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석탄비산재로부터 합성한 제올라이트를 이용한 유가금속이온의 흡착속도 및 등온 해석
안갑환 ( Kab-hwan Ahn ),이창한 ( Chang-han Lee ),이민규 ( Min-gyu Lee ) 한국환경과학회 2018 한국환경과학회지 Vol.27 No.2
In this study, zeolite (Z-C2) was synthesized using a fusion/hydrothermal method on coal fly ash (FA) discharged from a thermal power plant in the Ulsan area and then analyzed via scanning electron microscopy (SEM) and X-ray diffraction (XRD). The Z-C2 was characterized in terms of mineralogical composition and morphological analysis. The XRD results showed that its peaks had the characteristics of Na-A zeolite in the range of 2θ of 7.18~34.18. The SEM images confirmed that the Na-A zeolite crystals had a chamfered-edge crystal structure almost identical to that of the commercial zeolite. The adsorption kinetics of Cu, Co, Mn and Zn ions by Z-C2 were described better by the pseudo-second-order kinetic model more than by the pseudo-first-order kinetic model. The Langmuir model fitted the adsorption isotherm data better than the Freundlich model did. The maximum adsorption capacities of Cu, Co, Mn and Zn ions obtained from the Langmuir model were in the following order : Cu (94.7 mg/g) > Co (77.7 mg/g) > Mn (57.6 mg/g) > Zn (51.1 mg/g). These adsorption capacities are regarded as excellent compared to those of commercial zeolite.
상수원수의 혼화 및 응집 조건에 따른 DAF pump 장치의 부상분리효율
안갑환 ( Kab Hwan Ahn ),이창한 ( Chang Han Lee ) 한국환경과학회 2011 한국환경과학회지 Vol.20 No.5
This study found that flotation efficiencies for removing algae and micro particles in raw water were optimized on mixing intensity and time of the mixing and flocculation conditions with a continuous DAF system. It is more efficient for mixing intensity at 23.1 s-1 and time at 660 s(Gt value: 15246) to float flocculated floc with the raw water in M water treatment plant. Flotation efficiency was more than about 0.9 when operated pressure and A/S ratio were sustained at 5 kgf·cm-2 and up to 0.056 mL·mg-1. The continuous DAF system made by the study could be continuously operated for 20 days and sustained not exceeding 4 NTU with raw water with low turbidity(13.4~9.8 NTU).
Dewatering Characteristics for Physico-chemical Properties with Sewage Sludge
이창한,안갑환,송승구,Lee, Chang-Han,Ahn, Kab-Hwan,Song, Seung-Koo The Korean Society for Biotechnology and Bioengine 2010 KSBB Journal Vol.8 No.1
In this study, we found that dewatering properties were related with physico-chemical properties such as sludge concentration, pH, and zeta potential with sewage sludge, Ionic contents in digested sludge were in the order of $Ca^{2+}$ (14.2 mg/g) > $Mg^{2+}$ (1.9 mg/g) > $Na^+$ (1.4 mg/g) > $K^+$ (1.0 mg/g). Divalent ion more than monovalent have influenced on physico-chemical and dewatering properties. Floc size distribution in activated (AS) and digested sludge (DS) increased on lower pH range to be near isoelectric point and than specific resistance to filtration (SRF) decreased. A linear increase in SRF ($5.25\times10^{13}\sim2.86\times10^{14}$ m/kg in AS and $6.89\times10^{14}\sim1.09\times10^{15}$ m/kg in DS) was observed throughout low concentration range of 1230~9960 mg/L in AS and 2700~5400 mg/L in DS.