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        Aminated cassava residue-based magnetic microspheres for Pb(II) adsorption from wastewater

        Xinling Xie,Jie Huang,Youquan Zhang,Zhangfa Tong,Anping Liao,Xingkui Guo,Zuzeng Qin,Zhanhu Guo 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.2

        Aminated cassava residue magnetic microspheres (ACRPM) were synthesized via an inverse emulsion method by using chemically modified cassava residue as a crude material, and acrylic acid (AA), acrylamide (AM), and methyl methacrylate (MMA) as monomers and a polyethylene glycol/methanol system (PEG/MeOH) as the porogen. Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2 adsorption-desorption and vibrating sample magnetometry (VSM) were used to characterize the ACRPM. The results indicated that amino groups were grafted to the cassava residue magnetic microspheres, and the Fe3O4 nanoparticles were encapsulated in the microspheres. After porogen was added, the particle size of the ACRPM decreased from 16.5 μm to 150 nm with a pore volume of 0.05510m3/g, and the specific surface area of the ACRPM increased from 3.02 to 12.34m2/g. The ACRPM were superparamagnetic, and the saturation magnetization was 9.8 emu/g. The maximum adsorption capacity of Pb(II) on the ACRPM was 390mg/g. The ACRPM exhibited a large specific surface area and provided many adsorption sites for metal ion adsorption, which favored a high adsorption capacity. Additionally, the Pb(II) adsorption process was fitted to pseudo-second-order kinetic and Langmuir isothermal adsorption models. This suggests that the Pb(II) adsorption process was dominated by a chemical reaction process and that chemisorption was the rate-controlling step during the Pb(II) removal process. In addition, the adsorbent exhibited good stability after six consecutive reuses.

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        Thin-film electronics based on all-2D van der Waals heterostructures

        Liu Xinling,Yang Xiaomin,Sang Weihui,Huang Hai,Li Wenwu,Lin Yen-Fu,Chu Junhao 한국정보디스플레이학회 2021 Journal of information display Vol.22 No.4

        Two-dimensional (2D) layered materials including metal, semiconductor, and insulator have received extensive attention in recent years. The weak van-der-Waals (vdW) interactions between 2D materials layers enable them to isolate monolayers and restack into artificial 2D vdW heterostructures in the desired sequence. These assembled all-2D vdW heterostructures are promising platforms for fabricating next-generation electronics as well as optoelectronics. In particular, the all-2D vdW heterostructure devices composed entirely of 2D layered material have received extensive attention due to their natural thickness, atomically sharp heterointerfaces, and excellent mechanical flexibility. Herein, we firstly introduce 2D vdW heterostructures and their preparation methods. Secondly, the recent progress of field-effect transistors (FETs) and photodetectors based on all-2D vdW heterostructures are summarized. Finally, we discuss some challenges of all-2D vdW heterostructure-based devices for practical applications and offer personal perspectives toward the future development of thin-film electronics.

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        Radiation Dose Reduction and Surgical Efficiency Improvement in Endoscopic Transforaminal Lumbar Interbody Fusion Assisted by Intraoperative O-arm Navigation: A Retrospective Observational Study

        Junfeng Gong,Xinle Huang,Liwen Luo,Huan Liu,Hao Wu,Ying Tan,Changqing Li,Yu Tang,Yue Zhou 대한척추신경외과학회 2022 Neurospine Vol.19 No.2

        Objective: Endoscopic transforaminal lumbar interbody fusion (Endo-TLIF) has gained increasing popularity among spine surgeons. However, with the use of fluoroscopy, intraoperative radiation exposure remains a major concern. Here, we aim to introduce Endo-TLIF assisted by O-arm-based navigation and compare the results between O-arm navigation and fluoroscopy groups. Methods: Sixty-four patients were retrospectively analyzed from May 2019 to September 2020; the nonnavigation group comprised 34 patients, and the navigation group comprised 30 patients. Data on radiation dose, blood loss, postoperative drains, surgery time, complications, and length of hospital stay (LOS) were collected. Clinical outcomes were evaluated from postoperative data such as fusion rate, Oswestry Disability Index (ODI), and visual analogue scale (VAS). Radiation dose and surgery time were selected as primary outcomes; the others were second outcomes. Results: All patients were followed up for at least 12 months. No significant differences were detected in intraoperative hemorrhage, postoperative drains, hospital LOS, or complications between the 2 groups. The radiation dose was significantly lower in the navigation group compared with the nonnavigation group. The time of cannula placement and pedicle screw fixation was significantly reduced in the navigation group. No significant differences were detected between the clinical outcomes in the 2 groups (VAS and ODI scores). Conclusion: The present study demonstrates that O-arm-assisted Endo-TLIF is efficient and safe. Compared with fluoroscopy, O-arm navigation could reduce the radiation exposure and surgical time in Endo-TLIF surgery, with similar clinical outcomes. However, the higher doses exposed to patients remains a negative effect of this technology.

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