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      • KCI등재

        Bio waste 소재로부터의 마이크로 필러 추출

        남기법 ( Gibeop Nam ),송정일 ( Jung-il Song ) 한국복합재료학회 2018 Composites research Vol.31 No.5

        본 연구에서는 친환경적이고 공급이 안정적인 소재를 찾기 위하여, Bio waste인 쌀겨와 조개 껍질에서 활용하여 마이크로 사이즈의 미세 입자를 추출하고, 추출한 입자의 크기와 형상을 분석한 후 CFRP에 첨가하여 물성의 변화를 관찰하였다. 쌀겨와 탄화 쌀겨의 주요구성성분은 탄소, 산소, 규소로 이루어졌으며 탄화과정을 거치면서 탄소와 규소의 비율이 증가함을 확인하였고, 조개 껍질 분말에서는 탄소 산소와 칼슘이 검출되었으며 이는 조개 껍질의 주요구성물질인 탄산칼슘의 영향으로 보인다. 쌀겨 분말의 면적평균은 6.19 μm 체적평균은 14.77 μm으로 FE-SEM을 통하여 막대형상의 입자가 관찰되며 이는 쌀겨가 가지고 있던 껍질부분의 주름이나 표면의 털이 남아있는 형상으로 보인다. 탄화쌀겨의 분말은 면적평균은 1.55 μm 체적평균은 8.20 μm 조개 껍질 분말은 면적평균은 2.53 μm 체적평균은 5.79 μm로 분석되었으며 쌀겨분말의 경우 막대(Rod)형상의 입자들이 관찰되었고, 조개껍질 분말의 경우 판상(Plate)의 형상을 가지는 것으로 관찰되었다. CFRP에 첨가하였을 경우 첨가량에 비례하여 물성의 하락이 관찰되었는데 그 폭이 쌀겨분말의 경우가 가장 컸으며, 조개 껍질 분말의 경우 물성하락을 거의 유발하지 않음을 확인하였다. This paper explain about the development of environmental friendly, low cost and stable supply material i.e., rice husk and shell were used as micro incorporating bio waste filler. Those were processed by ball mill and analyzed through micro observation by FE-SEM, EDS and particle size distribution. The obtained filler was mixed with epoxy resin for the manufacturing of CFRP composite and study tensile properties. In EDS analysis main contents of rice husk and rice husk ash are C, O and Si. When rice husk was burned C and Si ration were increased. Shell powder has C, O and Ca. It caused CaCO<sub>3</sub> from shell. Surface weighted mean of rice husk powder is 6.19 μm and volume weighted mean is 14.77 μm. And it has rod type particles which caused hair and husk structure parts. Surface weighted mean of rice husk ash powder is 1.55 μm and volume weighted means is 8.20 μm. Surface weighted mean of shell powder is 2.53 μm and volume weighted mean is 5.79 μm. The tensile decreased with increasing the content of micro filler in CFRP composites. In case of rice husk, the significant decrement of tensile strength was observed. and in case of shell powder, there is no effect of changes take place in tensile strength.

      • KCI등재

        카본블랙 첨가량에 따른 인산형 연료전지(PAFC) 분리판용 천연흑연-고분자복합재료의 전기비저항

        김효창,이상민,남기법,노재승,Kim, Hyo-Chang,Lee, Sang-Min,Nam, Gibeop,Roh, Jae-Seung 한국재료학회 2020 한국재료학회지 Vol.30 No.10

        Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/㎤, which is 0.017 g/㎤ less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.

      • KCI등재

        Surface shape and pore size change in carbon blacks isothermally oxidized in air atmosphere according to burn-off ratio

