 음극 Tafel 분극법, 순환 전류-전위법 및 전기량 적정법 등의 전기화학 측정법과 X선 회절 분석법을 이용한 박막의 결정 상태 조사 등이 수행되었다. 특히 다중 순환 전류-전위 곡선으로부터 리튬 이온의 층간 반응은 발색 반응에 대한 인가 과전압이 약 1.0V 이내에서는 안정된 소 · 발색의 가역적 현상을 나타내었으나, 발색 반응에 대한 인가 과전압이 1.5V일 때는 발색 시 삽입된 박막 내부의 리튬이 소색 시 완전히 빠져 나오지 못하여, 박막 내부에 리튬이 축적되는 현상을 나타내었으며, 적은 순환 횟수임에도 불구하고 소 ·발색의 전류 밀도가 감소되는 것이 조사되어 발색에 필요한 인가 과전압의 한계가 존재함을 알 수 있었다. This work was performed to study the characteristics of electrochanical intercalation reactions occurring at the interface between the organic electrolyte and tungsten trioxide thin film (thickness of 4000Å) prepared by e-beam evaporation method as cathodically coloring oxide with regard to the electrochromism by the intercalating reactions of the lithium cation in the 1M LiClO₄/PC organic solution. The characteristics of electrochemical intercalation reactions were investigated by various DC electrochemical methods such as cathodic Tafel polarization test, multiple and the single sweep cyclic voltammetry and the coulometry titrations method. The surfaces of thin films were observed with the patterns of X ray diffraction after the coloring and bleaching reactions. In comparison with the previous results that WO₃ thin film intensely detached from the surface of electrode when the hydrogen cation was intercalated into WO₃ thin film in the O.1N H₂SO₄ aqueous solution, the intercalation reaction of lithium cation into WO₃ thin film in the 1M LiClO₄/PC organic solution was shown that the stable bleaching and coloration was appeared within 1.0V of the applied overpotential. When the overpotential of electrochromic reaction for lithium cation in the 1M LiClO₄/PC organic solution had been applied up to 1.5V, the accumulation phenomenon of lithium in amorphous WO₃ thin film layer occurred because the inserted lithium into amorphous WO₃ thin layer for coloring process was not fully removed from the thin layer to the electrolyte during bleaching process. It was found that there is a limitation of applied overpotential for coloring process by the reduction of the current densities of bleaching and coloration after few number of coloring and bleaching cycles.

암의 세계

민병철,Min, Byeong-Cheol 한국과학기술단체총연합회 1981 과학과 기술 Vol.14 No.10

부분강절 뼈대구조의 비탄성 좌굴해석

민병철,Min, Byoung Cheol 한국강구조학회 2014 韓國鋼構造學會 論文集 Vol.26 No.3

본 연구에서는 부분강절 뼈대구조물의 비탄성 좌굴해석기법을 제시하기 위하여, 이전의 연구[16]에서 제시되었던 부분강절 뼈대구조의 엄밀한 강도행렬과 선형해석을 위한 탄성 및 기하학적 강도행렬을 도입하고 비탄성 좌굴해석을 위해 도로교시방서의 극한내하력 기준과 EF법을 이용하여 부분강절 뼈대구조의 비탄성 좌굴해석 프로그램을 새롭게 개발하였다. 본 연구에서 제시한 부분강절 뼈대구조의 접선강도행렬은 안정함수를 사용함에 따라 부재 당 하나의 요소만으로 정확한 비탄성 좌굴해석 결과를 얻을 수 있으며 고유벡터를 이용하여 비탄성 좌굴형상을 얻을 수 있는 장점을 갖는다. 또한, 엄밀한 접선강도행렬에 대해 Taylor 전개를 수행하여 4차항까지 고려함으로서 탄성 강도행렬과 기하학적 강도행렬을 유도하고 선형화된 좌굴해석기법을 제시하였다. 결국, 접선강도행렬을 이용한 비선형 해석프로그램(M1)과 탄성 및 기하학적 강도행렬을 이용한 선형 해석프로그램(M2)이 개발되었으며 이를 이용하여 부분강절로 연결된 뼈대구조물의 비탄성좌굴에 대한 시스템 좌굴하중과 개별부재의 유효좌굴계수를 제시함에 따라 부분강절이 전체 구조계의 좌굴과 개별부재의 유효좌굴길이에 미치는 영향을 다양한 해석예제를 통해 조사하였다. An improved method for evaluating effective buckling length of semi-rigid frame with inelastic behavior is newly proposed. Also, generalized exact tangential stiffness matrix with rotationally semi-rigid connections is adopted in previous studies. Therefore, the system buckling load of structure with inelastic behaviors can be exactly obtained by only one element per one straight member for inelastic problems. And the linearized elastic stiffness matrix and the geometric stiffness matrix of semi-rigid frame are utilized by taking into account 4th terms of taylor series from the exact tangent stiffness matrix. On the other hands, two inelastic analysis programs(M1, M2) are newly formulated. Where, M1 based on exact tangent stiffness matrix is programmed by iterative determinant search method and M2 is using linear algorithm with elastic and geometric matrices. Finally, in order to verify this present theory, various numerical examples are introduced and the effective buckling length of semi-rigid frames with inelastic materials are investigated.

