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Lan Huong Nguyen,Van Son Le,Luu Dung Tran,Nam Van Thai,Ho Thi Ngoc Tram,Bui Quang Minh,Van Huy Nguyen 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.118 No.-
This study successfully developed a low-cost adsorbent from compositing between magnetic nanoparticle(CoFe2O4) and dragon fruit peel-derived biopolymer (DFP-BP) and applied it to remove arsenite (As(III)) from contaminated water. The batch experiments were designed to study the influence of operationalparameters on As(III) adsorption by nanocomposite (CoFe2O4@DFP-BP). With mapping analysis,the synthesized CoFe2O4@DFP-BP was characterized using SBET, SEM, FTIR, XRD, and EDS mapping. TheAs(III) adsorption mechanism was discussed based on material property data and isotherm and kineticanalysis. The result suggests that 5% is the best modification ratio on the CoFe2O4@DFP-BP for As(III)adsorption. The highest adsorption capacity of As(III) under the optimal conditions of pH 7, adsorbentdosage of 1.6 g/L, initial As(III) concentration of 2000 lg/L and the best described by the Sips modelwas 1922.7 lg/g. The adsorption kinetic followed pseudo-second-order, proving As(III) adsorption processcontrolled by chemisorption. The primary reaction pathway of As(III) adsorption on theCoFe2O4@DFP-BP5 was inner-sphere complexation through exchange between the nanoadsorbent’s surfaceand As(III) ions via oxygen-containing functional (carboxyl and hydroxyl) groups. The CoFe2O4 magneticnanoparticles coated by biopolymer overcame drawbacks, including low stability and mechanicalstrength of biopolymer and agglomerate trend of magnetic nanoparticles. The adsorption process washighly reversible and accessible in the separation of nanoadsorbent after adsorption by the magnet. Therefore, the nanocomposite formed from solid waste has excellent potential as a material for removingAs, contributing to sustainable development and feasibility in practical application.