게임의 근접전투에서 카메라 샷을 적용한 오클루젼 해결 기법

김방울,조경은,엄기현 한국게임학회 2011 한국게임학회 논문지 Vol.11 No.2

MMORPG와 같은 게임에서 근접전투가 벌어지는 샷에서 프라이머리 액터들간의 오클루젼이 종종 발생한다. 본 논문은 미디엄 샷(medium shot) 기법으로 오클루젼을 해결하고 오버-숄더 샷(over-shoulder shot) 기법으로 대결구도를 강화하는 미디엄 오버-숄더(Medium and Oversholder, MOS) 기법을 제안한다. 미디엄 샷 기법은 4개의 기준점을 설정하고. 오버-숄더 샷 기법은 측면의 기준점을 가변적으로 위치시키며 오클루더는 두 개의 스피어로 대체한다. 레이와 스피어가 교차하는지 여부로 잠재적 오클루젼 상태가 판별되면 오클루더의 우측 또는 좌측으로 카메라를 이동시키고, 오클루젼이 해결되면 이동을 멈춘다. 실험결과 MOS 기법은 샷당 평균 13.7μs 의 연산시간의 성능을 보였으며, 오클루젼은 평균 9.26% 비율로 뷰어의 시선 장애에 영향을 주진 않았다. In a game such as MMORPG, players often see occlusions between primary actors in a shot where shows a close quarter combat. This paper proposes an occlusion resolution technique(MOS) by grafting a medium shot technique and an over-shoulder shot technique to strengthen a confrontation structure. A medium shot technique sets 4 reference points at the up/down/left/right on the sphere of target. An over-shoulder shot technique is a technique of locating the reference points on the side variably. An occluder is replaced with 2 spheres. If a ray is emitted to a reference point from the camera point and intersects a sphere of occluder, it becomes a potential occlusion state. If so, we start to move the camera to the right or left of the occluder, keep moving it while new position of camera is in potential occlusion state, and stop its movement when the occlusion is resolved. Our experiments show that MOS technique consumes operational time of 13.7μs per shot on average, and that it resolves occlusions in 9.26% of ratio on average, and so doesn't have any effect on viewer's sight.

Preparation of the electrode using NiFe2O4 powder for the alkaline water electrolysis

황갑진,길보민,유철휘 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.48 No.-

The coin electrode was prepared by mixing the binder (polyethylene glycol or styrene butadiene rubber)and NiFe2O4 powder which was synthesized by a co-precipitate method, to use in the alkaline waterelectrolysis. The over-potential of the prepared coin electrode was measured in 7 mol L 1 KOH solutionfor an oxygen evolution reaction (OER) and a hydrogen evolution reaction (HER). From the data, it wasestimated that the prepared coin electrode is useful for the electrode in the alkaline water electrolysiswith its low over-potential (1.57 V and 2.20 V for OER and HER, respectively, at the current density of0.41 A cm 2).

Analysis on the Langmuir Adsorption Isotherm of the Over-Potentially Deposited Hydrogen (OPD H) at the Polycrystalline Au|Acidic Aqueous Electrolyte Interface Using the Phase-Shift Method

Chun Jang H.,Jeon Sang K. The Korean Electrochemical Society 2001 한국전기화학회지 Vol.4 No.3

순환전압전류 및 교류임피던스 기법을 이용하여 다결정 $0.5M\;H_2SO_4$수용액 계면에서 음극 $H_2$발생 반응을 위한 과전위 전착(흡착)된 수소의 Langmuir흡착등온식을 연구조사 하였다. 다결정 $Au|0.5M\;H_2SO_4$수용액 계면에서, 최적중간주파수일 때 위상이동 $(0^{\circ}\leq{-\phi}\leq90^{\circ})$ 거동은 표면피복율$(1\geq{\theta}\geq0)$ 거동에 정확하게 상응한다. 최적중간주 파수일 때 위상이동 변화 $({-\phi}\;vs.\;E)$즉 위상이동 방법은 다결정 $Au|0.5M\;H_2SO_4$수용액 계면에서 음극 $H_2$발생 반응을 위한 과전위 전착(흡착)된 수소의 Langmuir 흡착등온식$(\theta\;vs.\;E)$을 추정할 수 있는 새로운 방법으로 사용될 수 있다. 다결정 $Au|0.5M\;H_2SO_4$ 수용액 계면에서, 과전위 전착(흡착)된 수소의 흡착평형상수(K)와 표준자유에너지 $({\Delta}G_{ads})$는 각각 $2.3\times10^{-6}$과 $32.2kJ\;mol^{-1}$이다. The Langmuir adsorption isotherm of the over-potentially deposited hydrogen (OPD H) for the cathodic $H_2$ evolution reaction (HER) at the $poly-Au|0.5M\;H_2SO_4$ aqueous electrolyte interface has been studied using cyclic voltammetric and ac impedance techniques. The behavior of the phase shift $(0^{\circ}\leq{-\phi}\leq90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1\geq{\theta}\geq0)$ at the interface. The phase-shift profile $({-\phi}\;vs.\;E)$ for the optimum intermediate frequency, i.e., the phase-shift method, can be used as a new method to estimate the Langmuir adsorption isotherm $(\theta\;vs.\;E)$ of the OPD H for the cathodic HER at the interface. At the poly-$Au|0.5M\;H_2SO_4$ electrolyte interface, the equilibrium constant (K) and standard free energy $({\Delta}G_{ads})$ of the OPD H are $2.3\times10^{-6}\;and\;32.2\;kJ\;mol^{-1}$, respectively.

