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      • Study on the Emerging VOCs Analysis Method using Purge&Trap GC/MS in Raw Water and Treated Water

        Sowon Kang(강소원),Hyunseung Cho(조현승),Taekkyun Choi(최택균),Sunku Park(박선구),Hakseok Kim(김학석),Sangrak Lee(이상락),Juhyun Park(박주현) 환경독성보건학회 2021 한국독성학회 심포지움 및 학술발표회 Vol.2021 No.5

        Volatile Organic Compounds (VOCs) are unsaturated hydrocarbons that cause odors and ozone through volatilization into the atmosphere. In this study, the analysis method of VOCs was performed using Purge & Trap gas chromatography/mass spectrometry. Analysis method was discussed and optimized. The results of 14 VOCs have shown that Method Detection Limit (MDL) was in the range from 0.0098 μg/L to 0.6519 μg/L and Limit of Quantification (LOQ) was in the range from 0.0313 μg/L to 2.0762 μg/L. The results of accuracy and precision ranged from 85.9 % to 114.8 % and 1.0 % to 3.3 %. Investigation of the matrix effects on tap water has shown that this method is suitable for VOCs analysis. Raw water and treated water of 15 water treatment plants were studied by developed method. As a results, Chloromethane was detected in the range from N/D to 1.924 μg/L of raw water and in the range from N/D to 4.595 μg/L of treated water. Detection frequency was 50.0 % of raw water and 86.6 % of treated water. In the case of Chloromethane in raw water, the frequency of detection was decreased during the period of wet season. In addition, in the case of water treatment plant that does not use a coagulant or uses river-side filtered water, the formation of chloromethane was less in treated water. These results are intended to be used as scientific basis data for the preparation of the water quality environment policy system in the future.

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