일반화된 부분강절을 갖는 뼈대구조물의 안정성 및 P-Δ 해석

민병철,Min, Byoung Cheol 대한토목학회 2013 대한토목학회논문집 Vol.33 No.2

부재간의 연결조건에 따른 다양하고 복잡한 강구조물의 P-${\Delta}$ 해석 및 좌굴 거동특성을 파악하기 위하여, 본 연구에서는 부재의 연결이 회전 및 이동스프링으로 구성된 부분강절(semi-rigid) 뼈대요소의 일반화된 접선강도 행렬을 유도하였고 이로부터 다시 Taylor 전개를 적용하여 탄성강도 행렬과 기하학적 강도행렬을 일반화된 형태로 제시하였다. 이를 위하여, 보-기둥부재의 좌굴조건을 만족시키는 처짐함수로부터 안정함수(stability function)를 유도하였고, 횡변위(sway)를 고려한 힘-변위관계와 적합조건을 고려하여 엄밀한 부분강절 뼈대요소의 접선강도행렬을 제시하였다. 다양한 수치해석 예제에 대해 타 연구자의 해석 결과 및 본 연구의 선형 및 비선형 해석이론을 통한 좌굴해석 결과를 비교하여 본 연구의 타당성과 부분강절 뼈대구조물의 좌굴거동 특성을 제시하였다. For stability design and P-${\Delta}$ analysis of steel frames with semi-rigid connections, the explicit form of the exact tangential stiffness matrix of a generalized semi-rigid frame element having rotational and translational connections is firstly derived using the stability functions. And its elastic and geometric stiffness matrix is consistently obtained by Taylor series expansion. Next depending on connection types of semi-rigidity, the corresponding tangential stiffness matrices are degenerated based on penalty method and static condensation technique. And then numerical procedures for determination of effective buckling lengths of generalized semi-rigid frames members and P-${\Delta}$ and shortly addressed. Finally three numerical examples are presented to demonstrate the validity and accuracy of the proposed method. Particularly the minimum braced frames and coupled buckling modes of the corresponding frames are investigated.

통나무집의 동절기 실내 온열환경 요소의 측정과 온열감 평가에 관한 연구

민병철,전지현,국찬,Min, Byeong-Cheol,Jeon, Ji-Hyeon,Kook, Chan 한국주거학회 2007 한국주거학회 논문집 Vol.18 No.2

Various buildings constructed by environmentally friendly resources are being built in KOREA. Especially as the wood has distinctive ecological merits in comparison with reinforced concrete and brick, the buildings made by the wood are acknowledged with its superiority of ecological value. Enough field studies for their thermal environment, however, haven't been done. In this study, to investigate indoor environmental condition and occupants' response to it of Log Cabin in Gyeongsangnam-do Hamyang Country Jirisan Natural Recreation Forest, examination of indoor thermal environment and field subjective evaluation have been done in that fundamental information of thermal environment characteristics can be suggested. The results are following; 1) Thermal environment of the Log Cabins; Indoor and outdoor mean dry bulb temperature were $21.9^{\circ}C$ and $-3.1^{\circ}C$, and Indoor and outdoor average relative humidity were 25.8% and 52.1%. These results are below ASHRAE; dry bulb temp. $22.0^{\circ}C$, humidity 30%, and above domestic standards; dry bulb temp. $18{\sim}20.0^{\circ}C$, humidity $40{\sim}60%$. 2) Result of subjective evaluation; Thermal sensation and its comfort were evaluated as 'slightly uncomfortable' because of 'slightly warm'. And humid sensation and its comfort were evaluated as 'slightly uncomfortable' because of 'slightly warm'. 3) Result of vertical temperature and humidity; Vertical temperature difference from head to ankle was $0.54^{\circ}C$ which means most occupants may feel comfortable.

