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        Theoretical and practical models for shear strength of corroded reinforced concrete columns

        Bo Yu,Zihao Ding,Shengbin Liu,Bing Li 국제구조공학회 2021 Structural Engineering and Mechanics, An Int'l Jou Vol.79 No.5

        In order to predict the shear strength of corroded reinforced concrete column (CRCC) accurately and efficiently, both theoretical and practical models for shear strength of the CRCC were established through theoretical derivation and experimental validation. The deterioration mechanism for shear strength of the CRCC due to the steel reinforcement corrosion was explored first based on the shear mechanism analysis of the truss-arch model. Then a theoretical model for shear strength of the CRCC was developed by taking into account the influences of steel reinforcement corrosion on the effective yield strength of transverse reinforcement, the effective cross-sectional area of both corroded transverse and longitudinal reinforcements as well as the effective concrete shear area. Meanwhile, three practical models to evaluate the shear strength of the CRCC were proposed based on 54 sets of experimental data by determining the approximate values of three important parameters, including the contribution coefficient of shear strength for concrete, the ratio of shear stiffness between the truss model and the arch model, as well as the tangent value of the critical crack angle. Finally, the accuracy and applicability of both theoretical and practical models for shear strength of the CRCC were validated by comparing with five existing empirical shear strength models.

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        Genome-wide analysis and environmental response profiling of dirigent family genes in rice (Oryza sativa)

        Rongjun Chen,Yongrong Liao,Shengbin Liu,Yunyun Jiang,Changqiong Hu,Xuewei Zhang,Xufeng Cao,Zhengjun Xu,Xiaoling Gao,Lihua Li,Jianqing Zhu 한국유전학회 2017 Genes & Genomics Vol.39 No.1

        Dirigent (DIR) and DIR-like family genes were involved in lignification or in the response to pathogen infection and abiotic stress in plants. Little is known to us about how rice DIR genes respond to adverse conditions. In this study, we reported genome-wide analysis of 49 DIR or DIR-likes genes in rice. The 49 OsDIRs or OsDIR-likes were tandem arranged into ten clusters. The phylogenetic analysis indicated that the 49 rice DIR and DIR-like genes cluster into five distinct subfamilies, DIR-a and four DIRlike subfamilies (DIR-b/d, and DIR-g, DIR-c, DIR-e). Meta-analysis of microarray gene expression datas indicated that all the OsDIRs or OsDIR-likes were expressed almost at the same level but with different patterns: most OsDIRs or OsDIR-likes were expressed exclusively in stigma and ovary and were induced by IAA and BAP; several genes were induced by trans-zeatin (tZ) and DMSO; 23 OsDIRs or OsDIR-likes were responded to abiotic stress. Our analysis also showed that most of these genes could respond to abiotic stresses, which contained cis-regulatory elements. The present study will provide a useful reference for further functional analysis of the DIR genes in rice.

      • Cyano-Substituted Head-to-Head Polythiophenes: Enabling High-Performance n-Type Organic Thin-Film Transistors

        Wang, Hang,Huang, Jun,Uddin, Mohammad Afsar,Liu, Bin,Chen, Peng,Shi, Shengbin,Tang, Yumin,Xing, Guichuan,Zhang, Shiming,Woo, Han Young,Guo, Han,Guo, Xugang American Chemical Society 2019 ACS APPLIED MATERIALS & INTERFACES Vol.11 No.10

        <P>Polythiophenes, built on the electron-rich thiophene unit, typically possess high-lying energy levels of the lowest unoccupied molecular orbitals (LUMOs) and show hole-transporting properties. In this study, we develop a series of n-type polythiophenes, <B>P1</B>-<B>P3</B>, based on head-to-head-linked 3,3′-dialkoxy-4,4′-dicyano-2,2′-bithiophene (BTCNOR) with distinct side chains. The BTCNOR unit shows not only highly planar backbone conformation enabled by the intramolecular noncovalent sulfur-oxygen interaction but also significantly suppressed LUMO level attributed to the cyano-substitution. Hence, all BTCNOR-based polymer semiconductors exhibit low-lying LUMO levels, which are ∼1.0 eV lower than that of regioregular poly(3-hexylthiophene) (rr-P3HT), a benchmark p-type polymer semiconductor. Consequently, all of the three polymers can enable unipolar n-type transport characteristics in organic thin-film transistors (OTFTs) with low off-currents (<I>I</I><SUB>off</SUB>s) of 10<SUP>-10</SUP>-10<SUP>-11</SUP> A and large current on/off ratios (<I>I</I><SUB>on</SUB>/<I>I</I><SUB>off</SUB>s) at the level of 10<SUP>6</SUP>. Among them, polymer <B>P2</B> with a 2-ethylhexyl side chain offers the highest film ordering, leading to the best device performance with an excellent electron mobility (μ<SUB>e</SUB>) of 0.31 cm<SUP>2</SUP> V<SUP>-1</SUP> s<SUP>-1</SUP> in off-center spin-cast OTFTs. To the best of our knowledge, this is the first report of n-type polythiophenes with electron mobility comparable to the hole mobility of the benchmark p-type rr-P3HT and approaching the electron mobility of the most-studied n-type polymer, poly(naphthalene diimide-<I>alt</I>-bithiophene) (i.e., N2200). The change of charge carrier polarity from p-type (rr-P3HT) to n-type (<B>P2</B>) with comparable mobility demonstrates the obvious effectiveness of our structural modification. Adoption of <I>n</I>-hexadecyl (<B>P1</B>) and 2-butyloctyl (<B>P3</B>) side chains leads to reduced film ordering and results in 1-2 orders of magnitude lower μ<SUB>e</SUB>s, showing the critical role of side chains in optimizing device performance. This study demonstrates the unique structural features of head-to-head linkage containing BTCNOR for constructing high-performance n-type polymers, i.e., the alkoxy chain for backbone conformation locking and providing polymer solubility as well as the strong electron-withdrawing cyano group for lowering LUMO levels and enabling n-type performance. The design strategy of BTCNOR-based polymers provides useful guidelines for developing n-type polythiophenes.</P> [FIG OMISSION]</BR>

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