산성광산배수슬러지의 토양 중금속 안정화 적용 가능성

김민석 ( Min Suk Kim ),민현기 ( Hyun Gi Min ),이병주 ( Byeong Joo Lee ),장세인 ( Se In Chang ),김정규 ( Jeong Gyu Kim ),구남인 ( Na Min Koo ),박정식 ( Jeong Sik Park ),박관인 ( Gwan In Bak ) 한국환경농학회 2014 한국환경농학회지 Vol.33 No.2

BACKGROUND: Recent studies using various industrial wastes for heavy metal stabilization in soil were conducted in order to find out new alternative amendments. The acid mine drainage sludge(AMDS) contains lots of metal oxides(hydroxides) that may be useful for heavy metal stabilization not only waste water treatment but also soil remediation. The aim of this study was to investigate the applicability of acid mine drainage sludge for heavy metals stabilization in soils METHODS AND RESULTS: Alkali soil contaminated with heavy metals was collected from the agricultural soils affected by the abandoned mine sites nearby. Three different amounts(1%, 3%, 5%) of AMDS were applied into control soil and contaminated soil. For determining the changes in the extractable heavy metals, CaCl2 and Mehlich-3 were applied as chemical assessments for metal stabilization. For biological assessments, lettuce(Lactuca sativa L.) and chinese cabbage(Brassica rapa var. glabra) were cultivated and accumulation of heavy metals on each plant were determined. It was revealed that AMDS reduced heavy metal mobility and bioavailability in soil, which resulted in the decreases in the accumulation of As, Cd, Cu, Pb, and Zn in each plant. CONCLUSION: Though the high level of heavy metal concentrations in AMDS, any considerable increase in the heavy metal availability was not observed with control and contaminated soil. In conclusion, these results indicated that AMDS could be applied to heavy metal contaminated soil as an alternative amendments for reducing heavy metal mobility and bioavailability.

폐탄광지역 비소오염 농경지(논) 개량 시 복토두께에 따른 비소의 벼전이 및 토양용액 특성

고일하(Il-Ha Koh),권요셉(Yo Seb Kwon),정문호(Mun-Ho Jeong),고주인(Ju In Ko),박관인(Gwan-In Bak),지원현(Won Hyun Ji) 대한자원환경지질학회 2021 자원환경지질 Vol.54 No.4

본 연구에서는 폐금속광산과는 달리 우려기준 전후의 낮은 비소 오염농도 분포특성을 가지는 폐석탄광산 농경지 토양을 대상으로 광해방지사업(토양개량·복원사업) 시 복토층의 두께 감소 가능여부를 벼를 식재한 담수형 컬럼실험을 통해 검토하였다. 담수 후 4개월 동안 토양용액의 pH, EC, ORP 및 무기원소(Fe, Mn, Ca, As) 농도를 모니터링한 결과 컬럼하층에서 상층으로 미치는 영향은 높지 않은 것으로 나타났다. 복토 두께에 따른 비교에서도 하층의 영향보다는 복토층 두께 변화에 따른 ORP 변화가 복토재 무기원소의 거동에 영향을 미치는 결과를 보였다. 이러한 결과는 토양용액의 거동이 상하층간 반응의 영향보다는 각 층별 나타나는 토양의 이질성에 우선하여 나타난 것으로 판단되었다. 모니터링 종료시점에서 채취한 벼 뿌리의 비소 농도는 현행 사업 조건과 같은 40 cm 두께의 복토층을 조성한 경우 컬럼하층의 안정화 처리여부에 상관없이 대조구 대비 98%가 감소되었다. 20 cm 두께의 복토층에서는 오염토의 안정화가 없을 경우 58%, 안정화처리 시 80%의 전이감소 효율을 나타내었다. 따라서 오염 농경지 토양에 대한 적정 안정화 처리를 수행할 경우 복토재의 사용량을 감소시킬 수 있으며, 경제적인 사업수행효과도 이룰 수 있을 것으로 판단된다. This study was carried out to investigate the feasibility of reducing clean cover soil using a flooded column test in arseniccontaminated farmland reclamation of abandoned coal mine area that shows generally low or about worrisome level (25 mg/kg) of Korea soil environment conservation act unlike abandoned metal mine. During the monitoring period of soil solution for 4 months, chemical properties (pH, EC, ORP, Fe, Mn, Ca, and As) in each layer (clean soil cover and contaminated/stabilized soil) showed different variation. This result revealed that soil solution in stabilized or contaminated soil rarely affected that in cover soil. Whether stabilized or not, arsenic concentrations in the rice roots grown in the soil covers with the thickness of 40 cm decreased by 98% in compared with the that grown in the control soil. In case of the soil covers with 20 cm thickness on stabilized soil, it decreased by 80% and this was 22 percentage point higher than when the soil of lower layer was not stabilized. Thus, reducing clean cover soil could be possible in contaminated farmland soil reclamation if appropriate stabilization of contaminated soil is carried.