        이상민,이재호,남기법,김석환,김종복,노재승 한국탄소학회 2019 Carbon Letters Vol.29 No.6

        The present study examined changes in surface shape and pore size observed in carbon black particles isothermally oxidized in an air atmosphere according to their burn-off ratio. Carbon black materials were fed into a horizontal tubular furnace in an air atmosphere when the inside temperature reached 600 °C. Subsequently, while changing the isothermal oxidation time, carbon black samples with different burn-off ratios were obtained, i.e., 10.5, 20.0, 30.4, 41.0, 49.9, 59.8, 71.1, and 81.0%. The scanning electron microscope analysis revealed that the observed carbon black particles were in the form of aggregated primary particles, and that there was no change in the particle size of these primary particles as the burn-off process proceeded. The latter observation supported the observation that pores were formed in the carbon black samples during the burn-off process. Notably, the Brunauer–Emmett–Teller analysis exhibited hysteresis curves, indicating that the corresponding adsorption isotherms were of IV-type. It was also found that the area of the hysteresis curves increased as the burn-off process proceeded. The specific surface area of the raw carbon black sample was 58.00 m2/g, while that of the 81.0% sample was about 4.1 times the figure at 240.27 m2/g. The total pore volume VT was 0.17 cm3/g for the raw sample, and it was much higher for the 81.0% sample at 0.58 cm3/g. The transmission electron microscope analysis showed that the raw carbon black particles had a spherical shape with a smooth surface, but inner pores were not observed. In the 49.9% sample, pores with a size of about 5 nm were observed inside carbon black particles. Notably, the size of the pores observed in the 81.0% sample was about 20 nm and the large pores were created by the collapsing and merging of the smaller pores by oxidation.

      • KCI등재

        Effect of Coupling Agent and Fiber Loading on Mechanical Behavior of Chopped Jute Fiber Reinforced Polypropylene Composites

        세이크 라셀,남기법,변정명,김병선,송정일,Rasel, S.M.,Nam, G.B.,Byeon, J.M.,Kim, B.S.,Song, J.I. The Rubber Society of Korea 2011 엘라스토머 및 콤포지트 Vol. No.

        본 연구에서는 황마/폴리프로필렌 강화 섬유 복합재료를 사출성형 방법으로 제조하였으며, 섬유와 열가소성 기지재의 친화력과 접착력을 향상시키기 위해 말레산 무수물(Maleic anhydride, MA)을 결합제로 사용하였다. 천연 섬유인 황마의 표면처리 관찰을 위해서 주사전자현미경(SEM)과 적외선분광기(FTIR)를 사용하였고, 인장 및 굽힘 특성을 확인하기 위하여 기계적 특성 시험을 수행하였으며, 수분흡수율도 측정하여 비교하였다. 인장 및 굽힘 시험 결과 황마 복합재료(JFRP)는 기지재로 사용된 폴리프로필렌(PP)보다 높은 강도와 탄성계수를 나타내었고, 황마 복합재료의 강도 및 탄성계수는 결합제의 비율을 1~3%까지 증가시킴에 따라 높은 결과를 보였다. 이는 결합제의 비율을 증가시킬수록 섬유와 기지재 사이의 계면접착력을 향상시킬 수 있음을 의미한다. In this study, Jute fibers reinforced polypropylene (JFRP) composites were manufactured by injection molding technique. In order to improve the affinity and adhesion between fibers and thermoplastic matrices during manufacturing, Maleic anhydride (MA) as a coupling agent have been employed. Untreated and treated surfaces of jute fibers were characterized using SEM and Fourier transform infrared (FTIR). Physical properties like water absorption rate were studied. Tensile and flexural tests were carried out to evaluate the composite mechanical properties. Tensile test and bending test indicated that JFRP composites show higher strength and modulus than pure PP. In addition, strength and modulus were found to be influenced by the variation of MAPP content (1%, 2%, and 3%). Tensile fracture surfaces were examined using scanning electron microscope. It ensures better interfacial adhesion between fibers and matrix by increasing the percentage of MAPP.

      • 항만용 CSU 포탈거더의 보강형상에 따른 안정성평가

        김진우(Jin-woo Kim),남기법(Gibeop Nam),송정일(Jung Il Song) 대한기계학회 2011 대한기계학회 춘추학술대회 Vol.2011 No.5

        These days, CSU crane was used for math unpacked unloading such as iron, sand and etc. SMH built crane but it was occur cracks, therefor; SMH tried first modify however crack was occur again. So our study is a “Stability Analysis on Continuous Ship Unloader for Harbor.” First of all, we checked cause of crack and found match answer of problems. Second, we used 3D modeling and Analysis about original draw, first draw and second draw. To compare result, we could guess it caused by fatigue and first modify is not enough for dispersion stress but second draw can well dispersion stress then others.

