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Colloidal polymers from inorganic nanoparticle monomers
Hill, Lawrence J.,Pinna, Nicola,Char, Kookheon,Pyun, Jeffrey Elsevier 2015 Progress in polymer science Vol.40 No.-
<P><B>Abstract</B></P> <P>The use of preformed inorganic nanoparticles as “colloidal monomers” has received recent attention for the formation of one-dimensional (1-D) mesostructures, or “colloidal polymers.” These colloidal monomers form linear assemblies through attractive, directional, interparticle interactions, which are similar to covalent or supramolecular interactions in classical polymer science. However, in contrast to the high degree of structural control available in the synthesis of classical molecular polymers, methods to control fundamental structural features such as chain length (DP), composition (copolymers), and architecture (linear, branched, etc.) are still being developed for NP-based colloidal polymer systems. We therefore review the colloidal polymerization of inorganic nanoparticle monomers by applying the conceptual framework provided by polymer science to categorize these novel systems. The descriptive nomenclature used for classical polymers is applied to NP assembly to define more explicitly the types of colloidal polymers formed in terms of DP, architecture, and composition (for binary NP assemblies). This review includes descriptions of inorganic nanoparticle types useful for the formation of colloidal polymers with examples chosen to demonstrate control over mesoscopic structure and composition. The various emergent optical, electrical and electrochemical properties from these materials are also reviewed and correlated with structural control achieved in various colloidal polymer systems.</P>
THE SCALING RELATIONS AND STAR FORMATION LAWS OF MINI-STARBURST COMPLEXES
Nguyê,̃,n-Lu’o, Quang,Nguyê,̃,n, Hans V. V.,Motte, Fredé,rique,Schneider, Nicola,Fujii, Michiko,Louvet, Fabien,Hill, Tracey,Sanhueza, Patricio,Chibueze, James O.,Didelon, P American Astronomical Society 2016 The Astrophysical journal Vol.833 No.1
<P>The scaling relations and star formation laws for molecular cloud complexes (MCCs) in the Milky Way are investigated. MCCs are mostly large (R> 50 pc), massive (similar to 106 M circle dot) gravitationally unbound cloud structures. We compare their masses M-gas, mass surface densities Sigma(Mgas), radii R, velocity dispersions sigma, star formation rates (SFRs), and SFR densities Sigma(SFR) with those of structures ranging from cores, clumps, and giant molecular clouds, to MCCs, and galaxies, spanning eight orders of magnitudes in size and 13 orders of magnitudes in mass. This results in the following universal relations: sigma similar to R-0.5, M-gas similar to R-2, Sigma(SFR) similar to Sigma(1.5)(Mgas) , SFR similar to M-gas(0.9) , and SFR similar to sigma(2.7) Variations in the slopes and coefficients of these relations are found at individual scales, signifying different physics acting at different scales. Additionally, there are breaks at the MCC scale in the sigma-R relation and between starburst and normal star-forming objects in the SFR-M-gas and Sigma(SFR)-Sigma(Mgas) gas relations. Therefore, we propose to use the Schmidt-Kennicutt diagram to distinguish starburst from normal star-forming structures by applying a SMgas threshold of similar to 100M circle dot pc (2) and a Sigma(SFR) threshold of 1M circle dot yr (1) kpc (2). Mini-starburst complexes are gravitationally unbound MCCs that have enhanced Sigma(SFR) (> 1M circle dot yr(-1) kpc(-2)), probably caused by dynamic events such as radiation pressure, colliding flows, or spiral arm gravitational instability. Because of dynamical evolution, gravitational boundedness does not play a significant role in regulating the star formation activity of MCCs, especially the mini-starburst complexes, which leads to the dynamical formation of massive stars and clusters. We emphasize the importance of understanding mini-starbursts in investigating the physics of starburst galaxies.</P>