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        Characterization and performance of SmxA1xMnO3 (A=Ce, Sr, Ca) perovskite for efficient catalytic oxidation of toluene

        Jinghui Yao,Jiabin Zhou,Tianlei Zhang,Su Liu,Ke Du 한국화학공학회 2022 Korean Journal of Chemical Engineering Vol.39 No.11

        Catalytic oxidation of toluene was implemented over SmMnO3, Sm0.8A0.2MnO3 (ABO3, A=Ce, Sr, Ca) and Sm1xCaxMnO3 (x=0.0, 0.1, 0.2, 0.3) perovskite oxides synthesized via sol-gel method. The effects of A-site substitution of SmMnO3 and the amount of calcium substitution of SmMnO3 perovskite-type catalyst on the catalytic activity of toluene were investigated in a fixed bed reactor. The structure and chemical properties of the perovskites were studied by XRD, SEM, XPS, and H2-TPR. The results showed that the substitution of Ce and Ca had a positive impact about the catalytic properties of toluene oxidation, while a negative impact was caused by the substitution of Sr. The catalytic activity of toluene oxidation followed the order of Sm0.8Ca0.2MnO3>Sm0.8Ce0.2MnO3>SmMnO3>Sm0.8Sr0.2MnO3 in terms of the temperature of T90%, at toluene concentration=1,000 ppm and weight hourly space velocity (WHSV)=3,000mL/ g·h. Sm0.8Ca0.2MnO3 had the highest catalytic capacity (T90%=238 oC), which could be attributed to its high adsorbed oxygen concentration, Mn4+/Mn3+, and the best low-temperature reducibility (H2 consumption=0.36). Meanwhile, the Sm0.8Ca0.2MnO3 catalysts showed great long-term stability after 30 h of the reaction, and the toluene degradation rate remained over 95% at 350 oC.

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        Anwulignan alleviates D-galactose induced renal damage by regulating Nrf2/ARE signaling pathway in mice

        Chunna Liu,Huijiao Lin,Liu Jiawei,Yao Wang,Chunmei Wang,Jinghui Sun,Chunyan Yu,Ying Dong,Wenyue Zhuang,Shu Jing,JianGuang Chen,He Li 한국식품과학회 2021 Food Science and Biotechnology Vol.30 No.8

        Free radical accumulation in the body will cause oxidative stress damages including the renal damage. Schisandrae Sphenantherae Fructus (Schisandra), a traditional Chinese herbal medicine, has been used throughout the world. Anwulignan, a monomer extracted from Schisandra, has been shown in our previous studies to possess antioxidant and protective effects on the liver, brain and spleen damages in the aging mice. However, its effect on the renal damage caused by aging is not clear. This study showed that anwulignan could significantly increase the kidney index, the creatinine clearance, the activities of superoxide dismutase, catalase and glutathione peroxidase; reduce the urinary protein concentration, the serum urea nitrogen and creatinine content, the content of malondialdehyde and 8-hydroxylated deoxyguanosine in the renal tissue; and improve the renal tissue damage. Moreover, anwulignan increased the production of Nrf2, HO-1 and NQO1 proteins and decreased the production level of Keap1 protein in the renal tissue in the D-galactose induced aging mice. These results suggest that anwulignan significantly alleviates the renal damage by its antioxidant effect through regulating the production of Nrf2/ARE pathway-related proteins in the renal tissue in the D-galactose induced aging mice.

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        A Simplified Analytical Solution for the Necking Semi-empirical Stresses based on Aramis System

        Shier Dong,Anjiang Xian,Hazem Samih Mohamed,Yi Chen,Jinghui Yao 대한토목학회 2019 KSCE JOURNAL OF CIVIL ENGINEERING Vol.23 No.1

        To make comparison between classic necking stress solution Bridgman formula and ChenChi formula, the difference of necking surface profile assumptions in these two formulas were discussed theoretically. Then, the uniaxial tension experiment on 16 groups of carbon structural steels Q235 and Q345 were carried out at room temperature. Associate with the necking displacement measured by Aramis optical dynamic 3D strain measurement system, the parameter equation of necking surface profile was determined. The comparison results indicate that ChenChi formula is more accurate than Bridgman formula in calculating the necking stress distribution. Furthermore, to overcome the difficulty of measuring the radius curvature R in these formulas, an empirical formula of the geometric dimensions in the necking section was applied and the parameter was corrected based on the necking strain measured by Aramis system. As a result, the obtained equation in this study can provide an improved calculation method for the analysis of three-dimensional stress in necking and a reference for future research on the necking and ductile fracture of structural steels.

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