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      • KCI등재

        Aqueous two-phase extraction to separate alpha-ketoglutaric acid from fermentation broth by combining crystallization

        Xueqi Shi,Weiyi Su,Hongyu Zhang,Jing Fang,Ning Xu,Yanjun Jiang,Hao Li 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.115 No.-

        Alpha-ketoglutaric acid (a-KG) is a crucial intermediate with broad application prospects. However, thedownstream separation of a-KG from fermentation broth with low concentration and complex componentshas become the bottleneck of large-scale production. In this study, a-KG was separated from theactual fermentation broth by aqueous two-phase system (ATPS) and crystallization. The optimal ATPScomposed of acetone/(NH4)2SO4 was selected by studying the phase diagram and a-KG distributionbehavior in different organic solvents and salts/sugars. Under the optimized conditions, the purity ofa-KG products from crude fermentation broth reached 98.08%, and the one-pass extraction efficiencywas 90.52%. The removal of cell debris and soluble proteins increased with the increase of acetone and(NH4)2SO4 concentrations, with the removal ratios reaching up to 99.44% and 86.54%. In addition,92.56% of the glucose was distributed in the aqueous phase. Although the a-KG fermentation broth ismore complex than the whole-cell biotransformation, impurities in the crude fermentation broth couldbe efficiently removed and a higher a-KG distribution coefficient was obtained. Meanwhile, the recovered(NH4)2SO4 could be reused for fermentation medium. This strategy provides an economical and effectivemethod combined with upstream biosynthesis to recover a-KG and other bioproducts from crude fermentationbroth.

      • KCI등재

        High Strength-Thermal Conductivity Mg–Ga–Ca–Ce Sheet by Hot-Extrusion and Rolling

        Mouxin Wu,Xueqi Jiang,Jihua Chen,Hongge Yan,Weijun Xia,Bin Su,Yifu Deng 대한금속·재료학회 2024 METALS AND MATERIALS International Vol.30 No.1

        The thermal conductivity of magnesium alloys is increasingly required for fast heat dissipation in the automotive and electronicfields. However, the methods for mechanical property improvement such as grain refinement and alloying tend to deterioratetheir thermal conductivity. In this work, a novel low-alloy Mg–2Ga–0.6Ca–0.6Ce alloy exhibits a surprisingly goodcombination of high strength and high thermal conductivity compared with the other samples. The wrought alloys are of smallgrain sizes (< 2 μm), have high yield strength (> 272 MPa) and exhibit excellent thermal conductivity (> 143 W·m−1·K−1). The as-extruded alloy exhibits excellent yield strength (272 MPa) and high thermal conductivity (144.6 W·m−1·K−1) atroom temperature. After 30% rolling, the yield strength is further increased to 283 MPa, and the thermal conductivity isslightly reduced to 143.2 W·m−1·K−1. The effects of Ca and Ce addition on mechanical properties and thermal conductivityare analyzed from dislocation density, dynamic recrystallization fraction (fDRX), average grain size (dDRX) and texturecharacteristics. The higher yield strength can be attributed to the combination of grain boundary strengthening, dislocationstrengthening and second phase strengthening. Moreover, the addition of Ca and Ce can obviously reduce solute Ga atomsin α-Mg, which is the key to high thermal conductivity. Therefore, adding two alloying elements, Ca and Ce, significantlyimproves both tensile properties and thermal conductivity.

      • KCI등재

        Diagentic features of illite in Upper Triassic Chang-7 tight oil sandstones, Ordos Basin

        Ai Wang,Dakang Zhong,Haihua Zhu,Lele Guo,Yangjinfeng Jiang,Xueqi Yang,Rui Xie 한국지질과학협의회 2019 Geosciences Journal Vol.23 No.2

        The Upper Triassic Chang-7 tight oil sandstones are the main tight clastic reservoirs in the Ordos Basin, central China. Illite is one of the most important cements affecting porosity and permeability of the tight oil sandstones, and this study focuses on different types of illitization and its relative formation time. The Chang-7 tight sandstones are mainly fine-grained lithic arkose and feldspar lithic sandstones, rich in mica and illite (hydrous mica). They are formed in distal delta front to semi-deep and deep lake facies, mainly deposited in a low energy environment. Porosity and permeability are very low (average porosity 8.58% and permeability 0.20 mD). The illite has many morphological characteristics and is multiphase, incorporating six types of illitization: hydrous mica, mica, and smectite illitization at the eodiagenetic stage, and kaolinite and K-feldspar illitization, and neoformation illite particles, at the mesodiagenetic stage. These different types of illitization are mainly controlled by sedimentary environment and provenance. Quartz overgrowth and diagenetic illites appear to be locally mutually exclusive, competing for detrital grain surfaces, but neoformation illite particles appear to form on the quartz overgrowth. The systematic study of Upper Triassic Chang-7 tight oil sandstones carried out here, enhances our understanding of illitization and the diagenetic model of the Ordos Basin, and contributes to reducing the exploration risk of continental tight sandstone reservoirs.

      • KCI등재

        Depositional and diagenetic controls on the reservoir quality of Upper Triassic Chang-7 tight oil sandstones, southwestern Ordos basin, China

        Ai Wang,Dakang Zhong,Haihua Zhu,Lele Guo,Zhuopei Li,Yangjinfeng Jiang,Xueqi Yang,Rui Xie,Xiaowei Zheng 한국지질과학협의회 2019 Geosciences Journal Vol.23 No.3

        The seventh oil layer of the Upper Triassic Yanchang Formation (Chang-7) tight oil sandstone reservoirs is a major exploration target. A significant amount of hydrocarbons has been discovered in these reservoirs in the southwestern Ordos basin in China. The Chang-7 tight sandstones are characterised as tight with low porosity, low permeability, and strong heterogeneity. This study investigates the sedimentary facies, diagenesis, and their impact on the reservoir quality of the Chang-7 tight oil sandstones. The sandstones were deposited in a deltaic-lacustrine depositional system. Three major depositional facies are identified consisting of delta front fed by braided rivers and meandering rivers, and slump turbidite fans. The depositional environment exerts a key control on reservoir quality. The distinct low-energy sedimentary environment produced fine to very fine-grained sandstones with high matrix and mica contents, characterised by low initial porosity and permeability. Diagenesis mainly comprised mechanical compaction and cementation by quartz, carbonate minerals and various clay minerals. The reservoir properties of the Chang-7 sandstones are generally poor, with porosity of 1.4–20.7% (average porosity 8.6%) and permeability of 0.001–116.7 mD (average 0.2 mD), which are attributed to significant compaction and cementation. Mechanical compaction was more important than cementation for reducing porosity, whereas secondary dissolution porosity was significant for the Chang-7 tight oil sandstones due to closer proximity to the underlying Chang-73 source rocks.

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