Synthesis and Properties of Asymmetrical Zinc-phthalocyanines Containing a Siloxane End-group Linked with Alkyl Spacers of Different Lengths

홍선미,박종승,Hong, Sun-Mi,Park, Jong S. The Korean Fiber Society 2018 한국섬유공학회지 Vol.55 No.2

Phthalocyanine (Pc), which has an electron-rich, aromatic structure, exhibits excellent optical properties as well as thermal and chemical stability. Numerous Pc derivatives, based on highly conjugated ring systems, have been proposed to facilitate efficient energy or electron transfer. They have been frequently adopted for suitable applications such as sensors and photosensitizers. In this study, we present the synthesis and properties of various asymmetrical zinc-phthalocyanine (ZnPc) derivatives having a siloxane end-group linked with alkyl chain spacers of different lengths. A ZnPc-immobilized ITO electrode was prepared by the direct attachment of the siloxane anchoring group to the oxide surface. The synthesized Pcs and the immobilized Pc surfaces were fully characterized by various techniques. The effect of the alkyl spacer length on the optical and electrochemical properties of the Pc-functionalized electrode is briefly discussed.

비극성 용매에 높은 용해성을 가지는 프탈로시아닌 유도체 합성 및 광학 특성에 대한 연구

홍선미,아닐쿠마무티알라,박종승,Hong, Sun-Mi,Mutyala, Anil Kumar,Park, Jong S. 한국섬유공학회 2016 한국섬유공학회지 Vol.53 No.6

Phthalocyanine (Pc) exhibits excellent thermal, chemical, and physical stability, as well as outstanding absorption and emission properties, which are useful for its application in the fields of color filters, chemosensors, and photosensitizers. However, unsubstituted Pc is insoluble in common organic solvents due to its inherent intermolecular aggregation behavior, and thus needs to be finely dispersed in the presence of dispersants before use. In this article, we present a new Pc derivative, prepared by attaching long aliphatic groups at peripheral positions of Pc, which shows high solubility in most nonpolar solvents, leading to good optical properties. For its synthesis, dodecanyl-zinc Pc (dodecanyl-Zn-Pc) was prepared via direct tetramerization, starting with 4-dodecanyl phthalonitrile as the intermediate. Various characterization techniques were employed to estimate the structural and optical features of dodecanyl-Zn-Pc, including $^1H$ nuclear magnetic resonance, matrix-assisted laser desorption/ionization, and ultraviolet-visual spectrophotometry and fluorimetry. In addition, the morphology of dodecanyl-Zn-Pc film was examined by polarized optical microscopy.

초등학교 성교육 내용에 대한 교사 및 학생의 요구도 조사

홍선미,박신애,Hong, Sun-Mi,Park, Sin-Ae 한국지역사회간호학회 1999 지역사회간호학회지 Vol.10 No.2

This study has developed the sex education contents including new natural family plan, concept and principle by receiving the opinions and advices from professionals and professors on sex education, by amending and supplementing existing teaching materials on sex, and examining the books related with sex education contents that reflect the request of teachers and students, and the lack of sex education teaching materials which have been the reason that needs of school sex education has been highly recognized but not vitalized. The developed sex education contents are 8 areas such as knowing my body right, caring my body, observing the ability of being pregnant, marriage, sexual intercourse, process of pregnancy, miscarriage, and sexual violence, 30 lower areas, and 105 detailed contents in their composition, and here are the results of analyses of the degree of request of nurse teachers and the students on them. The teachers showed highest request in the area of sexual violence(M =4.67), the next was my body care(M=4.44), knowing my body right(M =4.38), process of pregnancy(M=4.13), marriage(M=4.11) and sexual intercoursen (M=3.98), ways of judging the ability of being pregnant(M=3.88), and miscarriage(M=3.72) showed comparative higher request than normal. Not like the teachers, the students showed that they requested Marriage area as the highest need(M=3.04) and next was sexual violence(M=3.02), caring my body(M=3.00) to have been higher than normal. Process of pregnancy(M=2.99), Sexual intercourse(M=2.81), miscarriage(M = 2.77), observation of the ability of being pregnant(M=2.74), and knowing my body right(M=2.70) have been the requests lower than normal. This study showed that sexual violence, marriage, caring my body, were the items most requested by both the leacgers and students and in elementary school the development of sex education teaching materials on natural family plan suitable to the level of development of the children has been requested as it has had no inclusion of the concept of natural family plan, and the students in elementary school are concerned on indirect sexual contents related with physical health like regular exercise rather than direct sexual education contents including sexual intercourse. All these show that they are still so naive on sex. The sense of the teachers on sex has been connected with the level of achievement of sex education of the children as it has been the important cause of deciding the contents of sex education. Therefore the materials developed onesidedly by leaders without reflecting the needs or the preference of the students might be worries of bringing shameful. low quality and negative opinions on sex, and on the other hand the children might lose the concerns and interest on sex education, So the materials should be developed to have the contents of sex education coinciding with the request of the children.