Analysis on the Frumkin Adsorption Isotherm of the Over-Potentially Deposited Hydrogen (OPD H) at the Polycrystalline Ni | Alkaline Aqueous Electrolyte Interface Using the Phase-Shift Method

Chun Jang H.,Jeon Sang K. The Korean Electrochemical Society 2001 한국전기화학회지 Vol.4 No.4

위상이동 방법을 이용하여 다결정 Ni|0.05M KOH수용액 계면에서 음극 $H_2$발생 반응을 위한 과전위 전착(흡착)된 수소의 Frumkin 흡착등온식을 연구조사 하였다. 다결정 Ni|0.05M KOH수용액 계면에서, 최적중간주파수일 때 위상이동$(0^{\circ}\leq{\phi}\leq90^{\circ})$ 거동은 표면피복율 $(1\geq{\theta}\geq0)$ 거동에 정확하게 상응한다. 최적중간주파수일 때 위상이동 변화 $(-{\phi}\;vs.\;E)$즉 위상이동 방법은 다결정 Ni|0.05M KOH수용액 계면에서 음극 $H_2$발생 반응을 위한 과전위 전착(흡착)된 수소의 Frumkin흡착등온식$(\theta\;vs.\;E)$을 추정할 수 있는 새로운 방법으로 사용될 수 있다. 다결정 Ni|0.05M KOH 수용액 계면에서, 표면피복율에 따른 과전위 전착(흡착)된 수소의 표준자유에너지 변화율(r), Frumkin 흡착등온식의 상호작용 파라미터(g), 표면피복율$(\theta)$에 따른 과전위 전착(흡착)된 수소의 흡착평형상수(K)와 표준자유에너지$({\Delta}G_{\theta})$는 각각 $24.8kJ mol^{-1},\;10,\;5.9\times10^{-6}{\leq}K{\leq}0.13,\;and\;5.1\leq{\Delta}G_{\theta}\leq29.8kJ\;mol^{-1}$이다. 전극속도론적 파라미터$(r,\;g,\;K,\;{\Delta}G_{\theta})$는 표면피복율${\theta}에 따른다. The Frumkin adsorption isotherm of the over-potentially deposited hydrogen (OPD H) for the cathodic $H_2$ evolution reaction (HER) at the poly-Ni|0.05M KOH aqueous electrolyte interface has been studied using the phase-shift method. The behavior of the phase shift $(0^{\circ}\leq{\phi}\leq90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1\geq{\theta}\geq0)$ at the interface. The phase-shift method, i.e., the Phase-shift profile $(-{\phi}\;vs.\;E)$ for the optimum intermediate frequency, can be used as a new method to estimate the Frumkin adsorption isotherm $(\theta\;vs.\;E)$ of the OPD H for the cathodic HER at the interface. At the poly-Ni|0.05M KOH aqueous electrolyte interface, the rate (r) of change of the standard free energy of the OPD H with $\theta$, the interaction parameter (g) for the Frumkin adsorption isotherm, the equilibrium constant (K) for the OPD H with $\theta$, and the standard free energy $({\Delta}G_{\theta})$ of the OPD H with ${\theta}$ are $24.8kJ mol^{-1},\;10,\;5.9\times10^{-6}{\leq}K{\leq}0.13,\;and\;5.1\leq{\Delta}G_{\theta}\leq29.8kJ\;mol^{-1}$. The electrode kinetic parameters $(r,\;g,\;K,\;{\Delta}G_{\theta})$ depend strongly on ${\theta} (0{\leq}{\theta}{\leq}1)$.

