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- 저자 : Vicente Rodriguez-Gonzalez (검색결과 2 건)
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Enhancement of NOx photo-oxidation by Fe-doped TiO2 nanoparticles
Adriana Martinez-Oviedo,Schindra Kumar Ray,Gobinda Gyawali,Vicente Rodriguez-Gonzalez,Soo Wohn Lee 한양대학교 세라믹연구소 2019 Journal of Ceramic Processing Research Vol.20 No.3
Microwave hydrothermal-assisted sol-gel method was employed to synthesize the Fe doped TiO2 photocatalyst. Themorphological analysis suggests anatase phase nanoparticles of ~20 nm with an SBET area of 283.99 m2/g. The doping of Feions in TiO2 created oxygen vacancies and Ti3+ species as revealed through the XPS analysis. The reduction of the band gap(3.1 to 2.8 eV) is occurred by doping effect. The as-prepared photocatalyst was applied for removal of NOx under solar lightirradiation. The doping of Fe in TiO2 facilitates 75 % of NOx oxidation efficiency which is more than two-fold enhancementthan the TiO2 photocatalyst. The possible reason of enhancement is associated with high surface area, oxygen vacancy, andreduction of the band gap. Also, the low production of toxic intermediates, NO2 gas, is further confirmed by Combustion IonChromatography. The mechanism related NOx oxidation by the doped photocatalyst is explained in this study.
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Rodríguez-Gómez Irene,Sánchez-Martín Coral,García-García Francisco J.,García-Esquinas Esther,Miret Marta,Vicente-Rodriguez Germán,Gusi Narcís,Mañas Asier,Carnicero José A.,Gonzalez-Gross Marcela,Ayuso 한국역학회 2022 Epidemiology and Health Vol.44 No.-
OBJECTIVES: This study investigated the associations of chronic diseases with changes in lifestyle and health behaviours in older people following the coronavirus disease 2019 (COVID-19) lockdown in Spain and compared the differences in changes over time. METHODS: 1,092 participants (80.3± 5.6 years; 66.5% female) from 2 Spanish cohorts were included. Telephone-based questionnaires were conducted to evaluate lifestyle and health risk behaviours at the end of lockdown and 7 months post-lockdown. Participants were classified as having physician-diagnosed chronic diseases based on self-reported data. Cox proportional models adjusted for major confounders were used. RESULTS: Compared to those without the corresponding chronic diseases, older people with hypertension were less likely to report increased alcohol consumption (hazard ratio [HR], 0.73; 95% confidence interval [CI], 0.55 to 0.99). Pulmonary diseases were associated with lower risks of increased sedentary time (HR, 0.58; 95% CI, 0.39 to 0.86) and worsened sleep quality (HR, 0.56; 95% CI, 0.36 to 0.87), while cardiovascular diseases were associated with a lower risk of decreased sedentary time (HR, 0.58; 95% CI, 0.38 to 0.88). Depression was linked to a higher likelihood of improved diet quality (HR, 1.53; 95% CI, 1.00 to 2.36). Cancer pacients were less likely to have worsened sleep quality (HR, 0.44; 95% CI, 0.22 to 0.89) but more likely to have reduced their frequency of social contact (HR, 2.05; 95% CI, 1.05 to 3.99). CONCLUSIONS: Older people with chronic diseases showed beneficial changes in lifestyle and health risk behaviours after the COVID-19 lockdown. In particular, older people with hypertension, pulmonary disease, and cancer tended to make beneficial lifestyle and health behaviour changes. However, older people with cardiovascular disease and depression engaged in more health risk behaviours.
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