Construction and effect of intramolecular hydrogen bond on solvent resistance of polymeric membranes and their application in impermeable membranes

Xiaoyun Li,Zhen Wang,Xin Jing,Xudong Li,Junwei Wang,Mao-qing Kang,Yuhua Zhao,Qifeng Li 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.107 No.-

Hydrogen bonds, which can be divided into many types along with the deepening of research, exist inmany compounds and have certain impact on properties of substances. In this work, effect of intramolecularhydrogen bond on solvent resistance of polymeric membranes was studied from two aspects. On theone hand, the existence of intramolecular hydrogen bond on solvent resistance of polymeric membraneswas studied by constructing and shielding special hydroxyl groups in typical polymer polyurethane. Onthe other hand, content of intramolecular hydrogen bond on solvent resistance was investigated by buildingdifferent ratios of inter- and intra-molecular hydrogen bonds in polyvinyl alcohols. The structures,solvent resistance and hydrogen bonding interactions were systematically investigated by FT-IR, XRD,Ds and performances before and after immersed in solvents. Permeabilities of the membranes for practicalapplication were also characterized. The results showed that distinct type and ratio of hydrogenbonds played different role on solvent resistance. A good agreement between the swelling performancesand content of intramolecular hydrogen bond proved the positive effect of intramolecular hydrogen bondon solvent durability of polymeric membranes. In addition, polyurethane membranes exhibited goodimpermeability to water vapor, oxygen and chloride ions which showed potential application in manyfields.

HMM and HSS Based Social Behavior of Intelligent Vehicles for Freeway Entrance Ramp

Guangming Xiong,Yong Li,Shiyuan Wang,Xiaoyun Li,Peng Liu 보안공학연구지원센터 2014 International Journal of Control and Automation Vol.7 No.10

In this paper, a novel approach of intelligent vehicle to interact and cooperate with other human driving vehicles is proposed at the freeway entrance ramp scenario. The system consists of a Safety Alert Module and Vehicle Control Module. The Safety Alert System module includes intention estimation and conflict judgment. A two dimension Hidden Markov Model (2DHMM) is used to estimate social vehicle’s driving intention in the intention estimation module. Then the conflict judgment module predicts the potential conflicts between the intelligent vehicle and social vehicle. Moreover, the hybrid state system (HSS) is introduced to control the intelligent vehicle while considering its decision making, states and dynamics. Co-simulation using PreScan and Simulink is conducted. The experiment results show that the intelligent vehicle performs well with a commendable social behavior in the freeway entrance ramp.

Surprise, Image and Life: Take the “life lost” event in the Oriental life world as an example

Li Xiaoyun,Wang ping,Hou jialin 아시아사회과학학회 2021 Jornal of Asia Social Science Vol.5 No.3

In the face of images, people s feelings are not necessarily rich, but may also be confused. Whether it is rational or aesthetic. Because emotionally, what they bring is tiredness and boredom. They are narrow-minded and not full. The simple idea of life world is the perfect existence. Even the “life lost”event can also “transform” our spirit. Simple life, not simple life.

Transition and Upgrading Routes of Hidden Champions in Chinese Manufactural Enterprises

Li Junfu,Li Xiaoyun 중한연구학회 2023 중한연구학간 Vol.0 No.30

How to overcome the dual constraints of resources and environment so as to achieve high-quality sustainable growth by means of transition and upgrading is a topic worth studying. Based on the theoretical frontier and the best practice of typical hidden champions, this paper sheds light on the transition and upgrading routes of Chinese hidden champions in manufactural sector, accordingly, a concrete framework is constructed : A hidden champion can successfully carry out transiation and upgrading by means of one or more of “seven strategies” which are comprised of greening, servitization, digitization, innovation, globalization, specialization and ecologization. In doing so, the hidden champions can achieve high-quality sustainable growth.

