새로운 고효울 유기 폴리머 녹색발광소자의 제작 및 특성 분석

오환술,Oh, Hwan-Sool 대한전자공학회 2001 電子工學會論文誌-SD (Semiconductor and devices) Vol.38 No.12

낮은 동작전압에서 안정하게 동작하고 고효율을 갖는 단층 폴리머 녹색광소자를 갖는 새로운 물질을 합성하였으며 이는 폴리머물질인 PC(B79)에 유기단분자인 전자수송성이 ?어난 NIDI와 정공수송성이 뛰어난 TTA를 분자분산하여 첨가색소인 C6의 도핑농도에 변화를 주어 스핀코팅으로 녹색발광소자를 제작하였다. 소자 구조는 glass/ITO/PC:TTA:NIDI:C6/cathode이고 음극전극으로 일함수가 낮은 Ca과 Mg 그리고 Ca/Al을 진공증착하여 전기적${\cdot}$광학적 특성을 비교조사하였다. C6의 도핑농도가 0.08mole%에서 양자효율이 최대인 0.52%를 얻었고 이것은 도핑하지 않을때보다 약 50배 높았고, 동작개시전압도 2.4V의 낮은 동작 개시전압에서 안정하게 동작하였다. 한편 PL과 EL측정결과 C6의 도핑농도를 변화하여도 발광파장의 최대값은 거의 일정하였다. PL강도의 최대발광파장은 495nm였고 EL강도의 최대발광파장은 520nm이고 FWHM은 약 70nm를 얻었다. Single-layer polymer green electroluminescent devices were fabricated with novel material synthesis by using moleculely-dispersed TTA and NIDI into the polymer PC(B79) emitter layer doped with C6 fluorescent dye which has low operating voltage and high quantum efficiency. A EL cell structure of glass substrate/indium-tin-oxide/PC:TTA:NIDI:C6/Ca/Al was employed and compared with various low work function cathode electrodes Ca and Mg metals. By adjusting the concentration of the fluorescent dye C6, low turn-on voltage of 2.4V was obtained, maximum quantum efficiency of 0.52% at 0.08mole% has been improved by about a factor of ~50 times in comparison with the undoped cell. The PL and EL colors can't be turned by changing the concentration of the C6 dopant. PL emission peaking was obtained at 495nm and EL emission peaking at 520nm with FWHM ~70nm

光誘電體 導波路에서의 스윗칭效果에 관한 解釋

吳煥述(Oh Hwan Sool),金映權(Kim Young Kwon) 대한전자공학회 1986 대한전자공학회 학술대회 Vol.1986 No.12

PVA 배열층을 이용한 펜타신 유기 박막 트랜지스터의 전기적 특성

전현성,오환술,Jun, Hyeon-Sung,Oh, Hwan-Sool 한국전기전자재료학회 2010 전기전자재료학회논문지 Vol.23 No.3

The pentacene-based organic thin film transistors(OTFTs) using polyvinylalcohol(PVA) alignment layer were fabricated on the $SiO_2$ evaporated to n-type (111) Si substrates. The pentacene film was deposited by thermally evaporated at $10^{-7}$ torr. X-ray diffraction (XRD) and atomic force microscope(AFM) measurement showed pentacene film which deposited on rubbed PVA layers were partially crystallized at (001) plane. The pentacene OTFTs with PVA layers rubbed perpendicular to the direction of current flow was shown to align better orientation than parallel rubbed case and thus to enhance the mobility and saturation current by a factor of 2.3 respectively. We obtained mobility by 0.026 $cm^2$/Vs and on-off current ratio by ${\sim}10^8$.

2개의 형광 도판트를 적용한 단일발광층 유기발광소자의 광학적 특성 연구

김태구,오환술,김유현,김우영,Kim, Tae-Gu,Oh, Hwan-Sool,Kim, You-Hyun,Kim, Woo-Young 한국진공학회 2010 Applied Science and Convergence Technology Vol.19 No.3

Organic light-emitting diodes (OLEDs) with single emissive layer structures using two fluorescent dopants were fabricated and the device was composed of ITO / NPB ($700{\AA}$) / MADN : C545T - 1.0% : DCJTB - 0.3% ($300{\AA}$) / Bphen ($300{\AA}$) / LiF ($10{\AA}$) /Al ($1,000{\AA}$). C545T and DCJTB were functioned as green fluorescent dye and red fluorescent dye under MADN as host material. Concentrations of C545T and DCJTB was changed in emissive layer of MADN. Optimized OLED device using two fluorescence dopants shows emission efficiency of 8.42 cd/A and luminescence of 3169 cd/$m^2$at 6 V with CIE color coordinate, (0.43, 0.50). Electroluminescence of optimized OLED showed two peak at 500 and 564 nm according to C545T and DCJTB. These results indicate that F$\ddot{o}$ster energy transfer energy transfer was from MADN to C545T and rather than to DCJTB continuously. 두 가지의 형광도판트를 이용하여 제작된 단일 발광층 유기발광다이오드(OLEDs)는 ITO / NPB ($700{\AA}$) / MADN : C545T - 1.0% : DCJTB - 0.3% ($300{\AA}$) / Bphen ($300{\AA}$>) / LiF ($10{\AA}$) / Al ($1,000{\AA}$)으로 구성되었다. C545T와 DCJTB는 각각 녹색과 적색 도판트로 사용되었고, 호스트 물질인 MADN에 대해서 각각 다른 농도로 도핑하였다. 이러한 두 가지 형광도 판트를 사용한 제적화된 OLED는 8.42 cd/A의 효율과 6 V에서 $3169 cd/m^2$의 발광 휘도와 (0.43, 0.50)의 색좌표를 가졌다. 이러한 OLED 구조의 electroluminescence는 각각 C545T와 DCJTB에 따라 500 nm와 564 nm의 피크를 가졌다. 이러한 결과는 MADN에서 C545T로 C545T에서 DCJTB로 포스터 에너지 전이가 일어났음을 설명할 수 있다.