자외선에너지를 ( UV - C ) 를 이용한 유기인계 화합물의 분해

민병철,권태무,김병관,김종향 ( Byoung Chul Min,Tae Moo Kyun,Byung Kwan Kim,Jong Hyang Kim ) 한국공업화학회 1997 응용화학 Vol.1 No.1

UV 조사에 의한 방향족오염물의 분해

민병철,김종향,김병관 ( Byoung Chul Min,Jong Hyang Kim,Byung Kwan Kim ) 한국공업화학회 1997 공업화학 Vol.8 No.3

방향족 오염물을 UV산화- 고도산화처리기술로 처리할 때, 여러 가지 반응조건에 따른 분해효율에 대해 고찰하였다. 벤젠 50pmm, 에틸벤젠 150ppm, 크실렌 250ppm을 각각 초기농도로하여 UV조사 하에서 시간변화에 따른 분해실험을 행한 결과, 반응 1시간 후 약 95% 이상의 분해율을 나타내었으나, 톨루엔의 경우에는 43%의 분해율을 보였다. 단일성분이 혼합성분에서 보다 분해가 좋았으며, pH변화에서는 벤젠은 pH변화에 관계없이 분해가 잘되었으며, 에틸벤젠 92%(pH 4.0), 90%(pH 6.4), 91%(pH 10.0), 크실렌 95%(pH 4.0), 90%(pH 6.4), 92%(pH 10.0), 그러나 톨루엔은 80%(pH 4.0), 43%(pH 6.4), 70%(pH 10.0)의 분해율을 나타내었다. 방향족 오염물의 TOC 감소는 에틸벤젠을 제외하고는 유사 1차 반응속도식에 일치하였으며, 이로부터 속도상수를 결정할 수 있었다. Aromatic pollutants(benzene, toluene, ethylbenzene and xylenes) were photodegraded by using a UV oxidation and the rates of degradation were investigated under various reaction conditions. Each of the solution containing 50 ppm benzene, 150 ppm ethylbenzene and 250 ppm xylenes was found UV-photodegraded over 90% in 1 hour of reaction time, wheras the only was 43% of degradation was obtained with 350 ppm toluene solution. A single component solution was more degradable than a mixed component solution and benzene was almost photodegraded at a pH 4.0, 6.4 and 10.0 after reaction time is 1 hr, ehtylbenzene was photodegraded about 92%(pH 4.0), 90%(pH 6.4) and 91%(pH 10.0), xylenes was photodegraded about 95%(pH 4.0), 90%(pH 6.4) and 92%(pH 10.0), but toluene was photodegraded about 80%(pH 40), 43%(pH 6.4) and 70%(pH 10.0), respectively. Kinetics studies show that the rate of decay in TOC(total organic carbon) were pseudo first-order rate except ethylbenzene, and then we could evaluate mineralization rate constants(k) of aromatics.

친환경 계면활성제 Potassium Cocoyl Glycinate (PCG)가 알칼리 전처리된 백합나무의 효소 당화에 미치는 영향

민병철(Byeong-Cheol Min),정수빈(Subin Jeong),송우용(Woo-Yong Song),성현아(Hyun-A Seong),신수정(Soo-Jeong Shin) 한국펄프·종이공학회 2018 펄프.종이기술 Vol.50 No.1

Potassium cocoyl glycinate (PCG) as a green surfactant was used to evaluate the possibility to substitute petrochemical surfactants for productivity improvement of enzymatic hydrolysis. Yellow poplar (Liriodendron tulipifera L. ) was subjected to NaOH (0.1%, 1.0% and 10.0%) pretreatment at 121°C for 60 min. Pretreated substrate (5.0% w/v) was hydrolyzed by enzyme under the variety PCG concentrations up to 0.3%. The optimum dose of PCG was around 0.03% at which it resulted in the highest total sugar production for all pretreatment conditions. The total sugar production of pretreated yellow poplar with 0.1%, 1.0% and 10.0% of NaOH increased from 2.3, 20.1, 20.8 g/L to 7.7, 25.7, 31.8 g/L under 0.03% of PCG concentration at 72 h hydrolysis. The effect of PCG to improve enzymatic hydrolysis was significantly promising as compared to other researches applying surfactants for hydrolysis. In conclusion, application of PCG was a promising alternative to replace petrochemical surfactants in enzymatic hydrolysis processes due to the high sugar production and positive influence on the ecosystem.

e-beam 증발법으로 제조된 비정질 WO₃박막과 전해질 계면으로 삽입되는 리튬의 층간 반응에 관한 전기화학적 특성

민병철,손태원,주재백,Min, Byoung-Chul,Sohn, Tae-Won,Ju, Jeh-Beck 한국공업화학회 1997 공업화학 Vol.8 No.6

