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        Variation in trophic pathways and food web characteristics revealed by stable isotopes in an intermittent stream system of the Inukami River, Japan

        신현선,Nozomi Amahashi,Lan Ao,Osamu Mitamura 한국통합생물학회 2011 Animal cells and systems Vol.15 No.3

        To examine variation in trophic pathways and the characteristics of food webs from organic matters to aquatic insects, we used stable isotopes to study an intermittent stream system of the Inukami River, Japan. The aquatic insects, including Glossosoma spp., Chironominae spp., Stenelmis spp., Rhyacophilla nigrocephala, and Hexatoma spp., were characterized by different feeding strategies. The δ^13C values for these species indicated that Glossosoma spp. graze upon periphyton; Chironominae and Stenelmis spp. mainly feed on benthic particulate organic matter, and R. nigrocephala and Hexatoma spp., which were identified as predators, feed upon Glossosoma, Stenelmis, and/or Chironominae spp. This suggests that the trophic position of consumers at each station may be determined by the trophic position of basal food sources in situ. For trophic pathways, the δ^13C values for both organic matter and aquatic insects tended to gradually decrease, whilst the δ^15N values increased from the upper reach to the lower reaches, relative to the physicochemical and geographical conditions. These parameters indirectly influence the flow of energy from organic matter to consumers within food web in an intermittent stream system.

      • KCI등재

        Grain size distribution and chemistry of the brackish Lake sediment in Korea

        I Chan Shin,Tetsuji Akatsuka,Hisayuki Azumi,Lan Ao,Nozomi Amahashi,Maki Oyagi,Noriko Ishida,Naoshige Goto,Masahiro Maruo,Akihiko Yagi,Yashshi Seike,Seung Hyun Lee,Sung Ae Yoon,Jun Kil Choi,Young Woong 대한환경공학회 2021 Environmental Engineering Research Vol.26 No.5

        To determine the grain size distribution and chemical characteristics of bottom surface sediments in shallow brackish lagoons, we studied sediment samples collected from the entire horizontal lake area and in vertical profiles from three stations in Lakes Youngrang and Hwajinpo, on the eastern coast of Korea. Vertical and horizontal grain size distributions of the bottom sediments indicated predominantly sand- and silt in both lakes. The vertical distribution of C/N ratios ranged from 6.14 to 11.92 in Lake Youngrang, and 6.74 to 12.34 in Lake Hwajinpo. The horizontal distribution of C/N ratios in Lake Youngrang ranged from 6.1 to 17.6, whereas they ranged from 4.4 to 12.1 in Lake Hwajinpo. C/N ratios showed locally different responses to the origin of allochthonous (partial region) and autochthonous (entire region) organic materials. Horizontally, bottom sediment with low δ<SUP>13</SUP>C and high δ<SUP>15</SUP>N in Lake Youngrang were likely to be influenced by autochthonous organic material derived from primary production, and would be affected by N inputs from sources. In contrast, high δ<SUP>13</SUP>C and low δ<SUP>15</SUP>N sediments in Lake Hwajinpo were likely to be influenced by cyanobacteria.

      • SCOPUSKCI등재

        Variation in trophic pathways and food web characteristics revealed by stable isotopes in an intermittent stream system of the Inukami River, Japan

        Shin, Hyun-Seon,Amahashi, Nozomi,Ao, Lan,Mitamura, Osamu The Korean Society for Integrative Biology 2011 Animal cells and systems Vol.15 No.3

        To examine variation in trophic pathways and the characteristics of food webs from organic matters to aquatic insects, we used stable isotopes to study an intermittent stream system of the Inukami River, Japan. The aquatic insects, including Glossosoma spp., Chironominae spp., Stenelmis spp., Rhyacophilla nigrocephala, and Hexatoma spp., were characterized by different feeding strategies. The ${\delta}^{13}C$ values for these species indicated that Glossosoma spp. graze upon periphyton; Chironominae and Stenelmis spp. mainly feed on benthic particulate organic matter, and R. nigrocephala and Hexatoma spp., which were identified as predators, feed upon Glossosoma, Stenelmis, and/or Chironominae spp. This suggests that the trophic position of consumers at each station may be determined by the trophic position of basal food sources in situ. For trophic pathways, the ${\delta}^{13}C$ values for both organic matter and aquatic insects tended to gradually decrease, whilst the ${\delta}^{15}N$ values increased from the upper reach to the lower reaches, relative to the physicochemical and geographical conditions. These parameters indirectly influence the flow of energy from organic matter to consumers within food web in an intermittent stream system.

      • Kinetic Resolution of Allylic Alcohol with Chiral BINOL-Based Alkoxides: A Combination of Experimental and Theoretical Studies

        Liu, Yidong,Liu, Song,Li, Dongmei,Zhang, Nan,Peng, Lei,Ao, Jun,Song, Choong Eui,Lan, Yu,Yan, Hailong American Chemical Society 2019 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.141 No.2

        <P>The development and characterization of enantioselective catalytic kinetic resolution of allylic alcohols through asymmetric isomerization with chiral BINOL derivatives-based alkoxides as bifunctional Brønsted base catalysts were described in the study. A number of chiral BINOL derivatives-based alkoxides were synthesized, and their structure-enantioselectivity correlation study in asymmetric isomerization identified a promising chiral Brønsted base catalyst, which afforded various chiral secondary allylic alcohols (ee up to 99%, <I>S</I> factor up to >200). In the mechanistic study, alkoxide species were identified as active species and the phenol group of BINOL largely affected the high reactivity and enantioselectivity via hydrogen bonding between the chiral Brønsted base catalyst and substrates. The strategy is the first successful synthesis strategy of various chiral secondary allylic alcohols through enantioselective transition-metal-free base-catalyzed isomerization. The applicability of the strategy had been demonstrated by the synthesis of the bioactive natural product (+)-veraguensin.</P> [FIG OMISSION]</BR>

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