Electrochemical Characteristics of Solid Polymer Electrode Fabricated with Low IrO₂ Loading for Water Electrolysis

Ban, Hee-Jung,Kim, Min Young,Kim, Dahye,Lim, Jinsub,Kim, Tae Won,Jeong, Chaehwan,Kim, Yoong-Ahm,Kim, Ho-Sung The Korean Electrochemical Society 2019 Journal of electrochemical science and technology Vol.10 No.1

To maximize the oxygen evolution reaction (OER) in the electrolysis of water, nano-grade $IrO_2$ powder with a low specific surface was prepared as a catalyst for a solid polymer electrolyte (SPE) system, and a membrane electrode assembly (MEA) was prepared with a catalyst loading as low as $2mg\;cm^{-2}$ or less. The $IrO_2$ catalyst was composed of heterogeneous particles with particle sizes ranging from 20 to 70 nm, having a specific surface area of $3.8m^2g^{-1}$. The anode catalyst layer of about $5{\mu}m$ thickness was coated on the membrane (Nafion 117) for the MEA by the decal method. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) confirmed strong adhesion at the interface between the membrane and the catalyst electrode. Although the loading of the $IrO_2$ catalyst was as low as $1.1-1.7mg\;cm^{-2}$, the SPE cell delivered a voltage of 1.88-1.93 V at a current density of $1A\;cm^{-2}$ and operating temperature of $80^{\circ}C$. That is, it was observed that the over-potential of the cell for the oxygen evolution reaction (OER) decreased with increasing $IrO_2$ catalyst loading. The electrochemical stability of the MEA was investigated in the electrolysis of water at a current density of $1A\;cm^{-2}$ for a short time. A voltage of ~2.0 V was maintained without any remarkable deterioration of the MEA characteristics.

The Phase-Shift Method for the Langmuir Adsorption Isotherms at the Noble Metal (Au, Rh) Electrode Interfaces

천장호,전상규,이재항,Chun, Jang H.,Jeon, Sang K.,Lee, Jae H. The Korean Electrochemical Society 2003 한국전기화학회지 Vol.6 No.2

The Langmuir adsorption isotherms of the over-potentially deposited hydrogen (OPD H) fur the cathodic $H_2$ evolution reaction (HER) at the poly-Au and $Rh|0.5M\;H_2SO_4$ aqueous electrolyte interfaces have been studied using cyclic voltammetric and ac impedance techniques. The behavior of the phase shift $(0^{\circ}{\leq}{-\phi}{\leq}90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1{\geq}{\theta}{\geq}0)$ at the interfaces. The phase-shift profile $({-\phi}\;vs.\;E)$ for the optimum intermediate frequency, i.e., the phase-shift method, can be used as a new electrochemical method to determine the Langmuir adsorption isotherm $({\theta}\;vs.\;E)$ of the OPD H for the cathodic HER at the interfaces. At the poly-Au|0.5M $H_2SO_4$ aqueous electrolyte interface, the equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the OPD H are $2.3\times10^{-6}$ and 32.2kJ/mol, respectively. At the poly-Rh|0.5M $H_2SO_4$ aqueous electrolyte interface, K and ${\Delta}G_{ads}$ of the OPD H are $4.1\times10^4\;or\;1.2\times10^{-2}$ and 19.3 or 11.0kJ/mol depending on E, respectively. In contrast to the poly-Au electrode interface, the two different Langmuir adsorption isotherms of the OPD H are observed at the poly-Rh electrode interface. The two different Langmuir adsorption isotherms of the OPD H correspond to the two different adsorption sites of the OPD H on the poly-Rh electrode surface.

Review on the Determination of Frumkin, Langmuir, and Temkin Adsorption Isotherms at Electrode/Solution Interfaces Using the Phase-Shift Method and Correlation Constants

( Jinyoung Chun ),( Jang H. Chun ) 한국화학공학회 2016 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.54 No.6

This review article described the electrochemical Frumkin, Langmuir, and Temkin adsorption isotherms of over-potentially deposited hydrogen (OPD H) and deuterium (OPD D) for the cathodic H₂ and D₂ evolution reactions (HER, DER) at Pt, Ir, Pt-Ir alloy, Pd, Au, and Re/normal (H₂O) and heavy water (D₂O) solution interfaces. The Frum-kin, Langmuir, and Temkin adsorption isotherms of intermediates (OPD H, OPD D, etc.) for sequential reactions (HER, DER, etc.) at electrode/solution interfaces are determined using the phase-shift method and correlation constants, which have been suggested and developed by Chun et al. The basic procedure of the phase-shift method, the Frumkin, Lang-muir, and Temkin adsorption isotherms of OPD H and OPD D and related electrode kinetic and thermodynamic param-eters, i.e., the fractional surface coverage (0 ≤ θ ≤ 1) vs. potential (E) behavior (θ vs. E), equilibrium constant (K), interaction parameter (g), standard Gibbs energy (ΔG_θ˚) of adsorption, and rate (r) of change of ΔG_θ˚ with θ (0 ≤ θ ≤ 1), at the interfaces are briefly interpreted and summarized. The phase-shift method and correlation constants are useful and effective techniques to determine the Frumkin, Langmuir, and Temkin adsorption isotherms and related electrode kinetic and thermodynamic parameters (θ vs. E, K, g, ΔG_θ˚, r) at electrode/solution interfaces.

