견의 저온 염색에 관한 연구 I. 산성 Milling형 염색에 있어서의 저온염색

배도규,배현석,정태암 한국잠사학회 1992 한국잠사곤충학회지 Vol.34 No.2

견의 저온염색용 조제(K-1)를 사용하여 염료 농도, 염욕의 pH, 염색시간에 따른 염색속도를 구하여 이 저온염색용가 염색에 미치는 영향을 분석한 결과를 다음과 같이 요약한다. 1. pH 7에서 K-1의 농도가 증가할수록 무첨가구에 비해 흡진율은 증가 하였으며, K-1의 농도가 3% o.w.f. 이상에서는 증가의 경향이 둔화되었다. 2. pH 5에서도 무첨가보다 K-1의 첨가구에서 높은 흡진율을 보였으며, pH 7의 5$0^{\circ}C$ 첨가구가 pH 5, 5$0^{\circ}C$의 무첨가구보다 확산성은 높게 나타났다. 3. 염료 농도별로 볼 때 pH 7과 pH 5에서 모두 K-l 첨가구에서는 무첨가구보다 흡진율이 클 뿐만 아니라 염료 농도에 따른 흡진율 감소가 적게 일어났다. Using the new type auxiliary(K-1), dyeing experiment was done at the various dyeing conditions and the effects of auxiliary on the dyeing properties of acid milling dye for the silk fiber were dicussed. The results obtained were as follows; 1. The exhaust rate of acid milling dye was increased according to the auxiliary concentration at dyebath pH 7, But the increasing tendency of exhaust rate was decreased above auxiliary concentration 3% o. w. f.. 2. It was the same tendency of exhaust rate at dyebath pH 5, but the diffusion was more powerful at dyebath pH 7 than pH 5. 3. The decreasing ratio of exhaust rate according to dye concentration increasing was lower at auxiliary addition than auxiliary non-addition. 4. The exhaust rate curve according to increasing dyeing temperature showed the inflection point at auxiliary non-addition, but it was not observed in auxiliary addition. Consequently, it seems to be avoid that the occurrence of uneven dyeing at auxiliary addition.

팥 종피에서의 색소 추출과 저장 안정성

배도규,정양숙 경북대학교 농업과학기술연구소 2010 慶北大農學誌 Vol.28 No.-

본 연구에서는 붉은팥과 검정팥 종피에 함유된 천연색소에 대한 연구의 일환으로, 추출방법에 따른 색소 추출 효율과 저장안정제 첨가에 따른 저장 안정성과 특성을 검토하여 다음과 같은 결과를 얻었다. 1. 붉은팥 종피의 용액 추출 시 까지는 온도가 높을수록, 시간이 경과될수록 색소 추출 효율이 높게 나타났으나, 에서는 시간이 경과될수록 색소 추출효율이 감소하는 경향을 보이며 pH 조건에서는 pH 5가 가장 효율적이었다. 2. 검정팥 종피의 용액 추출 시 온도가 높을수록, 시간이 경과될수록 색소 추출 효율이 높게 나타났으며, pH 조건에서는 pH 5가 가장 효율적이었다. 3. 착액 추출 시, 붉은팥의 경우 pH 5의 전처리가 증류수보다 색소 추출량이 많았으며, 검정팥의 경우 단시간 전처리에서는 증류수가 pH 5에서 보다 색소 추출량이 많았지만, 4시간 이상의 전처리에서는 오히려 pH 5에서 많게 나타났다. 4. 저장 안정제로 Methionine을 첨가한 결과에서는 붉은팥 종피의 경우에는 첨가량이 많을수록, 검정팥 종피의 경우에는 10mmol첨가가 20mmol 첨가보다 안정 효과가 큰 것으로 나타났다. Extraction efficiency of colorants from red bean and black bean seed coat and its storage stability were examined according to the various extracting and storage conditions in this study. The obtained results were as follows ; The absorbance values of extracted colorants were increased with increasing extract time and temperature. pH 4 extracting was most efficient among the various pH conditions. The absorbance values of extracted colorant from red bean were increased with increasing extract time and temperature, when the extraction process was kept at and , but it were decreased with increasing extract time at . In the case of black bean, it were also increased with increasing extract time and temperature. pH 5 extract was most efficient among the various pH conditions. In juice extractor system from red bean, the pH 5 of the pre-treatment was more efficient than the distilled water of pre-treatment. In black beans of the short-term pre-treatment with distilled water, the colorant was extracted better than at pH 5, but above 4 hours pre-treatment was decrease in pH 5. The Methionine added as a stabilizer gave the more effect to the stability of colorant from red bean the more Methionine addition. In the case of black bean 10mmol addition of methionine was more efficient than 20mmol.