고등학교 시각디자인의 창의력 신장을 위한 북 아트 교육 프로그램 제안

홍선미(Hong Sun-Mi),김양수(Ghim Yahn-shu) 한국디자인학회 2006 한국디자인학회 학술발표대회 논문집 Vol.- No.-

에쮸드(Etude)체험을 통한 Jazz Dance 전공자의 인식변화에 대한 질적 접근

홍선미 ( Sun Mi Hong ) 대한무용학회 2008 대한무용학회논문집 Vol.56 No.-

The purpose of this study shows a cultural phenomenon in which the role of dancers became diversified and those who studied jazz dance participated in various musical performances along with a range of dance musicals. Meanwhile, this study aims to deliver a qualitative approach to obtain a change of cognition which would improve when dancers feel the need for more detailed training methods to better demonstrate the characteristics, not of pure dancing, but of a musical, and are made to experience an "etude", like impromptu actors used in plays. Regarding research methods, the study made 7 participants- who currently major in jazz dance, had ever participated in a musical performance more than once, and never experienced an etude- experience the etude for 12 weeks. Concerning the analysis, the study reflected observations daily for 2 participants (one with a doctoral degree and the other in a doctoral course) along with results from the classification by area of an inductive analysis through an in-depth interview and the preparation of a personal report. Then, the study gained the following four results, involving first, perception of concentration, second, an increase in patience, third, the acquisition of confidence, and fourth, the perception of professionalism. Therefore, the study reached the conclusion that it is necessary for jazz dancers who pursue a dramatic musical, to train in how to arouse `emotion` rather than to command techniques through physical training. Namely, it would be necessary to conduct follow-up research into a training methodology enabling dancers to demonstrate their inner expressions suited to situations and roles.