강원도 폐탄광 산림복구지 관리방안 도출을 위한 산림복구후 시간경과에 따른 토양 화학적특성 분석

정문호(Mun Ho Jung),고주인(Ju In Ko),박관인(Gwan In Bak),지원현(Won Hyun Ji) 대한자원환경지질학회 2021 자원환경지질 Vol.54 No.4

본 연구는 강원지역 폐탄광 산림복구지에서 산림복구사업 후 시간경과에 따른 토양 화학적특성을 분석하여 관리방안 도출을 위해 수행하였다. 연구대상지는 강원도 정선군 5개 폐탄광과 영월군 3개 폐탄광 총 8개 폐탄광 산림복구지였으며, 경과시간별로 총 11회에 걸쳐 토양 화학적 특성을 분석하였다. 분석항목은 토양 pH, TOC, 총질소, 탄질률, 유효인산 등 5개 특성이었다. 분석결과 토양 pH와 유효인산 함량은 시간경과에 따라 감소하는 경향을, TOC와 총질소 함량, 탄질률은 증가하는 경향을 보였다. TOC와 총질소는 10년 경과시 폐탄광 산림복구를 위한 복토재의 품질기준을 만족하였으며, 토양 pH는 품질기준보다 낮아졌다. 따라서 산림복구사업후 토양 화학적 특성에 대한 장기모니터링 및 이를 통한 사후관리방안 수립이 필요하다. The objectives of this study were to analyze of soil chemical characteristics of abandoned coal mine forest rehabilitation areas in Gangwon-do. The study sites were 8 areas and the investigations were performed 11 times according to elapsed time. Soil characteristics were soil pH, TOC, Total-N, C/N ratio, and Av. P2O5. Soil pH and Av. P2O5 were decreased according to elapsed time after forest rehabilitation, while TOC, Total-N, and C/N ratio increased. TOC and Total-N arrived at quality requirements of covering soil for forest rehabilitation in abandoned coal mine area passed 10 years after forest rehabilitation, while soil pH became lower than that. Therefore, it needs long-term monitoring of soil chemical characteristics after the forest rehabilitation and to establish post management.

연구보문 : 토양환경; 여러 안정화제가 산성 및 알칼리 토양에서 중금속 안정화에 미치는 영향

김민석 ( Min Suk Kim ),민현기 ( Hyun Gi Min ),김정규 ( Jeong Gyu Kim ),구남인 ( Na Min Koo ),박정식 ( Jeong Sik Park ),박관인 ( Gwan In Bak ) 한국환경농학회 2014 한국환경농학회지 Vol.33 No.1