본 연구에서는 1M $LiClO_4/PC$ 유기 용액 중에 존재하는 리튬 이온의 층간 반응에 의하여 전기 발색 현상을 나타내는 전자-선 증발법으로 제조된 비정질의 텅스텐 산화물 박막과 전해질 계면에서의 전기화학적 특성들을 연구하기 위하여 음극 Tafel 분극법, 순환 전류-전위법 및 전기량 적정법 등의 전기화학 측정법과 X선 회절 분석법을 이용한 박막의 결정 상태 조사 등이 수행되었다. 특히 다중 순환 전류-전위 곡선으로부터 리튬 이온의 층간 반응은 발색 반응에 대한 인가 과전압이 약 1.0V 이내에서는 안정된 소 발색의 가역적 현상을 나타내었으나, 발색 반응에 대한 인가 과전압이 1.5V일 때는 발색 시 삽입된 박막 내부의 리튬이 소색 시 완전히 빠져 나오지 못하여, 박막 내부에 리튬이 축적되는 현상을 나타내었으며, 적은 순환 횟수임에도 불구하고 소 발색의 전류 밀도가 감소되는 것이 조사되어 발색에 필요한 인가 과전압의 한계가 존재함을 알 수 있었다. This work was performed to study the characteristics of electrochemical intercalation reactions occurring at the interface between the organic electrolyte and tungsten trioxide thin film (thickness of $4000{\AA}$) prepared by e-beam evaporation method as cathodically coloring oxide with regard to the electrochromism by the intercalating reactions of the lithium cation in the 1M $LiClO_4/PC$ organic solution. The characteristics of electrochemical intercalation reactions were investigated by various DC electrochemical methods such as cathodic Tafel polarization test, multiple and the single sweep cyclic voltammetry and the coulomety titrations method. The surfaces of thin films were observed with the patterns of X ray diffraction after the coloring and bleaching reactions. In comparison with the previous results that $WO_3$ thin film intersely detached from the surface of electrode when the hydrogen cation was intercalated into $WO_3$ thin film in the o.1N $H_2SO_4$ aqueous solution, the intercalation reaction of lithium cation into $WO_3$ thin film in the 1M $LiClO_4/PC$ organic solution was shown that the stable bleaching and coloration was appeared within 1.0V of the applied overpotential. When the overpotential of electrochromic reaction for lithium cation in the 1M $LiClO_4/PC$ organic solution had been applied up to 1.5V, the accumulation phenomenon of lithium in amorphous $WO_3$ thin film layer occurred because the inserted lithium into amorphous $WO_3$ thin layer for coloring process was not fully removed from the thin layer to the electrolyte during bleaching process. It was found that there is a limitation of applied overpotential for coloring process by the reduction of the current densities of bleaching and coloration after few number of coloring and bleaching cycles.

부분강절로 연결된 평면뼈대구조의 엄밀한 접선강도행렬 및 안정성 해석프로그램 개발

민병철,경용수,김문영,Min, Byoung Cheol,Kyung, Yong Soo,Kim, Moon Young 한국강구조학회 2008 韓國鋼構造學會 論文集 Vol.20 No.1

일반적인 강구조물의 연결은 강절(rigid) 또는 활절(hinge)로 취급되고 있으나 실제 강구조물은 연결부위에서 부재간의 상대적인회전이 허용됨으로 인해 부분강절(semi-rigid)의 특성을 갖게 된다. 본 연구에서는 부분강절을 회전스프링으로 가정하여 부재 단부에 적용시킨 평면 뼈대구조물의 엄밀한 접선강도행렬을 유도하고 이를 다시 탄성강도행렬과 기하학적 강도행렬로 분리 유도함으로써 부분강절을 갖는 평면 뼈대구조물의 안정성해석을 위한 일반화된 해석방법을 제시하고자 한다. 이를 위하여, 보-기둥부재의 좌굴조건을 만족시키는 처짐함수로부터 안정함수(stability function)를 유도하고, 횡변위(sway)를 고려한 힘-변위관계와 적합조건을 고려하여 정확한 접선강도행렬을 제시하였다. 본 연구의 타당성과 실용성 제고를 위해 두 가지 방법에 의한 수치해석프로그램을 개발하였고 다양한 해석예제를 통해, 타 연구자 해석 결과와 비교하고 부분강절이 구조물의 좌굴강도에 미치는 영향에 대하여 조사한다. Generally the connection of members is defined as hinge or rigid. But, real joints on structure have to be considered semi-rigid connections because this permits relative rotation for members on joints. The purpose of this study is to derive a generalized tangential stiffness matrix of frames with semi-rigid connections and to develop a buckling analysis program. For the exact stiffness matrix, an accurate displacement field is introduced using an equilibrium equation for beam-columns under the bending and axial forces. Also, stability functions that consider sway deformation and force-displacement relations with rotational spring on ends were defined. In order to illustrate the accuracy of this study and the characteristics of semi-rigid for system buckling load, samples of angle-, portal- and 3-story frames with semi-rigid connections are presented, where the proposed approach is found to be in excellent agreement with other research results. Meanwhile, the application of codes such as Eurocode 3 and LRFD led to significant inaccuracies.