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Enhancement of NOx photo-oxidation by Fe-doped TiO2 nanoparticles
Adriana Martinez-Oviedo,Schindra Kumar Ray,Gobinda Gyawali,Vicente Rodriguez-Gonzalez,Soo Wohn Lee 한양대학교 세라믹연구소 2019 Journal of Ceramic Processing Research Vol.20 No.3
Microwave hydrothermal-assisted sol-gel method was employed to synthesize the Fe doped TiO2 photocatalyst. Themorphological analysis suggests anatase phase nanoparticles of ~20 nm with an SBET area of 283.99 m2/g. The doping of Feions in TiO2 created oxygen vacancies and Ti3+ species as revealed through the XPS analysis. The reduction of the band gap(3.1 to 2.8 eV) is occurred by doping effect. The as-prepared photocatalyst was applied for removal of NOx under solar lightirradiation. The doping of Fe in TiO2 facilitates 75 % of NOx oxidation efficiency which is more than two-fold enhancementthan the TiO2 photocatalyst. The possible reason of enhancement is associated with high surface area, oxygen vacancy, andreduction of the band gap. Also, the low production of toxic intermediates, NO2 gas, is further confirmed by Combustion IonChromatography. The mechanism related NOx oxidation by the doped photocatalyst is explained in this study.
Modified blue TiO2 nanostructures for efficient photo-oxidative removal of harmful NOx gases
Hao Huy Nguyen,GYAWALI GOBINDA,Adriana Martinez-Oviedo,Hoang Phuc Nguyen,이수원 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.9
Blue TiO2 nanostructures were produced via Lithium/ethylenediamine (Li/EDA) reduction method and applied for photo-oxidative removal of harmful NOx gases under simulated solar light irradiation. Blue TiO2 possesses some unique physicochemical properties such as enhanced visible-light absorption, superficial defects or oxygen vacancies, and the evolution of Ti3+ species. Moreover, the photoluminescence spectra (PL) revealed the efficient separation of photoinduced electron-hole pairs in the modified blue TiO2 nanostructures, enhancing their photocatalytic activities. The results indicated that the blue TiO2 nanostructures exhibited the highest performance towards photo-oxidation of NOx gases, with an efficiency of 72.6% under simulated solar light irradiation