      • KCI등재

        황마 단섬유 강화 폴리프로필렌 복합재료의 기계적 거동에 미치는 결합제 및 섬유 Loading의 영향

        세이크라셀 ( S. M. Rasel ),남기법 ( G. B. Nam ),변정명 ( J. M. Byeon ),김병선 ( B. S. Kim ),송정일 ( J. I. Song ) 한국고무학회 2011 엘라스토머 및 콤포지트 Vol.46 No.3

        본 연구에서는 황마/폴리프로필렌 강화 섬유 복합재료를 사출성형 방법으로 제조하였으며, 섬유와 열가소성 기지재의 친화력과 접착력을 향상시키기 위해 말레산 무수물(Maleic anhydride, MA)을 결합제로 사용하였다. 천연섬유인 황마의 표면처리 관찰을 위해서 주사전자현미경(SEM)과 적외선분광기(FTIR)를 사용하였고, 인장 및 굽힘 특성을 확인하기 위하여 기계적 특성 시험을 수행하였으며, 수분흡수율도 측정하여 비교하였다. 인장 및 굽힘 시험결과 황마 복합재료(JFRP)는 기지재로 사용된 폴리프로필렌(PP)보다 높은 강도와 탄성계수를 나타내었고, 황마복합재료의 강도 및 탄성계수는 결합제의 비율을 1~3%까지 증가시킴에 따라 높은 결과를 보였다. 이는 결합제의 비율을 증가시킬수록 섬유와 기지재 사이의 계면접착력을 향상시킬 수 있음을 의미한다. In this study, Jute fibers reinforced polypropylene (JFRP) composites were manufactured by injection molding technique. In order to improve the affinity and adhesion between fibers and thermoplastic matrices during manufacturing, Maleic anhydride (MA) as a coupling agent have been employed. Untreated and treated surfaces of jute fibers were characterized using SEM and Fourier transform infrared (FTIR). Physical properties like water absorption rate were studied. Tensile and flexural tests were carried out to evaluate the composite mechanical properties. Tensile test and bending test indicated that JFRP composites show higher strength and modulus than pure PP. In addition, strength and modulus were found to be influenced by the variation of MAPP content (1%, 2%, and 3%). Tensile fracture surfaces were examined using scanning electron microscope. It ensures better interfacial adhesion between fibers and matrix by increasing the percentage of MAPP.

      • KCI등재

        열경화성 연속섬유 복합재를 이용해 외측 보강된 3D 프린팅 열가소성 복합재 구조물의 굽힘 특성 향상에 대한 연구

        백운경 ( Un-gyeong Baek ),남기법 ( Gibeop Nam ),노재승 ( Jae-seung Roh ),박성은 ( Sung-eun Park ),노정우 ( Jeong-u Roh ) 한국복합재료학회 2021 Composites research Vol.34 No.2

        3D 프린팅 기술은 금형이 없이 다양한 형태의 제품을 만들기 쉬운 장점이 있지만, 기존 보편화된 성형법에 비해 기계적 물성이 낮고, 소재 및 제작 조건 등에 따라 기계적 물성이 크게 달라지는 문제가 있다. 한편, 높은 물성을 구현하기 위해서는 제조비용이 높아지는 문제가 있어, 이에 대한 연구 필요성이 증가하고 있다. 본 연구에서는 단섬유 탄소섬유 보강 나일론 필라멘트를 이용하여 3D 프린팅 열가소성 구조물을 제작하였다. 또한 인발 성형된 연속섬유 형태의 탄소섬유 혹은 유리섬유 강화 열경화성 복합재를 이용해 외측면을 보강하여 기계적 물성 향상 방법을 제시하였다. 보강재의 보강 위치와 섬유의 종류에 따른 굽힘물성 향상을 확인하였다. 3D printing technology has the advantage of easy to make various shapes of products without a mold. However, it has a problem such as mechanical properties vary greatly depending on materials and manufacturing conditions. Thus, the need for research of 3D printing technology on ways to reduce manufacturing cost compared to physical properties is increasing. In this study, a 3D printing thermoplastic structure was fabricated using short fiber carbon fiber reinforced nylon filaments. And a method of improving mechanical properties was proposed by reinforcing the outer surface using pultruded continuous fiber-type carbon fiber or glass fiber-reinforced thermosetting composite material. It was confirmed that the bending properties were improved according to the reinforcing position of the stiffener and the type of fiber in the stiffener.

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