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Li, Y.,Balé,dent, V.,Bariš,ić,, N.,Cho, Y.,Fauqué,, B.,Sidis, Y.,Yu, G.,Zhao, X.,Bourges, P.,Greven, M. Macmillan Publishers Limited. All rights reserved 2008 Nature Vol.455 No.7211
The pseudogap region of the phase diagram is an important unsolved puzzle in the field of high-transition-temperature (high-T<SUB>c</SUB>) superconductivity, characterized by anomalous physical properties. There are open questions about the number of distinct phases and the possible presence of a quantum-critical point underneath the superconducting dome. The picture has remained unclear because there has not been conclusive evidence for a new type of order. Neutron scattering measurements for YBa<SUB>2</SUB>Cu<SUB>3</SUB>O<SUB>6+δ</SUB> (YBCO) resulted in contradictory claims of no and weak magnetic order, and the interpretation of muon spin relaxation measurements on YBCO and of circularly polarized photoemission experiments on Bi<SUB>2</SUB>Sr<SUB>2</SUB>CaCu<SUB>2</SUB>O<SUB>8+δ</SUB>(refs 12, 13) has been controversial. Here we use polarized neutron diffraction to demonstrate for the model superconductor HgBa<SUB>2</SUB>CuO<SUB>4+δ</SUB> (Hg1201) that the characteristic temperature T* marks the onset of an unusual magnetic order. Together with recent results for YBCO, this observation constitutes a demonstration of the universal existence of such a state. The findings appear to rule out theories that regard T* as a crossover temperature rather than a phase transition temperature. Instead, they are consistent with a variant of previously proposed charge-current-loop order that involves apical oxygen orbitals, and with the notion that many of the unusual properties arise from the presence of a quantum-critical point.
Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework
Souto, Manuel,Romero, Jorge,Calbo, Joaquí,n,Vitó,rica-Yrezá,bal, Iñ,igo J.,Zafra, José,L.,Casado, Juan,Ortí,, Enrique,Walsh, Aron,Mí,nguez Espallargas, Guille American Chemical Society 2018 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.140 No.33
<P/><P>“Breathing” metal–organic frameworks (MOFs) that involve changes in their structural and physical properties upon an external stimulus are an interesting class of crystalline materials due to their range of potential applications including chemical sensors. The addition of redox activity opens up a new pathway for multifunctional “breathing” frameworks. Herein, we report the continuous breathing behavior of a tetrathiafulvalene (TTF)-based MOF, namely <B>MUV-2</B>, showing a reversible swelling (up to ca. 40% of the volume cell) upon solvent adsorption. Importantly, the planarity of the TTF linkers is influenced by the breathing behavior of the MOF, directly impacting on its electrochemical properties and thus opening the way for the development of new electrochemical sensors. Quantum chemical calculations and Raman spectroscopy have been used to provide insights into the tunability of the oxidation potential.</P>