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Hydrogenation of methyl methacrylate under mild conditions using biosynthesis Ru catalyst
Hongling Zhou,Yangqiang Huang,Youwei Cheng,Lijun Wang,Xi Li 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.47 No.-
Hydrogenation of methyl methacrylate (MMA) was investigated over Ru-based catalyst supported onactive carbons (AC), which was prepared by bio-reduction method, using C. Platycladi (CP) leaf extract asreductant. By varying reaction temperature, hydrogen pressure and reaction time, hydrogenation ofMMA over the biosynthesis Ru-based catalyst was carried out, and resulted the optimum conditions,30 C (room temperature), 2.0 MPa, and 50 min. The as-prepared Ru/AC catalyst showed high catalyticactivity towards the hydrogenation of MMA, affording 100% of MMA conversion even under mildconditions without solvent and methyl isobutyrate was the only product.