수수에서의 색소 추출과 저장 안정성

배도규,이성은 경북대학교 농업과학기술연구소 2010 慶北大農學誌 Vol.28 No.-

본 연구에서는 수수피에 함유된 천연색소에 대한 연구의 일환으로, 추출방법에 따른 색소 추출 효율과 저장안정제 첨가에 따른 저장 안정성과 특성을 검토하여 다음과 같은 결과를 얻었다. 1. 용액 추출 시 온도가 높을수록, 시간이 경과될수록 색소 추출 효율이 높게 나타났으며, pH 조건에서는 pH 4가 가장 효율적이었다. 2. 착액 추출 시, 단시간 전처리에서는 증류수가 pH 5에서보다 색소 추출량이 많았지만, 20시간 이상의 장시간 전처리에서는 오히려 pH 5에서 많게 나타났다. 3. 수수피 색소용액의 pH 변화에 따른 색도는, pH가 증가할수록 옅은 황색에서 짙은 황색을 거쳐 붉은색 톤으로 변화하였다. 4. 저장 안정제로 Methionine을 첨가한 결과에서는 첨가에 따른 수수피 색소의 안정화 효과에서 저장기간 18일까지는 변색 지연 효과를 보였으며, Methionine 10 mmol 첨가>20 mmol 첨가>무첨가 순으로 안정 효과가 크게 나타났다. Extraction Efficiency of colorants from sorghum and its storage stability were examined according to the various extracting and storage conditions in this study. The obtained results were as follows ; The absorbance values of extracted colorants were increased with increasing extract time and temperature. The extraction at pH 4 extract was most efficient among the various pH conditions. In the juice extractor system, the amount of extracted colorant was more in distilled water pre-treatment than pH 5, but it was more in pH 5 in the long time pre-treatment above 20 hour. The color of extract solutions changed through variation of the pH. Its color changed from light yellow to heavy yellow finally red ton by pH increasing. The Methionine addition gave an effect on the storage stability of colorant solution and then had better storage stability. And so it delayed the color change up to storge period 18th day and the stabilizing effect was revealed in order of Methionine 10mmol-addition>20mmol-addtion>non-addtion.

Silk/Polyester 혼섬유 재료의 감량가공에 관한 연구 : Ⅱ.Spun silk/Polyester 혼섬유의 감량가공 Ⅱ.The Weight loss Finishing for the Spun silk/Polyester

배도규 한국잠사학회 1994 한국잠사곤충학회지 Vol.36 No.1

The weight lost for the mixture (spun silk/PET) was tested to investigate the effects of weight loss accelerator on the degumming and weight loss. The degumming loss of spun silk was drcreased while the weight loss of polyester (PET) was increased depending on the increased of weight loss accelerator concentration. The proper degumming of spun silk was obtained and simultancously the weight loss of PET was high for the spun silk/PET "A" and "B" type. The proper degumming of spun silk was obtained but the weight of PET was loss for the spun silk/PET "D" and "E" type. The degumming curve in spun silk part was showed the typical degumming curve but the weight loss of PET was increased depending on the increased of treatment time in the weight loss for the fabric composed of spun silk/PET.