지역사회 네트워크 중심 통합 사례관리에 대한 탐색적 연구

홍선미(Hong, Seon-Mee),하경희(Ha, Kyung-Hee) 한국사회복지행정학회 2009 한국사회복지행정학 Vol.11 No.1

국내 여성전용신용카드의 비쥬얼이미지 선호도 연구

홍선미 ( Hong Sun-mi ),이경현 ( Lee Kyoung-hyeon ) 한국디자인트렌드학회 2012 한국디자인포럼 Vol.35 No.-

지불수단으로서의 편리성과 효율성으로 신용카드 시장은 포화상태에 이르게 되었다. 카드사간 치열한 경쟁구도로 서비스의 차이에 한계를 보이고 있으며 이러한 상황에서 신용카드사의 디자인 영역이 크게 중요시되면서 하나의 경쟁요소로 자리잡았다. 시대가 변할수록 여성소비자들은 신용카드의 기능외에도 미적인 부분에 영향을 받으며 새로운 디자인을 추구하고 있다. 이에 본 연구는 국내 신용카드사의 여성전용신용카드 그래픽이미지에 따른 여성소비자의 태도를 분석하였다. 국내 신용카드사의 여성전용신용카드 디자인현황과 선호하는 디자인을 비교분석한 결과 서로 일치하지 않는 점들이 많은 것으로 나타났다. 여성소비자는 그래픽이미지에서 패턴강조 형태를 가장 선호하였으며 패턴중에서도 꽃잎을 반복적으로 사용한 자연이미지패턴형에 대한 선호도가 높으며, 컬러는 붉은계열을 가장 선호하였고 붉은계열중에서도 자주색을 가장 선호하는 것으로 나타났다. 여성을 대상으로한 설문조사 분석결과 연령별과 직업별에서는 약간씩의 차이만 있을 뿐 크게 다르게 나타나지 않았다. 본 연구 결과를 통해 국내 신용카드사의 여성전용신용카드 그래픽이미지의 중요성을 인식하고 향후 제작방향과 디자인 발전에 필요한 참고 자료로 제공하고자 한다. Marketing activities focused on corporate advertising are the most important element to banks, representative services enterprise. Corporate advertising of domestic banks has shown a relatively passive form compared with that of other industries in intervention and regulation of government before the financial crisis. However, After the financial crisis, advertising of banks has shown a significant change in message strategy. According to trends in M&A and the integration of holding companies between banks, corporate advertising of banks has become a more important position. This study analyzed corporation advertising of domestic banks faced with rapid change in banking market. Comparison with consumer`s minds before and after watching the advertising of banks revealed that the corporation advertising of domestic and foreign banks aimed for different images. The consumers preferred emphasizing on safety and profitability of bank and a mixed form of an emotional type and a rational type in corporation advertising of banks. In terms of expression case, it was demonstrated that consumers think positively emphasizing on using both model and symbolic materials in advertising. In addition, because of friendly image, consumers considered ordinary person more favorable for advertising model than famous person and using of new symbolic materials of each bank was preferred. Age rarely influenced the results of poll due to distinctiveness of the bank industry. It is expected that this study lead to positive impact on corporation image by suggesting appropriate direction of expression method and marketing.

사진 공유 모바일 어플리케이션 디자인 제안 - 혼행족을 중심으로 -

홍선미(주저자) ( Hong Seon Mi(주저자) ),김영은(공동저자) ( Kim Young Eun(공동저자) ),이승재(공동저자) ( Lee Seung Jae(공동저자) ),반영환(교신저자) ( Pan Young Hwan(교신저자) ) 디자인융복합학회 2018 디자인융복합연구 Vol.17 No.6

본 연구에서는 1인가구의 증가로 혼자 여행을 떠나는 혼행족의 비율의 증가에 주목하였다. 혼자 여행하는 사람들이 느끼는 아쉬운 점 중 하나는 멋진 장소에서 남기는 사진일 것이다. 스마트 폰이 현대인의 필수품이 되어 언제든 사용 가능한 환경이 조성되었지만 스마트 폰을 이용하여 혼자 여행하면서 멋진 사진을 남기기란 쉬운 일이 아니다. 이 연구는 혼행족을 위한 App의 기본 서비스 모델을 수립하기 위해, 비즈니스 트랜드 조사와 대표 SNS들의 기능들을 살펴보았으며, SNS를 통해 사용자들의 카메라 기능을 공유하는데 효율적이고 체계화된 서비스를 제안하는데 목적이 있다. 다양한 사용자 조사방법을 통해 사용자들의 불편함을 도출하였으며, 사용자 조사를 통해 얻어진 결과인 언제 어디서든 비슷한 자세와 구도로 찍은 지루한 셀피, 다른 사람이 건성으로 찍어주는 만족스럽지 않은 사진들, 해외여행지에서 언어 장벽으로 인한 사진 촬영 요청의 어려움, 사진 요청을 위해 타인에게 휴대폰을 건네주는데 따르는 도난, 분실의 위험 등을 개선시켜 앱을 기획하였다. 이러한 연구 결과는 특별한 순간에 더 멋진 추억을 기록할 수 있도록 사용자들에게 새로운 관점의 사진촬영의 경험을 줄 수 있을 것이다. This study is led by the ratio of the growth of people among those travelling by them selves. One of the most regretful experiences from many people who travel alone is inability to have memoriable pictures at great places during the trip. Smart phone is essential to modern people and they use what and when they want; however, it is very hard to remain nice pictures during the trip, especially by themselves. In order to establish the basic model service of app for user we research on business trends and foundamental features from SNS; therefore, we introduce efficient and systematic suggestion for sharing features on a camera to the users. Through many research methods, our app prevents a great deal of inconvenient problems and circumstances such as constant pose and boring selfies, unsatisfying picture results from a random photographer, difficulty of asking someone to take pictures of users overseas, and also the risk of losing a mobile device by handing it out to unknown people. The result of this study will give the users a new perspective of picturing and experience that remain their minds for good.

