Solvent assisted dyeing of wool fibers with reactive dyes in a ternary solvent system for protecting fibers against damage

Aming Wang,Feng Liu,Liangjun Xia,Chunhua Zhang,Sijie Zhou,Zhuan Fu,Yunli Wang,Weilin Xu 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.103 No.-

Severe effluent pollution and chemical damage to protein fibers generated from conventional aqueousdyeing process have stimulated interest in exploiting sustainable dyeing of wool. Herein, an ethanol(EtOH)-carbon tetrachloride (CCl4)-water (H2O) ternary solvent system was used as the dyeing mediumto protect wool fibers from being damaged in the dyeing process. The wool fibers were firstly pretreatedin an aqueous acid solution, followed by dyeing in the EtOH-CCl4-H2O (45:50:5) ternary solvent systemwith reactive dyes. The results indicated that the acid pretreatment solution could be reused for severaltimes, the samples dyed in the EtOH-CCl4-H2O mixture with the investigated dyes showed higher K/S valuescompared to the conventional approach, implying the increased dye utilization and decreased effluentsdischarge were realized. Furthermore, acceptable permeability, good colorfastness, and satisfactoryleveling properties of the dyed samples were achieved using the developed method. Additionally, thesolvent-assisted dyed samples showed improved mechanical properties compared with the conventionallydyed samples. The dyeing mechanisms of wool fibers in the EtOH-CCl4-H2O mixture were illustratedin detail. The proposed dyeing technology consumes fewer energy, freshwater, and chemicals comparedwith the conventional wool dyeing method. Future work will principally concentrate on the reuse of thedye-contaminated EtOH-CCl4-H2O mixture.

Thiazinogeldanamycin, a New Geldanamycin Derivative Produced by Streptomyces hygroscopicus 17997

( Si Yang Ni ),( Lin Zhuan Wu ),( Hong Yuan Wang ),( Mao Luo Gan ),( Yu Cheng Wang ),( Wei Qing He ),( Yi Guang Wang ) 한국미생물 · 생명공학회 2011 Journal of microbiology and biotechnology Vol.21 No.6

A new geldanamycin (GDM) derivative was discovered and isolated from the fermentation broth of Streptomyces hygroscopicus 17997. Its chemical structure was elucidated as thiazinogeldanamycin by LC-MS, sulfur analysis, and NMR. The addition of cysteine to the fermentation medium significantly stimulated the production level of thiazinogeldanamycin, suggesting cysteine as a precursor of thiazinogeldanamycin production. Although showing a decreased cytotoxicity against HepG2 cancer cells, thiazinogeldanamycin exhibited an improved water solubility and photostability. Thiazinogeldanamycin may represent the first natural GDM derivative characterized so far that uses GDM as its precursor. Its appearance also clearly indicates that an appropriate end-point of fermentation is of critical importance for the maximal production of GDM by Streptomyces hygroscopicus 17997.

Disorders of Liver : The Study Of The Relationship Between Morphological Characteristics Of Tumor Microvessel And The Clinical Pathology Features Of The Hepatocellular Carcinoma

( Zhuan Yi Cui ),( Gui Qi Wang ) 대한소화기학회 2007 SIDDS Vol.9 No.-

Background/Aims: There is sufficient evidence that tumour microvessels are pathology foundation and requisite condition of infarctate tumor in growthing and transferring. It is more to study primary hepatocellular carcinoma microvessels densities, while it is few to study the relation between microvessels morphous and tumor`s clinical pathology features. This aim of study is to explore the relation between the morphological characteristics of tumor microvessels and the clinical pathology features of hetatocellular carcinoma (HCC). Methods: To collect 55 primary hepatocellular carcinoma tissues preoperatively without artery embolotherapy, and there microvessels appearance was divided into 4 types: punctiform, filate, cireunduction, strip. The microvessels typing, differentiation level, tumors diameter, envelope and satellitic nubble were surveyed. Methods: To collect 55 primary hepatocellular carcinoma tissues preoperatively without artery embolotherapy, which was divided into 4types by microvessels modality: punctiform, filate, circumduction, strip. The microvessels typing, differentiation level, tumors diameter, envelope and satellitic nubble were surveyed. Results: Tumor microvessels typing degrees has the tendency of positive correlation with differentiation level and tumors diameter. Tumor microvessels typing degrees in HCC without envelope is higher than that in HCC with envelope. Tumor microvessels typing is no difference between HCC without satellitic nubble and HCC with satellitic nubble. Conclusions: The morphological Characteristics of HCC`s tumor microvessel were distinctive in different vegetal phases, and had definite rule. Tumor microvessels typing degrees is higher in low-grade differentiation level HCC, bigger HCC and HCC without envelope.