絹織物의 방추성에 關한 硏究 : Ⅰ.絹紡絲織物을 中心으로 Ⅰ.Wrinkle Recovery behavior of spun-silk fabric

裵道奎,南重熙,金種鎬 한국잠사학회 1986 한국잠사곤충학회지 Vol.28 No.1

This work was to realize the wrinkling behavior of spun silk fabric. The results were obtained through the various conditions such as temperature, wrinkling time, wrinkling load and crease recovery time. The obtained results were summerized as follows: 1. Wrinkle recovery of the silk fabric was decreased with the increase of temperature, humidity and the influence of humidity was superior to the influence of temperature. 2. The change of wrinkle recovery depending on the wrinkle recovery time showed the experimental equation (Y=a÷b ln T). The wrinkle recovery increased with the lapse of wrinkle recovery time but arrived at the equilibrium position about 300 sec. 3. The value "K1" of the silk fabric in the "Voigt model" was inferior as compared with the polyester and Nylon. 4. The change of wrinkle recovery depending on the wrinkling time was decreased with the lapse of wrinkle recovery time but the change of the value "a" could not be fined. 5. The change of wrinkle recovery depending on the wrinkling load was same as above 4.

Redox계에 의한 MAA Gragt 속도에 관한 연구

배도규,김종호 한국잠사학회 1997 한국잠사곤충학회지 Vol.39 No.1

The MAA graftings in silk fiber were done by redox system for the purpose of investingating the effect of ferrous sulfate additive on the grafting rate and graft ratio in various conditions. The graft ratio was higher in redox graft system than in peroxide graft system and the graft ratio in redox graft system was also higher depending on decrease of ferrous sulfate additive. The saturation graft ratio obtained by empirical equation, log X=K/t, was increasing depending on the increase of ferrous sulfate additive. Initial grafting rate was increased but the latter grafting rate was decreased in redox graft system. The effects of liquor ratio(L.R.) on the graft ratio in redox graft system, were higher in high L.R. than in low L.R..

견의 가공기술에 대해서

배도규 한국섬유공학회 1994 한국섬유공학회지 Vol.31 No.7

세리신 정착 기구에 관한 연구

배도규 한국잠사학회 1995 한국잠사곤충학회지 Vol.37 No.2

The sericin fixation of raw silk by glutaraldehyde solutions with catalyst(serifix B) was done and the effect of sericin fixation by catalyst on reaction mechanism, whiteness and physical properties were investigated and discussed. The obtained results were summarized as follows; 1) The complete sericin fixation were obtained by glutaraldehyde solution regardless the concentration of catalyst. 2) The tenacities of sericin fixed silk increased in comparison with that of nontreated silk. 3) There were not constant tendency in elongation of sericin fixed silk in comparison with nontreated silk. 4) The whiteness of sericin fixed silk treated glutaraldehyde solution with 5% o.w.f. or more were increased in comparison with that of nontreated silk. 5) FT-lR spectra were quite different from sericin fixed reagent and catalyst.

Redox계에 의한 MAA Graft 속도에 관한 연구

배도규,김종호 한국잠사학회 1997 한국잠사곤충학회지 Vol.39 No.1

The MAA graftings in silk fiber were done by redox system for the purpose of investigating the effect of ferrous sulfate additive on the grafting rate and graft ratio in various conditions. The graft ratio was higher in redox graft system than in peroxide graft system and the graft ratio in redox graft system was also higher depending on decrease of ferrous sulfate ddditive. The saturation graft ratio obtained by empirical equation, log X=K/t, was increasing depending on the increase of ferrous sulfate additive. Initial grfting rate was increased but the latter grafting rate was decreased in redox graft system. The effects of liquor ratio(L.R.) on the graft ratio in redox graft system, were higher in high L.R. than in low L.R..

실크의 非衣類用 이용

배도규 한국잠사학회 1994 한국잠사곤충학회지 Vol.36 No.2