고출력 CSP-LOC 레이저 다이오드의 모우드 특성에 관한 연구

윤석범,오환술,Yoon, Seok-Beom,Oh, Hwan-Sool 대한전자공학회 1988 전자공학회논문지 Vol. No.

본 논문은 최적의 고출력용 (GaAl) As/GaAs CSP-LOC 레이저 다이오드 구조를 설계하기 위하여 컴퓨터 시뮬레이션 하였다. 실험 데이터를 근거로한 레이저다이오드의 설계변수로 각 층의 두께, 흡수계수, 스트라이프 폭등이 사용되었고 활성층(d2)와 광 도파로층(d3)의 두께가 각각 0.08um, 0.5um일때와 0.1um, 0.4um일때 최적의 안정된 고출력용 CSP-LOC 구조를 얻었다. 따라서 본 노문에서는 실용적인 반도체레이저의 컴퓨터 시뮬레이션 프로그램을 개발하였고 임의의 재료를 갖는 CSP-LOC 구조에 이 프로그램의 적용이 가능하다. In this paper, we have optimized the computation of the CSP - LOC (Channel Substrate Planar-Large Optical Cavity) structure to design the gith power (Ga, Al) As/GaAs CSP-LOC laser diode. The parameters of the device on the bases of experimental datas include the effects of the various layer thickness, material absorption coefficients, stripe width and so forth. At active layer ($d_2$)=0.08 um with optical layer ($d_3$)=0.5 um and $d_2$ = 0.1 um with $d_3$ = 0.4 um, we find the narrower beam divergence and stable high power in the lowest-order mode without the phenomenon of spatial hole burning. The results of theoretical computation show good agreement with experimental measurements made on LPE grown CSP-LOC. Finally, we developed an practical program and the program is applicable to the CSP-LOC lasers with any materials.

광 통신용 1.3μm DCPBH - DFB 레이저 다이오드 제작

강명구,오환술 ( Myung Koo Kang,Hwan Sool Oh ) 한국전기전자재료학회 1997 전기전자재료학회논문지 Vol.10 No.4

신규 비공액성 청색발광재료 PPPMA-co-DTPM 공중합체 합성을 통한 백색유기발광소자 제작

조재영,오환술,김태구,윤석범,Cho, Jae-Young,Oh, Hwan-Sool,Kim, Tae-Gu,Yoon, Seok-Beom 한국전기전자재료학회 2005 전기전자재료학회논문지 Vol.18 No.7

To fabricate a single layer white organic light emitting diode (OLED), a novel non-conjugated blue emitting material PPPMA-co-DTPM copolymer was synthesized containing a perylene moiety unit with hole transporting and blue emitting ability and a triazine moiety unit with electron transporting ability. The devices were fabricated using PPPMA-co-DTPM $(PPPMA[70\;wt\%]:DTPM[30\;wt\%])$ copolymer by varying the doping concentrations of each red, green and blue fluorescent dye, by molecular-dispersing into Toluene solvent with spin coating method. In case of ITO/PPPMA-co-DTPM:TPB$(3\;mol\%):C6(0.04\;mol\%):NR(0.015\;mol\%)/Al$ structure, as they were molecular-dispersing into 30 mg/ml Toluene solvent, nearly-pure white light was obtained both (0.325, 0.339) in the CIE coordinates at 18 V and (0.335, 0.345) at 15 V. The turn-on voltage was 3 V, the light-emitting turn-on voltage was 4 V, and the maximum external quantum efficiency was $0.667\%$ at 24.5 V. Also, in case of using 40 mg/ml Toluene solvent, the CIE coordinate was (0.345, 0.342) at 20 V.