BACKGROUND: Recent studies using many amendments for heavy metal stabilization in soil were conducted in order to find out new materials. But, the studies accounting for the use of appropriate amendments considering soil pH remain incomplete. The aim of this study was to investigate the effects of initial soil pH on the efficiency of various amendments. METHODS AND RESULTS: Acid soil and alkali soil contaminated with heavy metals were collected from the agricultural soils affected by the abandoned mine sites nearby. Three different types of amendments were selected with hypothesis being different in stabilization mechanisms; organic matter, lime stone and iron, and added with different combination. For determining the changes in the extractable heavy metals, water soluble, Mehlich-3, Toxicity Characteristic Leaching Procedure, Simple Bioavailability Extraction Test method were applied as chemical assessments for metal stabilization. For biological assessments, soil respiration and root elongation of bok choy (Brassica campestris ssp. Chinensis Jusl.) were determined. CONCLUSION: It was revealed that lime stone reduced heavy metal mobility in acid soil by increasing soil pH and iron was good at stabilizing heavy metals by supplying adsorption sites in alkali soil. Organic matter was a good source in terms of supplying nutrients, but it was concerning when accounting for increasing metal availability.

미생물과 나노입자에 의한 토양 내 중금속의 미생물학적 흡착 고정화 기술

박형준(Hyung Jun Park),이무현(Mu Hyeon Lee),김영근(Young Geun Kim),박관인(Gwan In Bak),이진수(Jin Su Lee),이종운(Jong Un Lee) 대한지질학회 2013 대한지질학회 학술대회 Vol.2013 No.10

안정화제와 복토제가 청경채 (Brassica campestris var. chinensis)의 생장과 중금속 축적에 미치는 영향

민현기(Hyungi Min),김민석(Min-Suk Kim),구남인(Namin Koo),박관인(Gwan-In Bak),김정규(Jeong-Gyu Kim) 한국토양비료학회 2013 한국토양비료학회 학술발표회 초록집 Vol.2013 No.10

중금속 오염 토양에서 안정화제가 청경채의 초기 생육과 중금속 흡수량에 미치는 영향

김민석(Min-Suk Kim),구남인(Namin Koo),김정규(Jeong-Gyu Kim),양재의(Jae-E Yang),이진수(Jin-Su Lee),박관인(Gwan-In Bak) 한국토양비료학회 2012 한국토양비료학회지 Vol.45 No.6

본 연구에서는 6 종류의 안정화제의 중금속 안정화 효율을 평가하기 위해 생물학적 평가 방법을 이용하였다. 12 종의 식물을 대상으로 한 스크린 실험에서 청경채를 선발하여 이를 안정화제 평가에 사용하였다. 식물 독성실험 결과 농용석회와 제강슬래그는 청경채의 뿌리 신장에, 백운석은 지상부 신장에 각각 악영향을 주었다. 화학적 평가 방법뿐만 아니라 생물학적 평가 방법을 고려하였을 때에는 AMD 슬러지가 가장 추천되어질 만한 것으로 판단된다. 그러나 토양환경과 청경채의 특수성 때문에 위 결과를 일반화 하는 것은 어려우며 명확한 결과 도출을 위해서 재배기간의 조정과 추가적인 화학 침출 평가 방법 등이 필요해 보인다. There have been many studies about efficiency of amendments for heavy metal stabilization through chemical assessment. The objective of this study was to evaluate the efficiency of several soil amendments (lime, agric-lime, dolomite, steel slag, fly ash and acid mine drainage sludge) on heavy metals stabilization through not only chemical but also biological assessments (phytotoxicity test) in abandoned mining area soil. In order to achieve the goal, we conducted preliminary screening experiment targeting 12 types of crop plants such as radish, young radish, chinese cabbage, winter grown cabbage, cabbage, bok choy, chicory, crown daisy, carrot, chives, spinach, and spring onion. The results of inhibition rates of early plant growth in metal-contaminated soil against non-contaminated soil and the correlations between inhibitions items showed that the bok choy was appropriate specie with respect to confirm the effect of several amendments. Several amendment treatments on contaminated soil brought about the changes in the root and shoot elongation of bok choy after 1 week. Agric-lime, dolomite and steel slag treatments showed the great efficiency of reducing on mobility of heavy metals using chemical assessment. But in contrary, these treatments resulted in the reduction of root and shoot elongation and only AMD sludge increased that of elongation, significantly. When considering both chemical and biological assessments, AMD sludge could be recommended the compatible amendment for target contaminated soil. In conclusion, biological assessment was also important aspect of decision of successful soil remediation.