Kinetics of Levulinic Acid Produced from Glucose Using Modified HZSM-5

Xiaoyun Li,Lifei Yao,Lijie Jiang,Min Liang,Yu Qiu,Yuyang Tian,Shujun Han,Chuanling Si,Youngsoo Bae 강원대학교 산림과학연구소 2018 강원대학교 산림과학연구소 학술대회 Vol.2018 No.09

Levulinic acid is a valuable platform chemical which could be used as raw material to synthesis various chemicals and fuels. In this work, citric acid modified HZSM-5 and aluminum ion modified HZSM-5 were prepared and used in the production of levulinic acid from glucose. The modified HZSM-5 was characterized by XRD, SEM, FTIR, BET, TG and pyridine FTIR. The Brønsted acid sites density of citric acid modified HZSM-5 was higher than aluminum ion modified HZSM-5. More importantly, the kinetics of levulinic acid production catalyzed by citric acid modified HZSM-5 and aluminum ion modified HZSM-5 were investigated, respectively. The Saeman model was applied to predict the concentration of levulinic acid, and the values calculated by the model agreed well with the experimental data. The rate of production of levulinic acid with citric acid modified HZSM-5 was higher than that of aluminum ion modified HZSM-5. The model supplied a profound understanding in the conversion of glucose into levulinic acid with modified H-ZSM-5 zeolite.

China’s Foreign Aid

Li Xiaoyun,Ma Jiewen,Tang Lixia 한국국제협력단 2013 국제개발협력 Vol.2013 No.4

Exosomes from adipose-derived stem cells overexpressing Nrf2 accelerate cutaneous wound healing by promoting vascularization in a diabetic foot ulcer rat model

Xue-Li Zhou,Xiaoyun Xie,Weishuai Lian,Rongfeng Shi,Shilong Han,Haijun Zhang,Ligong Lu,Maoquan Li 생화학분자생물학회 2018 Experimental and molecular medicine Vol.50 No.-

Diabetic foot ulcers (DFU) increase the risks of infection and amputation in patients with diabetes mellitus (DM). The impaired function and senescence of endothelial progenitor cells (EPCs) and high glucose-induced ROS likely exacerbate DFUs. We assessed EPCs in 60 patients with DM in a hospital or primary care setting. We also evaluated the therapeutic effects of exosomes secreted from adipose-derived stem cells (ADSCs) on stress-mediated senescence of EPCs induced by high glucose. Additionally, the effects of exosomes and Nrf2 overexpression in ADSCs were investigated in vitro and in vivo in a diabetic rat model. We found that ADSCs that secreted exosomes promoted proliferation and angiopoiesis in EPCs in a high glucose environment and that overexpression of Nrf2 increased this protective effect. Wounds in the feet of diabetic rats had a significantly reduced ulcerated area when treated with exosomes from ADSCs overexpressing Nrf2. Increased granulation tissue formation, angiogenesis, and levels of growth factor expression as well as reduced levels of inflammation and oxidative stress-related proteins were detected in wound beds. Our data suggest that exosomes from ADSCs can potentially promote wound healing, particularly when overexpressing Nrf2 and therefore that the transplantation of exosomes may be suitable for clinical application in the treatment of DFUs.

GROUP-THEORETICAL ANALYSES OF IN-PLANE MODES IN TWO-DIMENSIONAL PHONONIC CRYSTALS

Li Cai,Xiaoyun Han,Jianyu Fang,Shengbing Chen 한국소음진동공학회 2008 한국소음진동공학회 국제학술대회논문집 Vol.2008 No.7

Weight Estimation and Secure Control for Discrete Stochastic Distribution Control Systems Under Sparse Sensor Attacks

Xiaoyun Yi,Yuwei Ren,Li Qi,Ben Niu,Yixian Fang 제어·로봇·시스템학회 2023 International Journal of Control, Automation, and Vol.21 No.4

In this paper, we investigate the problem of weight estimation and secure control for discrete stochastic distribution control (SDC) systems under sparse sensor attacks. Firstly, a Luenberger observer is designed for the linear SDC systems to perform the weight estimation under sparse sensor attacks. Then, a generalized proportionalintegral (PI) tracking control strategy is proposed for the linear B-spline model. Furthermore, the tracking problem for output probability density functions (PDFs) is implemented, and the designed controller ensures that the closedloop system is stable. Finally, the simulation results show the effectiveness of the proposed method.

ON NONSINGULAR EMBRY QUARTIC MOMENT PROBLEM

Li, Chungji,Sun, Xiaoyun Korean Mathematical Society 2007 대한수학회보 Vol.44 No.2

Given a collection of complex numbers ${\gamma}{\equiv}\{{\gamma}ij\}$ $(0{\leq}i+j{\leq}2n,\;|i-j|{\leq}n)$ with ${\gamma}00>0\;and\;{\gamma}ji=\bar{\gamma}ij$, we consider the moment problem for ${\gamma}$ in the case of n=2, which is referred to Embry quartic moment problem. In this note we give a partial solution for the nonsingular case of Embry quartic moment problem.