아우토노미아의 가능성 - 『난장이가 쏘아 올린 작은 공』을 중심으로

정문권(Jung Mounkwon),이강록(Lee Gangrock) 한국언어문학회 2006 한국언어문학 Vol.58 No.-

  -It centered on 〈small-sized ball shot by a dwarf〉:written by cho se hui-Until now, the research and assesment about 〈small-sized ball shot by a dwarf〉are divided two dimension. One is literal-social approch that concerned the life and pressive structure of out side status and contrastive universial recognition. Two is structure or using method of 〈small-sized ball shot by a dwarf〉. This paper emphasizes that diversity as a structure method of 〈small-sized ball shot by a dwarf〉 is actually dening contrast and division of universial recognition and recognising diversity through ‘difference’ and ‘disliking’. Such a diversity is constitued new society through the communication. this is the thought of autonomia. the thought of autonomia identified the diversity.<BR>  This paper try to approve the identity thought of autonomia and the catagory of recognition that present this 〈small-sized ball shot by a dwarf〉. As a result, the concept of ‘difference’ and ‘disliking’, ‘potential’, diversity ‘change -over recognition’ is discovered. As a same concept, the possibility of new constitution society is discovered.<BR>  So, 〈small-sized ball shot by a dwarf〉 is not a contrastive and divisional universial recognition that represented labor demonstration but a new active method as a preparing proposal that contain new recognition. As a result, that is the thought of autonomia that suggested by anthonio negry. As a same word, this paper try to approve that the thought of autonomia identified the diversity.

pH와 산화환원전위에 따른 상등수-퇴적물에서의 인 형태 변화

정우혁(Woo Hyeok Jung),김건하(Geon Ha Kim) 大韓環境工學會 2006 대한환경공학회지 Vol.28 No.5

Case study on risk evaluation of printed electronics using nanosilver ink

Kim Ellen,Lee Ji Hyun,Kim Jin Kwon,Lee Gun Ho,안강호,박정덕,Yu Il Je 나노기술연구협의회 2016 Nano Convergence Vol.3 No.2

Background With the ever-increasing development of nanotechnology, our society is being surrounded by possible risks related to exposure to manufactured nanomaterials. The consumer market already includes many products that contain silver nanoparticles (AgNPs), including various household products, such as yoga mats, cutting boards, running shirts, and socks. There is a growing concern over the release of AgNPs in workplaces related to the manufacture and application of nanomaterials. Objective This study investigated the release of AgNPs during the operation of a printed electronics printer. Methods Using an exposure simulation chamber, a nanoparticle collector, scanning mobility particle sizer (SMPS), condensation particle counter (CPC), dust monitor, and mixed cellulose ester (MCE) filters are all connected to measure the AgNP exposure levels when operating a printed electronics printer. Results A very small amount of AgNPs was released during the operation of the printed electronics printer, and the number of AgNPs inside the exposure simulation chamber was lower than that outside background. In addition, when evaluating the potential risks for consumers and workers using a margin of exposure (MOE) approach and target MOE of 1000, the operational results far exceeded the target MOE in this simulation study and in a previous workplace exposure study. Conclusion The overall results indicate a no-risk concern level in the case of printed electronics using nanosilver ink. Background With the ever-increasing development of nanotechnology, our society is being surrounded by possible risks related to exposure to manufactured nanomaterials. The consumer market already includes many products that contain silver nanoparticles (AgNPs), including various household products, such as yoga mats, cutting boards, running shirts, and socks. There is a growing concern over the release of AgNPs in workplaces related to the manufacture and application of nanomaterials. Objective This study investigated the release of AgNPs during the operation of a printed electronics printer. Methods Using an exposure simulation chamber, a nanoparticle collector, scanning mobility particle sizer (SMPS), condensation particle counter (CPC), dust monitor, and mixed cellulose ester (MCE) filters are all connected to measure the AgNP exposure levels when operating a printed electronics printer. Results A very small amount of AgNPs was released during the operation of the printed electronics printer, and the number of AgNPs inside the exposure simulation chamber was lower than that outside background. In addition, when evaluating the potential risks for consumers and workers using a margin of exposure (MOE) approach and target MOE of 1000, the operational results far exceeded the target MOE in this simulation study and in a previous workplace exposure study. Conclusion The overall results indicate a no-risk concern level in the case of printed electronics using nanosilver ink.