Low Power Digital Logic Gate Circuits Based on N-Channel Oxide TFTs

임도,박기찬,오환술,Ren, Tao,Park, Kee-Chan,Oh, Hwan-Sool The Institute of Electronics and Information Engin 2011 電子工學會論文誌-SD (Semiconductor and devices) Vol.40 No.1

N-channel 산화물 박막 트랜지스터(Thin Film Transistor, 이하 TFT)만을 이용한 저소비전력 inverter, NAND, NOR의 논리 게이트 회로를 제안한다. 제안된 회로는 asymmetric feed-through와 bootstrapping을 이용해서 pull-up, pull-down 스위치가 동시에 켜지지 않도록 설계하였다. 그 결과로 출력신호 전압 범위가 입력신호 전압과 동일하고 정전류가 흐르지 않는다. 인버터는 5 개의 TFT와 2 개의 capacitor로, NAND 및 NOR 게이트는 각각 10 개의 TFT와 4 개의 capacitor로 구성된다. 산화물 TFT 모델을 사용하여 SPICE 시뮬레이션을 수행하여 제안된 회로의 동작을 성공적으로 검증하였다. Low-power logic gates, i.e. inverter, NAND, and NOR, are proposed employing only n-channel oxide thin film transistors (TFTs). The proposed circuits were designed to prevent the pull-up and pull-down switches from being turned on simultaneously by using asymmetric feed-through and bootstrapping, thereby exhibited same output voltage swing as the input signal and no static current. The inverter is composed of 5 TFTs and 2 capacitors. The NAND and the NOR gates consist of 10 TFTs and 4 capacitors respectively. The operations of the logic gates were confirmed successfully by SPICE simulation using oxide TFT model.

차세대 CMOS구조에서 고에너지 이온주입에 의한 래치업 최소화를 위한 모델 해석

노병규,조소행,오환술,Roh, Byeong-Gyu,Cho, So-Haeng,Oh, Hwan-Sool 대한전자공학회 1999 電子工學會論文誌, D Vol.d36 No.2

차세대 CMOS용 구조에서 래치업 특성을 최소화하는 고에너지 이온주입을 이용한 retrograde well과 게더링(매몰층)의 최적 공정 설계 변수 값들을 구했다. 본 논문에서는 두 가지의 모의 모델 구조를 제안하고, Silvaco사의 Athena와 Atlas 툴에 의한 모의실험 결과를 비교 분석하였다. 첫 번째 모델은 게더링층과 retrograde well,을 조합한 구조이며 트리거전류가 600 ${\mu}A/{\mu}m$ 이상의 결과를 얻었고, 두 번째 모델은 twin retrograde well을 이용하여 유지전류가 2500${\mu}A/{\mu}m$ 이상의 결과를 얻었다. 모의실험결과 두 모델 모두 도즈량이 많을수록 패치업 면역 특성이 좋아짐을 보았다. 모의실험 조건에서 두 모델 모두 n'-p' 간격은 2${\mu}m$로 고정하였다. We designed the optimal device parameters of the retrograde well and the gettering layer(buried layer) using the high energy ion implantation for the next generation of CMOS struoture and proposed two models and simulated these models with Athena and Atlas, Silvaco Co. We obtained trigger currents which is more than 600 ${\mu}A/{\mu}m$ when the structure has been combined the gettering layer and the retrograde well. And the second model(twin retrograde well) was obtained that holdingcurrents were over 2500${\mu}A/{\mu}m$. As results, the more heavier dose, the more improved the latch-up immunity. The n'-p' spacing was fixed a 2${\mu}m$ in both models.

신규 합성한 청색발광재료 nitro-DPVT를 사용한 백색 유기발광다이오드의 형광색소 도핑농도 및 NPB 층의 두께 변화에 따른 특성 분석

전현성,조재영,오환술,윤석범,Jeon, Hyeon-Sung,Cho, Jae-Young,Oh, Hwan-Sool,Yoon, Seok-Beom 한국전기전자재료학회 2006 전기전자재료학회논문지 Vol.19 No.4

A stacked white organic light-emitting diode (OLED) having a blue/orange emitting layer was fabricated by synthesizing nitro-DPVT, a new derivative of the blue-emitting material DPVBi on the market. The white-emission of the two-wavelength type was successfully obtained by using both nitro-DPVT for blue~emitting material, orange emission as a host material and Rubrene for orange emission as a guest material. The basic structure of the fabricated white OLED is glass/ITO/NPB$(200{\AA})$/nitro-DPVT$(100{\AA})$/nitro-DPVT:$Rubrene(100{\AA})/BCP(70{\AA})/Alq_3(150{\AA})/Al(600{\AA})$. To evaluate the. characteristics of the devices, firstly, we varied the doping concentrations of fluorescent dye Rubrene from 0.5 % to 0.8 % to 1.3 % to 1.5 % to 3.0 % by weight. A nearly pure white-emission was obtained in CIE coordinates of (0.3259, 0.3395) when the doping concentration of Rubrene was 1.3 % at an applied voltage of 18 V. Secondly, we varied the thickness of the NPB layer from $150{\AA}\;to\;200{\AA}\;to\;250{\AA}\;to\;300{\AA}$ by fixing doping with of Rubrene at 1.3 %. A nearly pure white-emission was also obtained in CIE coordinates of (0.3304, 0.3473) when the NPB layer was $250-{\AA}$ thick at an applied voltage of 16 V. The two devices started to operate at 4 V and to emit light at 4.5 V. The external quantum efficiency was above 0.4 % when almost all of the current was injected.