교사 언어에 중심을 둔 교실 관찰을 통한 교사연수-질문

홍선미 ( Sun Mi Hong ) 경희대학교 교육발전연구원(구.교육문제연구소) 2005 慶熙大學校 敎育問題硏究所 論文集 Vol.21 No.1

Verlaine의 무의식적 욕망 속에서 색채 이미지

홍선미 ( Hong Sun-mi ) 한국프랑스어문교육학회 2004 프랑스어문교육 Vol.17 No.-

Nous effectuerons l'analyse «des images des couleurs» utilisées dans son oeuvre par Paul Verlaine, en nous appuyant sur la théorie de la psychanalyse. En effet, les deux méthodes d'investigation du psychisme humain s'efforcent de rendre compte de l'expérience inconsciente du poète (notamment de ses origines, remontant à son enfance) du rapport de cette expérience avec son oeuvre poétiqu , sa correspondant, son journal intime. Au cours de cette étud, nous faisons apparaître que, dans l'inconscient de Verlaine, le désir interdit, provoqué par «l'expérience traumatique» de l'enfance, s'exprime, dans ses oeuvres poétiques en particulier, à travers des «images des couleurs». «L'image de couleur» est, pour le poète, un moyen d'exposer l'image du désir inconscient. Et cette «image de couleur » joue un rôle important dans son désir inconscient. A travers des oeuvres, on doit rappeler l'influence que sa Mère a eux sur l'auteur et les effets à long terme de «l'expérience traumatique de l'enfance». Ces deux données se recouvrent avec des images de différents couleurs. L'oeuvre de Verlaine est en accord avec le poète qui été durant toute sa vie, la fragile victime de plusieurs traumatisme remontant à ses jeunes années. Ainsi, la vision de la femme en général et de l'amour en particulier que Verlaine a pu avoir, est bien liée à des images de différentes couleurs suivant les moments: Le blanc, le vert, le gris, le noir! Dans le même temps, nous nous sommes penchés sur les divers épisodes de sa vie qui sont susceptibles de nous éclairer sur une connaissance approfondie de l'auteur, sur la nature de sa maladie mélancolique et le caractère spécifique de son oeuvre. De cette connaissance, on peut expliquer dans la poésie de Verlaine, son narcissisme sans doute, un processus de sublimation qu'il n'a pas pu mener à son terme, son rôle de voyeur face au comportement des homosexuels et des lesbiennes, son comportement d'alcoolique agressif et désespéré. A travers ses «images de couleur» on peut déceler aussi une forme de transfert de ce spectateur des sentiments, et la fragilité d'un enfant éprouvé par les interprétations qui ont été faites de son oeuvre par ses contemporains et son environnement proche, ainsi que des réflexions désobligeantes qui ont pu êtres faites à propres de cette relation Mères- Fils et Fils-Mères, en raison de la connotation psychanalytique qui a pu en être donnée en s'appuyant sur les fameux complexe d'oedipe, si bien étudié par Freud. Cette étude sur «les images des couleurs» de Paul Verlaine pourrait ouvrir la voie à une autre application de la méthode psychanalytique à d'autres oeuvres telles que la peinture, le cinéma lorsque l'art devient thérapie en employant une «image de couleur».