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산화·환원법에 의한 폐텅스텐 스크랩의 재활용에 관한 기초연구
김상욱,윤지석,김태욱,조봉휘,김인호,김상무,송창빈,Kim, Sang-Uk,Yun, Ji-seok,Kim, Tae-Wook,Cho, Bong-Hwi,Kim, In-Ho,Kim, Sang-Mu,Song, Chang-Bin 한국분말야금학회 2017 한국분말재료학회지 (KPMI) Vol.24 No.1
This study is carried out to obtain basic data regarding oxidation and reduction reactions, originated on the recycling of waste tungsten hard scraps by oxidation and reduction processes. First, it is estimated that the theoretical Gibbs free energy for the formation reaction of $WO_2$ and $WO_3$ are calculated as ${\Delta}G_{1,000K}=-407.335kJ/mol$ and ${\Delta}G_{1,000K}=-585.679kJ/mol$, from the thermodynamics data reported by Ihsan Barin. In the experiments, the oxidation of pure tungsten rod by oxygen is carried out over a temperature range of $700-1,000^{\circ}C$ for 1 h, and it is possible to conclude that the oxidation reaction can be represented by a relatively linear relationship. Second, the reduction of $WO_2$ and $WO_3$ powder by hydrogen is also calculated from the same thermodynamics data, and it can be found that it was difficult for the reduction reaction to occur at $1,027^{\circ}C$, in the case of $WO_2$, but it can happen for temperatures higher than $1127^{\circ}C$. On the other hand, $WO_3$ reduction reaction occurs at the relatively low temperature of $827^{\circ}C$. Based on these results, the reduction experiments are carried out at a temperature range of $500-1,000^{\circ}C$ for 15 min to 4 h, in the case of $WO_3$ powder, and it is possible to conclude that the reduction at $900^{\circ}C$ for 2h is needed for a perfect reduction reaction.
초음파 볼밀링 공정에 의한 용매 점도 특성에 따른 텅스텐계 합금 분쇄 거동
류근혁,소형섭,윤지석,김인호,이근재,Ryu, KeunHyuk,So, HyeongSub,Yun, JiSeok,Kim, InHo,Lee, Kun-Jae 한국분말재료학회 (*구 분말야금학회) 2019 한국분말재료학회지 (KPMI) Vol.26 No.3
Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.