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        Microstructure and property evolution of diamond-like carbon films co-doped by Al and Ti with different ratios

        Zhou, Yong,Guo, Peng,Sun, Lili,Liu, Linlin,Xu, Xiaowei,Li, Wenxian,Li, Xiaowei,Lee, Kwang-Ryeol,Wang, Aiying Elsevier Sequoia 2019 Surface & coatings technology Vol.361 No.-

        <P><B>Abstract</B></P> <P>Diamond-like carbon (DLC) films with weak carbide metal Al and carbide metal Ti co-doping (Al/Ti-DLC) were prepared by a hybrid ion beam deposition system. The atomic ratios of doped Al to Ti were tailored via designing the special Al/Ti combined sputtering target. The composition, microstructure, roughness, residual stress, hardness, toughness, and tribological behaviors of the deposited films were systematically evaluated to explore the dependence of structural properties on Al/Ti ratios. Results indicated that the high-throughput preparation of DLC films with different Al/Ti atomic ratios was achieved by tailoring the sputtering target and process parameters without the difference in both the film thickness and total Al/Ti content. With the Al/Ti ratios in the films decreased from 8.8 to 3.0, the residual stress, hardness, and toughness of Al/Ti-DLC films increased obviously, originating from the increased fraction of titanium carbide and the reduced Al content. However, the coefficient of friction and wear rate with decreasing the Al/Ti ratio were obviously improved, which was related with the transformation of underlying friction mechanism from the sliding interface graphitization to dangling bond-passivation. The present results not only suggest a high-throughput method to fabricate co-doped DLC films, but also promote the scientific understanding and engineering application of DLC films with high performance.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Ti/Al co-doped diamond-like carbon films were fabricated by a hybrid ion beam method. </LI> <LI> Different Al/Ti ratios were successfully achieved at one time using designed target. </LI> <LI> Al/Ti ratios had no effect on the chemical state of co-doped Ti and Al atoms. </LI> <LI> The mechanical and tribological properties were strongly dependent on Ti/Al ratios. </LI> <LI> Different friction mechanisms were observed with Al/Ti ratios ranged from 8.8 to 3.0. </LI> </UL> </P>

      • KCI등재

        Coral‑Like NiFe2O4/C Composite as the High‑Performance Anode Material for Lithium‑Ion Batteries

        Shanshan Bao,Yifei Xiao,Junfeng Li,Bo Yue,Yanjun Li,Wenxian Sun,Lei Liu,Yi Huang,Li Wang,Peicong Zhang,Xuefei Lai 대한금속·재료학회 2020 ELECTRONIC MATERIALS LETTERS Vol.16 No.3

        In this work, we fabricated NiFe2O4/C composite with a coral-like structure through co-precipitation approach followed bythermal decomposition. The composite with a large surface area of 162.1 m2 g−1 and an average pore size of 11.8 nm wasobtained. The porous structure in the composite derived from oxalate can Effectively accommodate the volume changesof NiFe2O4 during the cycling processes. When used as anode materials, the initial charge and discharge capacities of thecomposite were 926.7 and 1277.7 mAh g−1 at 100 mA g−1. After 50 cycles, the reversible capacity of NiFe2O4/C could stillremain at 892.4 mAh g−1. Even at a current density of 2000 mA g−1, the reversible capacity still reached 523.3 mAh g−1. The results showed that the synergy between NiFe2O4 and carbon improved the electrochemical performance, and the porouscomposite could stabilize the structure of the electrode.

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