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Zhiyong Chen,Jianjun Lu,Xuping Li,Xuting Jin,Lijuan Shi,Miaoqing Liu,Zhilin Sun 한국고분자학회 2015 Macromolecular Research Vol.23 No.9
A novel 1,10-phenanthroline-functionalized polyimide (CMPI-Phen) was prepared as polymer matrix by the nucleophilic substitution reaction between chloromethylated polyimide (CMPI) and 5-amino-1,10-phenanthroline (NH2-Phen). Then, two kinds of luminescent materials of 1,10-phenanthroline-functionalized polyimide containing Eu(III) complexes, were obtained by two different methods. Their structures and properties were characterized by Fourier transform infrared (FTIR) spectroscopy, 1H nuclear magnetic resonance (NMR) spectroscopy, elemental analysis, inductively coupled plasma (ICP), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), X-ray diffraction (XRD), luminescence spectrometry, and luminescence decay analysis. Investigations revealed that both the CMPI-Phen-Eu(III) and CMPI-Phen-Eu(TTA)3 display highly efficient red emissions, suggesting their potential application as luminescent materials. However, compared with CMPI-Phen-Eu(III), CMPI-Phen-Eu(TTA)3, where TTA stands for thenoyltrifluoroacetone, exhibits more excellent and stable fluorescence intensity and longer luminescence lifetime (134.30 μs). The weight-average molecular weights of CMPI-Phen-Eu(III) and CMPI-Phen- Eu(TTA)3 are 2.40×104 and 3.11×104, respectively. The Eu contents of CMPI-Phen-Eu(TTA)3 and CMPI-Phen-Eu(III) were measured by ICP to be 7.00% and 5.92%, respectively. TGA demonstrated that both CMPI-Phen-Eu(III) and CMPI-Phen-Eu(TTA)3 have high thermal stability and their 5% loss weight temperatures were 356 and 280 oC, respectively. Moreover, both CMPI-Phen-Eu(III) and CMPI-Phen-Eu(TTA)3 were soluble in polar solvents such as dimethylformamide (DMF), dimethylacetamide (DMAc), 1-methyl-2-pyrrolidone (NMP), and dimethylsulfoxide (DMSO) under heating conditions, and could be easily cast into tough thin films.
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Xuefeng Zhang,Yujie Zhang,Qin Yang,Yingchun Yang,Xuping Sun 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.127 No.-
Sulfate radical-based advanced oxidation processes (AOPs) are highly reliable for the elimination of recalcitrantcontaminants by increasing degradability and reducing toxicity. Here, MnFe2O4 nanowires(MnFe2O4 NWs), composed of abundant MnFe2O4 nanoparticles immobilized on one-dimensional carbonnanowires derived from annealed MnFe-Nitrilotriacetic acid (MnFe-NTA) precursor was successfully synthesized. The MnFe2O4 NWs, which could provide more active sites, were then utilized to activate peroxymonosulfate(PMS) for oxidizing the target pollutant Moxifloxacin (MOX) in an aqueous solution. TheMnFe2O4 NWs/PMS system acquired 91.9% removal of MOX and achieved 55.1% chemical oxygen demand(COD) degradation efficiency in 30 min. The results exhibited that the increased catalyst doses and PMSconcentration lead to ascending MOX removal rate, which decreased with the participation of co-existingions. Besides, there is a close relationship between original pH and MOX degradation efficiency. It wasfound that SO4 –, OH, 1O2, and O2 – were involved in the MOX degradation by quenching experimentsand electron paramagnetic resonance (EPR) detection. More importantly, the stable magnetism ofMnFe2O4 NWs contributed to its convenient recycling. Finally, a reliable mechanism for activating PMSwas proposed based on the aforementioned results and previous researches, which could exhibit a novelhorizon in effluent treatment.
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