Research on Drug Retail Surveillance and Management System Concerned with Adverse Drug Reaction

Zhang Qinghua,Zhao Shanshan,Wang Zhuan,Cheng Guoquan,Wei Jun,Hu Haiqin 제어로봇시스템학회 2009 제어로봇시스템학회 국제학술대회 논문집 Vol.2009 No.8

Drug security is very important to people. The adverse drug reaction events happened several times these years. The drug retail record should be monitored to prevent drug security event occur. There should be a system to monitor the drug stores to find out which one is selling the outdated drugs, or selling the drugs that have no license agreement. When drug security event occurred, the retail information can be used to find out the customer who bought the drug, where and how much the drug left in the drug stores. The solution and measures such as drug recycle or going to hospital should be carried out according to the retail information from the terminal market. This paper brings out a drug retail tracking and tracing solution system. With this system, drug retail information can be real-time obtained. The information supports the decision to solve the adverse drug reaction events.

1-(2-Pyridylazo)-2-naphthol as a synergistic additive for improving throwing power of through hole copper electronic electroplating

Lei Jin,Zhao-Yun Wang,Zhuan-Yun Cai,Jia-Qiang Yang,An-Ni Zheng,Fang-Zu Yang,De-Yin Wu,Dongping Zhan 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.125 No.-

In this work, we develop a novel 1-(2-Pyridylazo)-2-naphthol (PAN)-based acidic sulfate copper electronicelectroplating process for compact, homogeneous and conformal copper thickening of throughhole (TH). The adsorption characteristics, electrochemical properties and the interaction mechanismsof three additives (PEG, SPS and PAN) are studied in detail. Scanning electron microscope (SEM) and opticalmicroscope (OM) reveal that PAN can make the copper coating in fine grains and high throwing powerof 90.35% in TH without an overhang phenomenon. Theoretical calculations illustrate that the bindingenergies between additive molecules and copper surface decrease in the order: PAN > SPS > PEG. Cyclic voltammetry experiments at rotating rates of 1200 and 200 r/min prove that PAN itself can accelerateand weakly suppress copper electrodeposition at the center and mouth of TH, respectively. PANbehaves respectively the synergistic and antagonistic effects with PEG at the mouth and center of TH,and the weakly synergistic effects with SPS both at the mouth and center of TH. The addition of PANto the virgin make-up solution (VMS) containing PEG and SPS causes decreasing the relative electriccharge (DQ) at high and low rotating rates from 18.52 ± 0.08% to 8.25 ± 0.05%, which satisfies the closercopper electronic electroplating rate at the center and mouth of TH. The effective and complicated synergisticeffects of the additives PEG, SPS and PAN can achieve compact, homogeneous and conformal copperthickening of TH.

Transcriptional Analysis of 10 Selected Genes in a Model of Penicillin G Induced Persistence of Chlamydophila psittaci in HeLa Cells

( Yan Qun Hu ),( Li Li Chen ),( Chuan Wang ),( Ya Feng Xie ),( Zhi Xi Chen ),( Liang Zhuan Liu ),( Ze Hong Su ),( Yi Mou Wu ) 한국미생물 · 생명공학회 2015 Journal of microbiology and biotechnology Vol.25 No.8

Chlamydophila psittaci is an important intracellular pathogen. Persistent infection is an important state of the host-parasite interaction in this chlamydial infection, which plays a significant role in spreading the organism within animal populations and in causing chronic chlamydiosis and serious sequelae. In this study, a C. psittaci persistent infection cell model was induced by penicillin G, and real-time quantitative PCR was used to study the transcriptional levels of 10 C. psittaci genes (dnaA, dnaK, ftsW, ftsY, grpE, rpsD, incC, omcB, CPSIT_0846, and CPSIT_0042) in acute and penicillin-G-induced persistent infection cultures. Compared with the acute cultures, the penicillin-G-treated cultures showed a reduced chlamydial inclusion size and a significantly decreased number of elementary body particles. Additionally, some enlarged aberrant reticulate body particles were present in the penicillin- G-treated cultures but not the acute ones. The expression levels of genes encoding products for cell division (FtsW, FtsY) and outer membrane protein E encoding gene (CPSIT_0042) were downregulated (p < 0.05) from 6 h post-infection onward in the persistent infection cultures. Also from 6 h post-infection, the expression levels of DnaA, DnaK, IncC, RpsD, GrpE, and CPSIT_0846 were upregulated (p < 0.05); however, the expression level of OmcB in the persistent infection was almost the same as that in the acute infection (p > 0.05). These results provide new insight regarding molecular activities that accompany persistence of C. psittaci, which may play important roles in the pathogenesis of C. psittaci infection.

Association of Lipoprotein-Associated Phospholipase A_2 with Characteristics of Vulnerable Coronary Atherosclerotic Plaques

Yu-Sheng Liu,Qing-Hua Lu,Xiao-Bo Hu,Hong-Zhuan Li,Wei-Dong Jiang,Xin Wang,Hao Lin,Ai-Qiong Qin,Yong-Mei Wang,Tong Zhao,Zhao-Qiang Dong,Mei Zhang 연세대학교의과대학 2011 Yonsei medical journal Vol.52 No.6

Purpose: Lipoprotein-associated phospholipase A2 (Lp-PLA_2) is an inflammatory enzyme expressed in atherosclerotic plaques. We investigated the association of circulating Lp-PLA_2 with characteristics of vulnerable coronary atherosclerotic plaques. Materials and Methods: We recruited 113 patients with either unstable angina (UA, n=59) and stable angina (SA, n=54) by coronary angiography. Thirty-six healthy subjects served as controls. Intravascular ultrasound (IVUS) was used to evaluate the characteristics of coronary atherosclerotic plaque, and serum Lp-PLA2 concentration was measured as well. Results: Lp-PLA_2 concentration was significantly higher in both UA and SA patients [(396±36) μg/L and (321±39) μg/L, respectively]compared with the controls [(127±49) μg/L, p<0.01], and higher in UA than SA group. IVUS findings showed that remodeling index (RI) (0.91±0.15 vs. 0.85±0.11, p=0.005) and eccentricity index (EI) (0.73±0.16 vs. 0.65±0.22, p=0.039) were larger in UA than in SA group, and fibrous caps were thicker in SA than UA group [(0.91±0.23) mm vs. (0.63±0.21) mm, p=0.032]. Moreover, Lp-PLA_2 correlated positively with EI (r=0.439, p<0.01) and RI (r=0.592, p<0.05) in UA group. There was an inverse relationship between Lp-PLA_2 and fibrous cap thickness in both UA (r=-0.587, p<0.001) and SA (r=-0.318, p<0.05) groups. The independent risk factors in UA group were Lp-PLA_2 (OR=1.055, 95% CI: 1.03-1.08, p=0.013), LDL-cholesterol (OR=0.032, 95% CI: 0.00-0.05, p=0.041) and fibrous cap thickness (OR=0.008, 95% CI: 0.00-0.45, p=0.019). Lp-PLA_2 was strongly associated with both EI and fibrous cap thickness in both groups. Conclusion: Serum level of Lp-PLA_2 is associated with both eccentricity index and fibrous cap thickness in both UA and SA groups. Elevated levels of circulating Lp-PLA_2 might to be a strong risk factor and more serious for unstable angina than stable angina.